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RESEARCH PAPER · Crystal Growth & Design · 2013

Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3

Hongwei Yu, Shilie Pan, Hongping Wu, Zhihua Yang, Lingyun Dong, Xin Su, Bingbing Zhang, Hongyi Li

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Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3OriginalNoncentrosymmetric Cubic CsCdBO3 with Bichromophore23Li 0.8 Mg 2.1 B 2 O 5 F: the first borate fluoride with magnesium–oxygen–fluorine octahedral chains20BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion8Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer8M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)15Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O1616Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13Synthesis, structures, and properties of two magnesium silicate fluorides Mg 5 (SiO 4 ) 2 F 2 and Mg 3 SiO 4 F 214Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21Li 3 AlSiO 5 : the first aluminosilicate as a potential deep-ultraviolet nonlinear optical crystal with the quaternary diamond-like structure54Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Eu 2+ -Doped NaBa 4 (AlB 4 O 9 ) 2 X 3 (X = Cl, Br) phosphors with intense two-center blue emission and high color purity for n-UV pumped white light-emitting diodes31New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies25New lead( ii ) borates in the PbO/PbF 2 /H 3 BO 3 ternary phase diagram: syntheses and structures of β-Pb 6 B 10 O 21 and Pb 4 B 8 O 164The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes44The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density14Ba 3 B 10 O 17 Br 2 : a new barium borate halide with B–O layered structure4A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge27Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of an Acentric Borate Fluoride: Ba2B5O9F·0.5H2O5Second-order nonlinear optical crystals with mixed anions250Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties23Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)36Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties24Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)33Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups12Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra10Borates: A Rich Source for Optical Materials1089Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layer26Synthesis and optical properties of N→Ga coordinated gallium boroxines6NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate7CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy28Aluminoborates as Nonlinear Optical Materials79Aluminoborates as Nonlinear Optical Materials14Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks15Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties11CsAlB 3 O 6 Cl: the rational construction of a KBBF-type structure with aligned 2 ∞ [AlB 3 O 6 Cl] layers via introducing unprecedented [AlO 3 Cl] tetrahedra5Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8BaAlPO 4 F 2 : structure and properties of the first barium fluoroaluminophosphate with the mixed anion group [Al 2 PO 8 F 5 ]1LiBa 3 Al 2 B 3 O 11 : a deep-ultraviolet transparent optical borate featuring a 2D [Al 2 B 3 O 11 ] ∞ layered structure0Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge0

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  1. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore

    European Journal of Inorganic Chemistry · 2013-10-02

    Hongwei Yu, Hongping Wu, Shilie Pan, Bingbing Zhang, Ming Wen, Zhihua Yang, Hongyi Li, Xiangzhan Jiang

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  2. Li 0.8 Mg 2.1 B 2 O 5 F: the first borate fluoride with magnesium–oxygen–fluorine octahedral chains

    Dalton Transactions · 2013-11-11

    Zheng Wang, Min Zhang, Shilie Pan, Ying Wang, Hui Zhang, Zhaohui Chen

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  3. BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion

    CrystEngComm · 2014-01-01

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Qiang Bian, Zhihua Yang, Hongping Wu, Min Zhang

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  4. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

    Crystal Growth & Design · 2014-03-13

    Shujuan Han, Ying Wang, Shilie Pan, Xiaoyu Dong, Hongping Wu, Jian Wei Han, Yun Mo Yang, Hongwei Yu, Chunyan Bai

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  5. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

    Inorganic Chemistry · 2014-09-26

    Chunyan Bai, Hongwei Yu, Shujuan Han, Shilie Pan, Bingbing Zhang, Ying Wang, Hongping Wu, Zhihua Yang

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  6. Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer

    New Journal of Chemistry · 2014-09-30

    Xiangzhan Jiang, Yun Mo Yang, Shilie Pan, Jian Wei Han, Xiaoyu Dong, Fangyuan Zhang, Hongwei Yu, Ying Wang

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  7. M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)

    Inorganic Chemistry · 2014-11-21

    Jianhua Gao, Jian Li, Dino Sulejmanovic, Shiou‐Jyh Hwu

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  8. Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16

    Materials Research Bulletin · 2014-11-25

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Xiaoxia Nina Lin, Shujuan Han

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  9. Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 6

    Physical Chemistry Chemical Physics · 2015-01-01

    Yun Mo Yang, Xin Su, Shilie Pan, Zhihua Yang

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  10. Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)

    Dalton Transactions · 2015-01-01

    Shujuan Han, Ying Wang, Qun Jing, Hongping Wu, Shilie Pan, Zhihua Yang

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  11. Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates

    Inorganic Chemistry Frontiers · 2015-01-01

    Yeong Hun Kim, T. Thao Tran, P. Shiv Halasyamani, Kang Min Ok

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  12. Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra

    RSC Advances · 2015-01-01

    Chunyan Bai, Shujuan Han, Shilie Pan, Bingbing Zhang, Yun Mo Yang, Lin Li, Zhihua Yang

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  13. Synthesis, structures, and properties of two magnesium silicate fluorides Mg 5 (SiO 4 ) 2 F 2 and Mg 3 SiO 4 F 2

    New Journal of Chemistry · 2015-01-01

    Ni Zhen, Kui Wu, Qiang Li, Shilie Pan, Wenhui Gao, Zhihua Yang

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  14. Linear optical and thermo-physical properties of polar K3B6O10Cl crystal

    Journal of Materiomics · 2015-07-14

    Hongping Wu, Hongwei Yu, Zhihua Yang, Jian Wei Han, Kui Wu, Shilie Pan

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  15. Li 3 AlSiO 5 : the first aluminosilicate as a potential deep-ultraviolet nonlinear optical crystal with the quaternary diamond-like structure

    Physical Chemistry Chemical Physics · 2015-12-12

    Xinglong Chen, Fangfang Zhang, Lili Liu, Bing‐Hua Lei, Xiaoyu Dong, Zhihua Yang, Hongyi Li, Shilie Pan

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  16. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

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  17. Eu 2+ -Doped NaBa 4 (AlB 4 O 9 ) 2 X 3 (X = Cl, Br) phosphors with intense two-center blue emission and high color purity for n-UV pumped white light-emitting diodes

    Journal of Materials Chemistry C · 2016-01-01

    Zhipeng Lian, Qingfeng Yan

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  18. New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method

    Dalton Transactions · 2016-01-01

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  19. NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies

    The Journal of Physical Chemistry C · 2016-02-16

    Ming Wen, Xin Su, Hongping Wu, Juanjuan Lu, Zhihua Yang, Shilie Pan

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  20. New lead( ii ) borates in the PbO/PbF 2 /H 3 BO 3 ternary phase diagram: syntheses and structures of β-Pb 6 B 10 O 21 and Pb 4 B 8 O 16

    New Journal of Chemistry · 2017-01-01

    Lingyun Dong, Liangliang Jia, Lijun Wang

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  21. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

    Dalton Transactions · 2017-01-01

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  22. Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes

    Chemistry - A European Journal · 2017-04-24

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  23. The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density

    Journal of Alloys and Compounds · 2017-05-11

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  24. Ba 3 B 10 O 17 Br 2 : a new barium borate halide with B–O layered structure

    Dalton Transactions · 2018-01-01

    Shujuan Han, H. P. Wu, Hao Li, Zhihua Yang, Shilie Pan, Hao Yu

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  25. A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge

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  26. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

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  27. High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of an Acentric Borate Fluoride: Ba2B5O9F·0.5H2O

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  28. Second-order nonlinear optical crystals with mixed anions

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  29. Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties

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  30. Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)

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  31. Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties

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  32. Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)

    Inorganic Chemistry · 2019-06-04

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  33. Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups

    Inorganic Chemistry · 2019-12-26

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  34. Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra

    Chemical Communications · 2020-01-01

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  35. Borates: A Rich Source for Optical Materials

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  36. Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layer

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  37. Synthesis and optical properties of N→Ga coordinated gallium boroxines

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  38. NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate

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  39. CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy

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  40. Aluminoborates as Nonlinear Optical Materials

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  42. Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks

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  44. CsAlB 3 O 6 Cl: the rational construction of a KBBF-type structure with aligned 2 ∞ [AlB 3 O 6 Cl] layers via introducing unprecedented [AlO 3 Cl] tetrahedra

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  47. BaAlPO 4 F 2 : structure and properties of the first barium fluoroaluminophosphate with the mixed anion group [Al 2 PO 8 F 5 ]

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  48. LiBa 3 Al 2 B 3 O 11 : a deep-ultraviolet transparent optical borate featuring a 2D [Al 2 B 3 O 11 ] ∞ layered structure

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  50. BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge

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