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RESEARCH PAPER · Journal of the American Chemical Society · 2016

Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates

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Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl SilicatesOriginalChemInform Abstract: Understanding the Formation of Salt‐Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt‐Inclusion Cesium Halide Uranyl Silicates.0Th(H2O)(IVO3)2[IVII0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites9Manganese Vanadate Chemistry in Hydrothermal BaF2 Brines: Ba3Mn2(V2O7)2F2 and Ba7Mn8O2(VO4)2F2312Supercritical synthesis and topological analysis of K 5 U 5 O 17 (OH)3Where Do New Materials Come From? Neither the Stork nor the Birds and the Bees! In Search of the Next “First Material”1Flux versus Hydrothermal Growth: Polymorphism of A2(UO2)Si2O6 (A = Rb, Cs)19Observation of Intense X-ray Scintillation in a Family of Mixed Anion Silicates, Cs3RESi4O10F2 (RE = Y, Eu–Lu), Obtained via an Enhanced Flux Crystal Growth Technique59Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds20Synthesis and Crystal Structure of the Layered Lanthanide Oxychlorides Ba3Ln2O5Cl210A Family of Layered Phosphates Crystallizing in a Rare Geometrical Isomer of the Phosphuranylite Topology: Synthesis, Characterization, and Computational Modeling of A4[(UO2)3O2(PO4)2] (A = Alkali Metal) Exhibiting Intralayer Ion Exchange21Hydrothermal Synthesis, Study, and Classification of Microporous Uranium Silicates and Germanates18Comparison of Uranium(VI) and Thorium(IV) Silicates Synthesized via Mixed Fluxes Techniques14Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Breaking a Paradigm: Observation of Magnetic Order in the Purple U(IV) Phosphite: U(HPO3)25Complex Topologies from Simple Building Blocks: Uranium(IV) Thiophosphates21Formation of Open Framework Uranium Germanates: The Influence of Mixed Molten Flux and Charge Density Dependence in U-Silicate and U-Germanate Families19Versatile Uranyl Germanate Framework Hosting 12 Different Alkali Halide 1D Salt Inclusions32Understanding the Stability of Salt-Inclusion Phases for Nuclear Waste-forms through Volume-based Thermodynamics11Mineralogy, Crystallography and Structural Complexity of Natural Uranyl Silicates31Overstepping Löwenstein’s Rule—A Route to Unique Aluminophosphate Frameworks with Three-Dimensional Salt-Inclusion and Ion-Exchange Properties28Flux crystal growth of uranium( v ) containing oxyfluoride perovskites13Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides49Highly crystalline lithium chloride-intercalated graphitic carbon nitride hollow nanotubes for effective lead removal28Synthesis and crystal structure of [(Cs6F)(Cs3AgF)][Ge14O32] through alkali halide flux growth13Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth13Mg3Pt(BO3)2O2: The first platinum borate from the flux technique13Crystal growth of novel 3D skeleton uranyl germanium complexes: influence of synthetic conditions on crystal structures10New germanate and mixed cobalt germanate salt inclusion materials: [(Rb 6 F)(Rb 4 F)][Ge 14 O 32 ] and [(Rb 6 F)(Rb 3.1 Co 0.9 F 0.96 )][Co 3.8 Ge 10.2 O 30 F 2 ]10Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space7Two‐Dimensional Uranyl Borates: From Conventional to Extreme Synthetic Conditions13Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)13Unusual Heterometallic Cation‐Cation Interactions in Uranyl Zinc Germanates4“Soft” Alkali Bromide and Iodide Fluxes for Crystal Growth36Radionuclides from Nature to Nature: Recent Progress in Immobilization of High Level Nuclear Wastes in SYNROC17Flux crystal growth of a new BaTa2O6 polymorph, and of the novel tantalum oxyfluoride salt inclusion phase [Ba3F]Ta4O12F: Flux dependent phase formation5Flux Growth of Uranyl Titanates: Rare Examples of TiO4 Tetrahedra and TiO5 Square Bipyramids10Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates14Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate3Pentanary cesium titanyl/titanate silicate oxyfluorides: Syntheses and structures2Semiconducting silicon–phosphorus frameworks for caging exotic polycations10Uranyl Titanate Silicates: Syntheses, Structures, and Family Relations5Precisely control the ultraviolet to blue light conversion for plant growth: Rigid crystal structure, lattice substitution and flux effect in the Ca1.1Sr0.9SiO4:Ce3+, Li+ phosphor21Two tetravalent uranium silicate and germanate crystals with three membered single-ring by molten salt method: K2USi3O9 and Cs2UGe3O930Luminescence and Scintillation in the Niobium Doped Oxyfluoride Rb4Ge5O9F6:Nb8[Cs6Cl][Ga5GeQ12] (Q = S, Se): two novel porous layered chalcohalides exhibiting two-band emission and ion exchange properties6Effect of charge and anisotropic diffusivity on ion exchange kinetics in nuclear waste form materials6Polyoxometalates from Gases: Mineral-Inspired Synthesis and Characterization of Novel Compounds Containing [Me⊂Cu12o8(Aso4)8] Q- Polyoxocuprate Clusters (Me = Ti(Iv), Bi(Iii))0(Na,Li) 3 (Cl,OH)[Cu 3 OAl(PO 4 ) 3 ]: a first salt-inclusion aluminophosphate oxocuprate with a new type of crystal structure0Organic flux synthesis of covalent organic frameworks109Flux Synthesis, UV–vis Absorbance, and Magnetism of Cesium Copper Silicates with an Isolated Super-Super Exchange Spin Dimer in Cs6Cu2Si9O230Polyoxometalates from gases: Mineral-inspired synthesis and characterization of novel compounds containing [M⊂Cu12O8(AsO4)8]q- polyoxocuprate clusters (M = Ti(IV), Bi(III))3Structural diversity and complexity of antiperovskites38A new salt-inclusion compound CsCl·(VOSe 2 O 5 ) 4 showing nearly isolated spin-1/2 chain structure with a typical square lattice1Uranyl-Tc( vii )/Tc( v ) hybrid clusters5Exploring the Valence Diversity of Uranium by Flux Growth of Uranium Silicate under Inert Atmosphere6Semiconductive Behavior and Photoconductivity of Uranyl Dithiophosphinate Single Crystal1Three uranyl silicate framework structures, Cs1.8K0.2[(UO2)(Si2O6)], K4Sr[(UO2)(Si4O12)], and [Cs2KF][(UO2)(Si4O10)], and theoretical calculation of density functional theory for salt-inclusion material2Results of 25-Year Studies of Uranium Compounds at the Department of Crystallography of St. Petersburg State University3Incorporation of uranium to the langbeinite family in Cs2UⅣLn(PO4)3 actinide waste forms3Rich Chemical Behavior and Topological Variation in Uranium Phosphates via Flux Growth under an Inert Atmosphere0Crystal structure of a new salt-inclusion vanadyl(IV) phosphate CaF(H 2 O)[VO(PO 4 )], related to sincosite0

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  1. ChemInform Abstract: Understanding the Formation of Salt‐Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt‐Inclusion Cesium Halide Uranyl Silicates.

    ChemInform · 2016-09-01

    Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  2. Th(H2O)(IVO3)2[IVII0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites

    Inorganic Chemistry · 2016-11-17

    Yaxing Wang, Linjuan Zhang, Lanhua Chen, Weifeng Li, Xing Dai, Juan Diwu, Jian‐Qiang Wang, Zhifang Chai, Shuao Wang

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  3. Manganese Vanadate Chemistry in Hydrothermal BaF2 Brines: Ba3Mn2(V2O7)2F2 and Ba7Mn8O2(VO4)2F23

    Inorganic Chemistry · 2016-12-05

    Liurukara Duminda Sanjeewa, Colin D. McMillen, Michael A. McGuire, Joseph W. Kolis

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  4. Supercritical synthesis and topological analysis of K 5 U 5 O 17 (OH)

    CrystEngComm · 2017-01-01

    Justin B. Felder, Mark D. Smith, Hans‐Conrad zur Loye

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  5. Where Do New Materials Come From? Neither the Stork nor the Birds and the Bees! In Search of the Next “First Material”

    Scholar Commons (University of South Carolina) · 2017-01-01

    Gregory W. Morrison, Dileka Abeysinghe, Justin B. Felder, Shani Egodawatte, Timothy Ferreira, Hans‐Conrad zur Loye

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  6. Flux versus Hydrothermal Growth: Polymorphism of A2(UO2)Si2O6 (A = Rb, Cs)

    Inorganic Chemistry · 2017-01-20

    Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  7. Observation of Intense X-ray Scintillation in a Family of Mixed Anion Silicates, Cs3RESi4O10F2 (RE = Y, Eu–Lu), Obtained via an Enhanced Flux Crystal Growth Technique

    Journal of the American Chemical Society · 2017-09-19

    Gregory W. Morrison, Allison M. Latshaw, Nicholas R. Spagnuolo, Hans‐Conrad zur Loye

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  8. Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds

    Inorganic Chemistry · 2017-10-09

    Yaxing Wang, Tao Duan, Zhehui Weng, Jie Ling, Xuemiao Yin, Lanhua Chen, Daopeng Sheng, Juan Diwu, Zhifang Chai, Ning Liu, Shuao Wang

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  9. Synthesis and Crystal Structure of the Layered Lanthanide Oxychlorides Ba3Ln2O5Cl2

    Inorganic Chemistry · 2018-02-02

    Tiglet Besara, Daniel Candala Ramírez, Jifeng Sun, Nathaniel W. Falb, Wangwei Lan, Jennifer Neu, Jeffrey B. Whalen, David Joseph Singh, Theo Siegrist

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  10. A Family of Layered Phosphates Crystallizing in a Rare Geometrical Isomer of the Phosphuranylite Topology: Synthesis, Characterization, and Computational Modeling of A4[(UO2)3O2(PO4)2] (A = Alkali Metal) Exhibiting Intralayer Ion Exchange

    Inorganic Chemistry · 2018-04-02

    Christian A. Juillerat, Emily E. Moore, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  11. Hydrothermal Synthesis, Study, and Classification of Microporous Uranium Silicates and Germanates

    Inorganic Chemistry · 2018-04-02

    Haijian Li, Philip Kegler, Dirk Bosbach, Evgeny V. Alekseev

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  12. Comparison of Uranium(VI) and Thorium(IV) Silicates Synthesized via Mixed Fluxes Techniques

    Inorganic Chemistry · 2018-05-16

    Haijian Li, Philip Kegler, Vladislav V. Klepov, Martina Klinkenberg, Dirk Bosbach, Evgeny V. Alekseev

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  13. Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

    Chemistry of Materials · 2018-06-22

    Hans‐Conrad zur Loye, Theodore M. Besmann, Jake Amoroso, Kyle S. Brinkman, Agnès Grandjean, Charles H. Henager, Shenyang Hu, Scott T. Misture, Simon Robert Phillpot, Natalia B. Shustova, Hui Wang, Robert J. Koch, Gregory W. Morrison, Ekaterina A. Dolgopolova

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  14. Breaking a Paradigm: Observation of Magnetic Order in the Purple U(IV) Phosphite: U(HPO3)2

    Inorganic Chemistry · 2018-07-31

    Justin B. Felder, Mark D. Smith, Hans‐Conrad zur Loye

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  15. Complex Topologies from Simple Building Blocks: Uranium(IV) Thiophosphates

    Inorganic Chemistry · 2018-08-16

    Vladislav V. Klepov, Hans‐Conrad zur Loye

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  16. Formation of Open Framework Uranium Germanates: The Influence of Mixed Molten Flux and Charge Density Dependence in U-Silicate and U-Germanate Families

    Inorganic Chemistry · 2018-08-20

    Haijian Li, Eike M. Langer, Philip Kegler, Giuseppe Modolo, Evgeny V. Alekseev

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  17. Versatile Uranyl Germanate Framework Hosting 12 Different Alkali Halide 1D Salt Inclusions

    Inorganic Chemistry · 2018-09-05

    Christian A. Juillerat, Emily E. Moore, Gregory W. Morrison, Mark D. Smith, Theodore M. Besmann, Hans‐Conrad zur Loye

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  18. Understanding the Stability of Salt-Inclusion Phases for Nuclear Waste-forms through Volume-based Thermodynamics

    Scientific Reports · 2018-10-11

    Emily E. Moore, Vancho Kocevski, Christian A. Juillerat, Gregory W. Morrison, Mingyang Zhao, Kyle S. Brinkman, Hans‐Conrad zur Loye, Theodore M. Besmann

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  19. Mineralogy, Crystallography and Structural Complexity of Natural Uranyl Silicates

    Minerals · 2018-11-27

    Jakub Plášil

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  20. Overstepping Löwenstein’s Rule—A Route to Unique Aluminophosphate Frameworks with Three-Dimensional Salt-Inclusion and Ion-Exchange Properties

    Inorganic Chemistry · 2018-12-07

    Vladislav V. Klepov, Christian A. Juillerat, Evgeny V. Alekseev, Hans‐Conrad zur Loye

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  21. Flux crystal growth of uranium( v ) containing oxyfluoride perovskites

    Inorganic Chemistry Frontiers · 2019-01-01

    Christian A. Juillerat, Vancho Kocevski, Gregory W. Morrison, S. Karakalos, Deepak Patil, Scott T. Misture, Theodore M. Besmann, Hans‐Conrad zur Loye

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  22. Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides

    Dalton Transactions · 2019-01-01

    Christian A. Juillerat, Vladislav V. Klepov, Gregory W. Morrison, Kristen A. Pace, Hans‐Conrad zur Loye

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  23. Highly crystalline lithium chloride-intercalated graphitic carbon nitride hollow nanotubes for effective lead removal

    Environmental Science Nano · 2019-01-01

    Ying Zhou, Changzhong Liao, Yiang Fan, Shengshou Ma, Minhua Su, Zhengyuan Zhou, Ting‐Shan Chan, Ying‐Rui Lu, Kaimin Shih

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  24. Synthesis and crystal structure of [(Cs6F)(Cs3AgF)][Ge14O32] through alkali halide flux growth

    Solid State Sciences · 2019-08-16

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  25. Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth

    Frontiers in Chemistry · 2019-08-21

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  26. Mg3Pt(BO3)2O2: The first platinum borate from the flux technique

    Journal of Solid State Chemistry · 2019-11-01

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  27. Crystal growth of novel 3D skeleton uranyl germanium complexes: influence of synthetic conditions on crystal structures

    Dalton Transactions · 2020-01-01

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  28. New germanate and mixed cobalt germanate salt inclusion materials: [(Rb 6 F)(Rb 4 F)][Ge 14 O 32 ] and [(Rb 6 F)(Rb 3.1 Co 0.9 F 0.96 )][Co 3.8 Ge 10.2 O 30 F 2 ]

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    Darren Carone, Mohammad Usman, Vladislav V. Klepov, Mark D. Smith, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  29. Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space

    CrystEngComm · 2020-01-01

    Christian A. Juillerat, Vladislav V. Klepov, Mark D. Smith, Hans‐Conrad zur Loye

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  30. Two‐Dimensional Uranyl Borates: From Conventional to Extreme Synthetic Conditions

    European Journal of Inorganic Chemistry · 2020-01-22

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  31. Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)

    Inorganic Chemistry · 2020-04-10

    Kristen A. Pace, Robert J. Koch, Mark D. Smith, Gregory W. Morrison, Vladislav V. Klepov, Theodore M. Besmann, Scott T. Misture, Hans‐Conrad zur Loye

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  32. Unusual Heterometallic Cation‐Cation Interactions in Uranyl Zinc Germanates

    European Journal of Inorganic Chemistry · 2020-05-06

    Huangjie Lu, Jian Hung Lin, Yaxing Wang, Zi‐Jian Li, Xiaofeng Guo, Jian‐Qiang Wang, Shuao Wang

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  33. “Soft” Alkali Bromide and Iodide Fluxes for Crystal Growth

    Frontiers in Chemistry · 2020-06-26

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  34. Radionuclides from Nature to Nature: Recent Progress in Immobilization of High Level Nuclear Wastes in SYNROC

    Journal of Inorganic Materials · 2020-07-14

    Tao Duan, Yi Ding, Shilin Luo, ZHANG Shengtai, Jian Liu

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  35. Flux crystal growth of a new BaTa2O6 polymorph, and of the novel tantalum oxyfluoride salt inclusion phase [Ba3F]Ta4O12F: Flux dependent phase formation

    Journal of Solid State Chemistry · 2020-10-27

    Ceren Kütahyalı Aslani, Vladislav V. Klepov, Hans‐Conrad zur Loye

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  36. Flux Growth of Uranyl Titanates: Rare Examples of TiO4 Tetrahedra and TiO5 Square Bipyramids

    The Journal of Physical Chemistry A · 2020-11-03

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  37. Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates

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  38. Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate

    Inorganics · 2021-04-06

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  39. Pentanary cesium titanyl/titanate silicate oxyfluorides: Syntheses and structures

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  40. Semiconducting silicon–phosphorus frameworks for caging exotic polycations

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  41. Uranyl Titanate Silicates: Syntheses, Structures, and Family Relations

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  42. Precisely control the ultraviolet to blue light conversion for plant growth: Rigid crystal structure, lattice substitution and flux effect in the Ca1.1Sr0.9SiO4:Ce3+, Li+ phosphor

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  43. Two tetravalent uranium silicate and germanate crystals with three membered single-ring by molten salt method: K2USi3O9 and Cs2UGe3O9

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  44. Luminescence and Scintillation in the Niobium Doped Oxyfluoride Rb4Ge5O9F6:Nb

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  45. [Cs6Cl][Ga5GeQ12] (Q = S, Se): two novel porous layered chalcohalides exhibiting two-band emission and ion exchange properties

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  46. Effect of charge and anisotropic diffusivity on ion exchange kinetics in nuclear waste form materials

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  47. Polyoxometalates from Gases: Mineral-Inspired Synthesis and Characterization of Novel Compounds Containing [Me⊂Cu12o8(Aso4)8] Q- Polyoxocuprate Clusters (Me = Ti(Iv), Bi(Iii))

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  48. (Na,Li) 3 (Cl,OH)[Cu 3 OAl(PO 4 ) 3 ]: a first salt-inclusion aluminophosphate oxocuprate with a new type of crystal structure

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  49. Organic flux synthesis of covalent organic frameworks

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  50. Flux Synthesis, UV–vis Absorbance, and Magnetism of Cesium Copper Silicates with an Isolated Super-Super Exchange Spin Dimer in Cs6Cu2Si9O23

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