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RESEARCH PAPER · Inorganic Chemistry · 2020

Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides

Sergey N. Volkov, Dmitri O. Charkin, M. Yu. Arsent’ev, Alexey V. Povolotskiy, Sergey Yu. Stefanovich, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Vladimir Vladimirovich Shilovskikh, Р. С. Бубнова

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Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate HalidesOriginalNew germanate and mixed cobalt germanate salt inclusion materials: [(Rb 6 F)(Rb 4 F)][Ge 14 O 32 ] and [(Rb 6 F)(Rb 3.1 Co 0.9 F 0.96 )][Co 3.8 Ge 10.2 O 30 F 2 ]10Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge31Incorporation of iodine into uranium oxyhydroxide phases9Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide15A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice11Ag 4 B 7 O 12 X (X = Cl, Br, I) Heptaborate Family: Comprehensive Crystal Chemistry, Thermal Stability Trends, Topology, and Vibrational Anharmonicity13Gram–Charlier approach for anharmonic atomic displacements in inorganic solids: A review16A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I9Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families17Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>0Synthesis, Characterization and Optical Properties of Two Novel Metal Borates1The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>6When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family3Synthesis and Crystal Structure of the First Aqueous Silver Borate Nitrate Ag3B4O6(OH)2(NO3)4Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers5Crystal Chemistry of Silver Borates with Salt Inclusion Structure2Empirical electronic polarizabilities of iodine (I − ) and bromine (Br − , Br 7+ ) for the prediction of refractive indices2Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure1On the border between layered and framework motifs: Ag2[B8O12(OH)2], a novel silver borate with corrugated open-framework layers and unusual hydrogen bonding0

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  1. New germanate and mixed cobalt germanate salt inclusion materials: [(Rb 6 F)(Rb 4 F)][Ge 14 O 32 ] and [(Rb 6 F)(Rb 3.1 Co 0.9 F 0.96 )][Co 3.8 Ge 10.2 O 30 F 2 ]

    CrystEngComm · 2020-01-01

    Darren Carone, Mohammad Usman, Vladislav V. Klepov, Mark D. Smith, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  2. Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge

    Inorganic Chemistry Frontiers · 2020-10-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  3. Incorporation of iodine into uranium oxyhydroxide phases

    Dalton Transactions · 2021-01-01

    Gabriel L. Murphy, Philip Kegler, Martina Klinkenberg, Andreas Wilden, Maximilian Henkes, Dimitri Schneider, Evgeny V. Alekseev

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  4. Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges

    New Journal of Chemistry · 2022-01-01

    Jianbang Chen, Jie Zhang, Aixin Zhu, Xuchu Huang

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  5. Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide

    CrystEngComm · 2022-01-01

    Sergey N. Volkov, Dmitri O. Charkin, M. Yu. Arsent’ev, Sergey M. Aksenov, Lev S. Manelis, Maria Georgievna Krzhizhanovskaya, O. Yu. Sinel’shchikova, В. Л. Уголков, Alexey V. Povolotskiy, Vladimir Vladimirovich Shilovskikh, Andrey A. Antonov, Р. С. Бубнова

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  6. A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice

    Solid State Sciences · 2022-01-31

    Sergey N. Volkov, Dmitri O. Charkin, Lev S. Manelis, M. Yu. Arsent’ev, Valentina A. Yukhno, Alexey V. Povolotskiy, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Vera A. Firsova, Sergey M. Aksenov, Р. С. Бубнова

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  7. Ag 4 B 7 O 12 X (X = Cl, Br, I) Heptaborate Family: Comprehensive Crystal Chemistry, Thermal Stability Trends, Topology, and Vibrational Anharmonicity

    Inorganic Chemistry · 2022-12-21

    Sergey N. Volkov, Dmitri O. Charkin, Vera A. Firsova, Lev S. Manelis, A. M. Banaru, Alexey V. Povolotskiy, Valentina A. Yukhno, M. Yu. Arsent’ev, Yevgeny E. Savchenko, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Р. С. Бубнова, Sergey M. Aksenov

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  8. Gram–Charlier approach for anharmonic atomic displacements in inorganic solids: A review

    Crystallography Reviews · 2023-07-03

    Sergey N. Volkov, Dmitri O. Charkin, Vera A. Firsova, Sergey M. Aksenov, Р. С. Бубнова

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  9. A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I

    Solid State Sciences · 2023-10-04

    Sergey N. Volkov, Dmitri O. Charkin, Vadim E. Kireev, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Nikita Sergeyevich Tsvetov, Yulia A. Vaitieva, Sergey M. Aksenov, Р. С. Бубнова

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  10. Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families

    Solid State Sciences · 2023-12-15

    Sergey N. Volkov, Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, Daria A. Banaru, Yulia A. Vaitieva, Maria Georgievna Krzhizhanovskaya, N. A. Yamnova, Vadim E. Kireev, Alevtina N. Gosteva, Nikita Sergeyevich Tsvetov, Yevgeny E. Savchenko, Р. С. Бубнова

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  11. Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions

    New Journal of Chemistry · 2024-01-01

    Lei Huai, Wenlong Liu, Beibei Zhang, Ru‐Ling Tang, Yi‐Lei Lv, Yue‐Qi Wei, Sheng‐Ping Guo

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  12. The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>

    SSRN Electronic Journal · 2024-01-01

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, Maxim Yu. Arsent apos ev, Maria Georgievna Krzhizhanovskaya, Valeriy L. Ugolkov, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  13. Synthesis, Characterization and Optical Properties of Two Novel Metal Borates

    ChemistrySelect · 2024-04-11

    Menghan Zhou, Hui Yang, Zhifen Guo, Cuixia Xu, Xiaomin Gu, Yuan Hua Lin

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  14. The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>

    Journal of Crystal Growth · 2024-07-31

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, M. Yu. Arsent’ev, Maria Georgievna Krzhizhanovskaya, В. Л. Уголков, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  15. When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family

    Inorganic Chemistry Communications · 2024-08-31

    Sergey N. Volkov, Dmitri O. Charkin, Maria Georgievna Krzhizhanovskaya, А.М. Горянский, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, Sergey Yu. Stefanovich, M. Yu. Arsent’ev, В. Л. Уголков, Yevgeny E. Savchenko, Eduard V. Topalov, Sergey M. Aksenov

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  16. Synthesis and Crystal Structure of the First Aqueous Silver Borate Nitrate Ag3B4O6(OH)2(NO3)

    Journal of Structural Chemistry · 2024-10-01

    Yuliua O. Kopylova, Sergey N. Volkov, Sergey M. Aksenov, Р. С. Бубнова

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  17. Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers

    Dalton Transactions · 2025-01-01

    Sergey N. Volkov, Xia Yang, Vadim E. Kireev, A. M. Banaru, Shujuan Han, Alevtina N. Gosteva, M. Yu. Arsent’ev, Dmitri O. Charkin, Alexey V. Povolotskiy, Yevgeny E. Savchenko, Maria Georgievna Krzhizhanovskaya, Stepan A. Vorobiev, Yulia A. Vaitieva, Sergey M. Aksenov, Fangfang Zhang

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  18. Crystal Chemistry of Silver Borates with Salt Inclusion Structure

    Crystallography Reports · 2025-04-01

    S. N. Volkov, Dmitri O. Charkin, Sergey M. Aksenov, A. M. Banaru, Yu.O. Kopylova, Р. С. Бубнова

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  19. Empirical electronic polarizabilities of iodine (I − ) and bromine (Br − , Br 7+ ) for the prediction of refractive indices

    European Journal of Mineralogy · 2025-12-01

    Shaghayegh Nezamabadi, Patrick A. Fuzon, Florian Kraus, R. X. Fischer

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  20. Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure

    Journal of Solid State Chemistry · 2026-04-02

    Yu.A. Vaitieva, A. M. Banaru, A.N. Gosteva, M. Yu. Arsent’ev, M.G. Krzhizhanovskaya, S.N. Volkov, Sergey M. Aksenov

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  21. On the border between layered and framework motifs: Ag2[B8O12(OH)2], a novel silver borate with corrugated open-framework layers and unusual hydrogen bonding

    Journal of Solid State Chemistry · 2026-08-05

    A. M. Banaru, Yu.A. Vaitieva, A. N. Gosteva, M. Yu. Arsent’ev, A. A. Kompanchenko, Y. E. Savchenko, Maria Georgievna Krzhizhanovskaya, S. N. Volkov, Sergey M. Aksenov

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