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RESEARCH PAPER · Inorganic Chemistry · 2013

New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles

Hongwei Yu, Hongping Wu, Shilie Pan, Ying Wang, Zhihua Yang, Xin Su

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New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 TrianglesOriginalChemInform Abstract: New Salt‐Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles.0Special ∞1[OPb2] Chains and ∞1[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb2(O4Pb8)(BO3)3Br3 and Pb2(O8Pb12)(BO3)2Br614Pb 4 Zn 2 B 10 O 21 : a congruently melting lead zinc borate with a novel [B 10 O 24 ] anionic group and an interesting [Pb 4 O 12 ] ∞ chain28A novel aluminoborate open-framework [In(dien) 2 ][Al 2 B 7 O 16 H 2 ] with large chiral cavities templated by chiral main group metal complexes51Ba18F18In8S21 and Ba9F10In4S10: new kind of mixed anion compounds with the novel low-dimensional structure9Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422Sodium–rare earth carbonates with shorite structure and large second harmonic generation response44Two Cu-complex directed aluminoborates: from 2D layers to 3D frameworks16Two New Barium Borate Fluorides ABa12(BO3)7F4 (A = Li and Na)41M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)15Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Na3Ba2(B3O6)2F: Next Generation of Deep-Ultraviolet Birefringent Materials188Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Organically templated linear metal sulfites2Pb 6 Ba 2 (BO 3 ) 5 X (X = Cl, Br): new borate halides with strong predicted optical anisotropies derived from Pb 2+ and (BO 3 ) 3−23New isoformula borates with similar structures and different properties – Acentric nonlinear optical KGd[B6O10(OH)2] and centrosymmetric KHo[B6O10(OH)2]6Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates9M 2 Ca 3 B 16 O 28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers10Pb 2 Bi 2 GaB 3 O 11 , a new congruent-melting galloborate containing two types of asymmetric cations with a moderate birefringence5Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products38Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates61K5Ba10(BO3)8F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure43Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates31Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method106Synthesis, Crystal Structure, and Nonlinear Optical Properties of a New Alkali and Alkaline Earth Metal Carbonate RbNa5Ca5(CO3)810ACaBO 3 (A = Cs, Rb): two new cubic borates with isolated BO 3 groups24ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges17DFT-Based Comparative Study about the Influence of Fluorine and Hydroxyl Anions on Opto-Electric Properties of Borate Crystals: Choice for Better Anion13Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides21Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O7730Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals258Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge4A novel ammonium pentaborate – poly(ethylene-glycol) templated polymer-inclusion compound6Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways5Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates14Borates: A Rich Source for Optical Materials1090Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer11Structure-performance relationship in tri-coordinated nonlinear optical materials toward optimal second harmonic generation and phase matching31Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer11CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy28Synthesis, Structure Determination, and Characterizations of a Polar Salt-Inclusion Scandium Germanate, Rb10Li3Sc4Ge12O36F7MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges12Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission10Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6Rb 7 PbY 2 (B 5 O 10 ) 3 : A Noncentrosymmetric Rare-Earth Borate Nonlinear Optical Crystal with [B 5 O 10 ] Unit16Synthesis, structural characterization and comparative optoelectronic performance analysis of Al/KSrSm(BO 3)2 /Si and Al/KCaSm(BO 3)2 /Si photodiodes2NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains1A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )1Na 2 SnSO 4 F 2 : an ultraviolet-transparent sulfate crystal with large birefringence driven by stereochemically active tin( ii )1Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances3Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances33

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  1. ChemInform Abstract: New Salt‐Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles.

    ChemInform · 2013-06-21

    Hongwei Yu, Hongping Wu, Shilie Pan, Ying Wang, Zhihua Yang, Xin Su

    Read original paper ↗ ·

  2. Special ∞1[OPb2] Chains and ∞1[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb2(O4Pb8)(BO3)3Br3 and Pb2(O8Pb12)(BO3)2Br6

    Inorganic Chemistry · 2013-09-19

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Xiaoyu Dong, Shujuan Han, Min Zhang

    Read original paper ↗ ·

  3. Pb 4 Zn 2 B 10 O 21 : a congruently melting lead zinc borate with a novel [B 10 O 24 ] anionic group and an interesting [Pb 4 O 12 ] ∞ chain

    New Journal of Chemistry · 2013-10-14

    Hongwei Yu, Hongping Wu, Shilie Pan, Bingbing Zhang, Lingyun Dong, Shujuan Han, Zhihua Yang

    Read original paper ↗ ·

  4. A novel aluminoborate open-framework [In(dien) 2 ][Al 2 B 7 O 16 H 2 ] with large chiral cavities templated by chiral main group metal complexes

    Chemical Communications · 2013-10-31

    Lin Cheng, Guo‐Yu Yang

    Read original paper ↗ ·

  5. Ba18F18In8S21 and Ba9F10In4S10: new kind of mixed anion compounds with the novel low-dimensional structure

    CrystEngComm · 2014-01-01

    Zhong‐Zhen Luo, Chensheng Lin, Weilong Zhang, Hao Zhang, Zhangzhen He, Wen‐Dan Cheng

    Read original paper ↗ ·

  6. Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 4

    New Journal of Chemistry · 2014-01-01

    Zheng Wang, Min Zhang, Shilie Pan, Zhihua Yang, Hui Zhang, Bingbing Zhang, Ying Wang, Jing Kang, Xiaoxia Nina Lin

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  7. Sodium–rare earth carbonates with shorite structure and large second harmonic generation response

    CrystEngComm · 2014-01-01

    Min Luo, Chensheng Lin, Guohong Zou, Ning Ye, Wendan Cheng

    Read original paper ↗ ·

  8. Two Cu-complex directed aluminoborates: from 2D layers to 3D frameworks

    Dalton Transactions · 2014-01-01

    Lin Cheng, Junwei Zhao, Guo‐Yu Yang

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  9. Two New Barium Borate Fluorides ABa12(BO3)7F4 (A = Li and Na)

    Inorganic Chemistry · 2014-02-20

    Jing Zhao, Rukang K. Li

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  10. M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)

    Inorganic Chemistry · 2014-11-21

    Jianhua Gao, Jian Li, Dino Sulejmanovic, Shiou‐Jyh Hwu

    Read original paper ↗ ·

  11. Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2014-12-01

    Hongping Wu, Hongwei Yu, Qiang Bian, Zhihua Yang, Shujuan Han, Shilie Pan

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  12. Na3Ba2(B3O6)2F: Next Generation of Deep-Ultraviolet Birefringent Materials

    Crystal Growth & Design · 2014-12-08

    Hui Zhang, Min Zhang, Shilie Pan, Zhihua Yang, Zheng Wang, Qiang Bian, Xueling Hou, Hongwei Yu, Fangfang Zhang, Kui Wu, Feng Yang, Qinjun Peng, Zuyan Xu, Kelvin B. Chang, Kenneth Reinhard Poeppelmeier

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  13. Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 6

    Physical Chemistry Chemical Physics · 2015-01-01

    Yun Mo Yang, Xin Su, Shilie Pan, Zhihua Yang

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  14. Organically templated linear metal sulfites

    RSC Advances · 2015-01-01

    Ranjay K. Tiwari, Jitendra Kumar, J. N. Behera

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  15. Pb 6 Ba 2 (BO 3 ) 5 X (X = Cl, Br): new borate halides with strong predicted optical anisotropies derived from Pb 2+ and (BO 3 ) 3−

    Dalton Transactions · 2015-01-01

    Lu Liu, Bingbing Zhang, Fangfang Zhang, Fangfang Zhang, Shilie Pan, Fangyuan Zhang, Fangyuan Zhang, Xingwen Zhang, Xiaoyu Dong, Zhihua Yang

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  16. New isoformula borates with similar structures and different properties – Acentric nonlinear optical KGd[B6O10(OH)2] and centrosymmetric KHo[B6O10(OH)2]

    Solid State Sciences · 2015-05-26

    Elena L. Belokoneva, A. P. Topnikova, Sergey Yu. Stefanovich, Elena Dobretsova, Anatoly S. Volkov, Olga V. Dimitrova

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  17. Linear optical and thermo-physical properties of polar K3B6O10Cl crystal

    Journal of Materiomics · 2015-07-14

    Hongping Wu, Hongwei Yu, Zhihua Yang, Jian Wei Han, Kui Wu, Shilie Pan

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  18. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

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  19. Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates

    Elsevier eBooks · 2016-01-01

    Shilie Pan, Y. Wang, Kenneth Reinhard Poeppelmeier

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  20. M 2 Ca 3 B 16 O 28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers

    RSC Advances · 2016-01-01

    Xiangyu Zhang, Danni Li, Hongping Wu, Zhihua Yang, Shilie Pan

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  21. Pb 2 Bi 2 GaB 3 O 11 , a new congruent-melting galloborate containing two types of asymmetric cations with a moderate birefringence

    Dalton Transactions · 2016-01-01

    Lili Liu, Yun Mo Yang, Linping Li, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  22. Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products

    Crystal Growth & Design · 2016-02-02

    Gregory W. Morrison, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  23. Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates

    Journal of the American Chemical Society · 2016-05-24

    Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  24. K5Ba10(BO3)8F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure

    The Journal of Physical Chemistry C · 2016-08-01

    Lili Liu, Yun Mo Yang, Qun Jing, Xiaoyu Dong, Zhihua Yang, Shilie Pan, Kui Wu

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  25. Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates

    Inorganic Chemistry · 2016-09-26

    Miriding Mutailipu, Min Zhang, Xiaoyu Dong, Yanna Chen, Shilie Pan

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  26. Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2016-12-14

    Guoqiang Q. Shi, Fangfang Zhang, Bingbing Zhang, Dianwei Hou, Xinglong Chen, Zhihua Yang, Shilie Pan

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  27. Synthesis, Crystal Structure, and Nonlinear Optical Properties of a New Alkali and Alkaline Earth Metal Carbonate RbNa5Ca5(CO3)8

    Crystals · 2016-12-31

    Qiaoling Chen, Min Luo

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  28. ACaBO 3 (A = Cs, Rb): two new cubic borates with isolated BO 3 groups

    Dalton Transactions · 2017-01-01

    Ming Wen, Hongping Wu, Xin Su, Juanjuan Lu, Zhihua Yang, Xiaohong Wu, Shilie Pan

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  29. ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges

    Dalton Transactions · 2017-01-01

    Ruru Ma, Dongdong Xu, Yun Mo Yang, Xin Su, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  30. DFT-Based Comparative Study about the Influence of Fluorine and Hydroxyl Anions on Opto-Electric Properties of Borate Crystals: Choice for Better Anion

    Inorganic Chemistry · 2017-04-27

    Beenish Bashir, Bingbing Zhang, Ming‐Hsien Lee, Shilie Pan, Zhihua Yang

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  31. Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides

    Chemistry - A European Journal · 2017-06-02

    Lili Liu, Yun Mo Yang, Junben Huang, Xiaoyu Dong, Zhihua Yang, Shilie Pan

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  32. Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77

    Inorganic Chemistry · 2017-10-09

    Maierhaba Abudoureheman, Shujuan Han, Ying Wang, Qiong Liu, Zhihua Yang, Shilie Pan

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  33. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

    Chao Wu, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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  34. Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

    Chemistry of Materials · 2018-06-22

    Hans‐Conrad zur Loye, Theodore M. Besmann, Jake Amoroso, Kyle S. Brinkman, Agnès Grandjean, Charles H. Henager, Shenyang Hu, Scott T. Misture, Simon Robert Phillpot, Natalia B. Shustova, Hui Wang, Robert J. Koch, Gregory W. Morrison, Ekaterina A. Dolgopolova

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  35. Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge

    Solid State Sciences · 2018-12-01

    Kun Chai, Hongyi Li, Mingyuan Zhu, Bin Dai

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  36. A novel ammonium pentaborate – poly(ethylene-glycol) templated polymer-inclusion compound

    Chemical Communications · 2019-01-01

    Anna Ploszajski, Matthew Billing, Neal T. Skipper, Jeremy K. Cockcroft

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  37. Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways

    Dalton Transactions · 2020-01-01

    Mengmeng Ding, Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  38. Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates

    Crystal Growth & Design · 2020-11-12

    Gregory W. Morrison, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  39. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

    Read original paper ↗ ·

  40. Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Guo‐Yu Yang

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  41. Structure-performance relationship in tri-coordinated nonlinear optical materials toward optimal second harmonic generation and phase matching

    Coordination Chemistry Reviews · 2021-06-08

    Fengjuan Hou, Dajiang Mei, Mingjun Xia, Yuandong Wu

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  42. Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer

    Dalton Transactions · 2021-12-01

    Chengfa Wu, Zilong Chen, Jianbang Chen, Zhihua Yang, Fangfang Zhang, Hongsheng Shi, Shilie Pan

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  43. CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy

    Journal of Materials Chemistry C · 2022-01-01

    Yuchen Yan, Jiahao Jiao, Chenchen Tu, Min Zhang, Zhihua Yang, Shilie Pan

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  44. Synthesis, Structure Determination, and Characterizations of a Polar Salt-Inclusion Scandium Germanate, Rb10Li3Sc4Ge12O36F

    Inorganic Chemistry · 2022-01-14

    Chuan Yi Tang, Mingjun Xia, Rukang K. Li

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  45. MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2022-02-02

    Zhikang Chen, Kewang Zhang, Zi‐Jian Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  46. Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation

    Materials Today Chemistry · 2023-01-01

    Huanhuan Cheng, Z. Li, Fromenteze Zhang, Zhihua Yang, Shilie Pan

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  47. K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission

    Inorganic Chemistry · 2023-12-15

    Jianyi Zuo, Qiuyuan Feng, Hong Lei Du

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  48. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Xiaoyan Zhou, Xiang Mao, Pu Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  49. Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions

    New Journal of Chemistry · 2024-01-01

    Lei Huai, Wenlong Liu, Beibei Zhang, Ru‐Ling Tang, Yi‐Lei Lv, Yue‐Qi Wei, Sheng‐Ping Guo

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  50. Rb 7 PbY 2 (B 5 O 10 ) 3 : A Noncentrosymmetric Rare-Earth Borate Nonlinear Optical Crystal with [B 5 O 10 ] Unit

    Inorganic Chemistry · 2025-03-14

    Xinyu Gao, Qing‐Yu Liu, Zhihua Yang, Jian Wei Han, Shilie Pan

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