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RESEARCH PAPER · Chemical Science · 2018

Ba 4 Bi 2 (Si 8−x B 4+x O 29 ) ( x = 0.09): a new acentric metal borosilicate as a promising nonlinear optical material

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Ba 4 Bi 2 (Si 8−x B 4+x O 29 ) ( x = 0.09): a new acentric metal borosilicate as a promising nonlinear optical materialOriginalA 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials78Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge14Fluoroborophosphates: a family of potential deep ultraviolet NLO materials43NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active44Electro-optical properties of bowl-like B36 cluster doped with the first row transition metals: A DFT insight31A new barium-containing alkali metal silicate fluoride NaBa3Si2O7F with deep-UV optical property12Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra73Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra18Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions21A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 1219PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringence37Second harmonic generation responses of KH 2 PO 4 : importance of K and breaking down of Kleinman symmetry49Key Factors Controlling the Large Second Harmonic Generation in Nonlinear Optical Materials37K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46Syntheses, characterization and calculations of LimAnM6O15 (A=Rb, Cs; M=Si, Ge; m+n=6)18Nonlinear optical metal-organic frameworks for ratiometric temperature sensing in physiological range34KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold42High-temperature, high-pressure hydrothermal synthesis, crystal structure, and solid state NMR spectroscopy of a lead borosilicate with boron–silicon mixing: Pb 6 B 2 Si 8 O 255K 3 Na(TaF 7 )(SiF 6 ): a mixed-anion pentanary fluoride with zero-dimensional anions exhibiting a large band gap14Rare-Earth-Free Barium Borostannate with Deep-Blue Light Emission16Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence31K6Bi13(PO4)15, K5Bi(P2O7)2, A5Bi5(PO4)4(P2O7)2 (A=K, Rb): New bismuth phosphates with different condensed phosphate groups8Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate4AZn 2 (BO 3 )Si 2 O 5 (A = Rb, Cs): first examples of KBe 2 BO 3 F 2 structure type in the borosilicate family exhibiting a deep-ultraviolet cutoff edge25BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect32Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material44HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window62RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks11Cation Regulation to Investigate the Chalcogenide Borate RE6Nb2MgSB8O26 (RE = La–Nd) Family12NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges8Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units38Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O32Three polar indium phosphites exhibiting diverse structural networks and SHG-activity9Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence18Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li 3 (OH)PbSiO 463Ba 4 B 14 O 25 : A Deep Ultraviolet Transparent Nonlinear Optical Crystal with Strong Second Harmonic Generation Response Achieved by a Boron‐Rich Closed‐Loop Strategy12CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework24Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units3Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units3Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl24Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers3Two Hydroxyfluorooxoborates Achieving Deep‐Ultraviolet Cutoff Edges and Moderate Birefringence by Assembling Multi‐Anionic Groups6Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates8Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units0La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4Two α‐SiO 2 ‐Related Deep‐Ultraviolet Phase‐Matchable Optical Nonlinear Beryllium Silicate Crystals Na 2 BeSiO 4 and Li 2 BeSiO 4 with Enhanced SHG Effect10Chemical substitution towards a rare-earth borate ultraviolet NLO crystal exhibiting a strong SHG response17Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response2BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge0

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  1. A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials

    Chemical Science · 2019-01-01

    Kui Wu, Yu Chu, Zhihua Yang, Shilie Pan

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  2. Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge

    Inorganic Chemistry Frontiers · 2019-01-01

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Yan Chen, Jiang‐Gao Mao

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  3. Fluoroborophosphates: a family of potential deep ultraviolet NLO materials

    Inorganic Chemistry Frontiers · 2019-01-01

    Baolin Wu, Chun‐Li Hu, Ru‐Ling Tang, Fei‐Fei Mao, Jianghe Feng, Jiang‐Gao Mao

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  4. NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates

    Inorganic Chemistry · 2019-03-04

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Sujuan Yu, Shilie Pan

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  5. KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active

    Crystal Growth & Design · 2019-06-06

    Zeng-Hao Yue, Zhen‐Tao Lu, Huaiguo Xue, Sheng‐Ping Guo

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  6. Electro-optical properties of bowl-like B36 cluster doped with the first row transition metals: A DFT insight

    Physica E Low-dimensional Systems and Nanostructures · 2019-06-19

    Ehsan Shakerzadeh, Marie karbasiyuon

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  7. A new barium-containing alkali metal silicate fluoride NaBa3Si2O7F with deep-UV optical property

    Science China Materials · 2019-07-03

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Tushagu Abudouwufu, Shilie Pan

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  8. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie International Edition · 2019-08-26

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  9. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie · 2019-08-29

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  10. Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions

    Dalton Transactions · 2019-10-27

    Ru‐Ling Tang, Chun‐Li Hu, Jianghe Feng, Zhi Gang Fang, Yan Chen, Fang Kong, Jiang‐Gao Mao

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  11. A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals

    Journal of Materials Chemistry C · 2019-12-10

    Ya Feng Yang, Kui Wu, Xiaowen Wu, Bingbing Zhang, Lihua Gao

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  12. Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 12

    Dalton Transactions · 2019-12-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  13. PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringence

    Chemical Communications · 2020-01-01

    Shutong Jiang, Jinjie Zhou, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  14. Second harmonic generation responses of KH 2 PO 4 : importance of K and breaking down of Kleinman symmetry

    RSC Advances · 2020-01-01

    Minghao Jia, Xiyue Cheng, Myung‐Hwan Whangbo, Maochun Hong, Shuiquan Deng

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  15. Key Factors Controlling the Large Second Harmonic Generation in Nonlinear Optical Materials

    ACS Applied Materials & Interfaces · 2020-01-24

    Xiyue Cheng, Zhenhua Li, Xintao Wu, Maochun Hong, Myung‐Hwan Whangbo, Shuiquan Deng

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  16. K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions

    Chemistry of Materials · 2020-04-02

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Hao Zeng, Zhihua Yang, Shilie Pan

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  17. Syntheses, characterization and calculations of LimAnM6O15 (A=Rb, Cs; M=Si, Ge; m+n=6)

    Science China Materials · 2020-05-15

    Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  18. Nonlinear optical metal-organic frameworks for ratiometric temperature sensing in physiological range

    Chinese Chemical Letters · 2020-10-14

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  19. KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold

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  20. High-temperature, high-pressure hydrothermal synthesis, crystal structure, and solid state NMR spectroscopy of a lead borosilicate with boron–silicon mixing: Pb 6 B 2 Si 8 O 25

    Dalton Transactions · 2021-01-01

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  21. K 3 Na(TaF 7 )(SiF 6 ): a mixed-anion pentanary fluoride with zero-dimensional anions exhibiting a large band gap

    Dalton Transactions · 2021-01-01

    Ru‐Ling Tang, Xin Lian, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  22. Rare-Earth-Free Barium Borostannate with Deep-Blue Light Emission

    Chemistry of Materials · 2021-02-17

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  23. Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence

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  24. K6Bi13(PO4)15, K5Bi(P2O7)2, A5Bi5(PO4)4(P2O7)2 (A=K, Rb): New bismuth phosphates with different condensed phosphate groups

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  25. Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate

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  26. AZn 2 (BO 3 )Si 2 O 5 (A = Rb, Cs): first examples of KBe 2 BO 3 F 2 structure type in the borosilicate family exhibiting a deep-ultraviolet cutoff edge

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  27. BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect

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  28. Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material

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  29. HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups

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  30. Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window

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  31. RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks

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  32. Cation Regulation to Investigate the Chalcogenide Borate RE6Nb2MgSB8O26 (RE = La–Nd) Family

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  33. NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges

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  34. Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units

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  35. Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O3

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  36. Three polar indium phosphites exhibiting diverse structural networks and SHG-activity

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  37. Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence

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  38. Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li 3 (OH)PbSiO 4

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  39. Ba 4 B 14 O 25 : A Deep Ultraviolet Transparent Nonlinear Optical Crystal with Strong Second Harmonic Generation Response Achieved by a Boron‐Rich Closed‐Loop Strategy

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  40. CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework

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  41. Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units

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  42. Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units

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  43. Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl2

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  44. Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers

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  45. Two Hydroxyfluorooxoborates Achieving Deep‐Ultraviolet Cutoff Edges and Moderate Birefringence by Assembling Multi‐Anionic Groups

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  46. Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates

    Inorganic Chemistry · 2024-05-08

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  47. Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units

    Zeitschrift für anorganische und allgemeine Chemie · 2024-06-19

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  48. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  49. Two α‐SiO 2 ‐Related Deep‐Ultraviolet Phase‐Matchable Optical Nonlinear Beryllium Silicate Crystals Na 2 BeSiO 4 and Li 2 BeSiO 4 with Enhanced SHG Effect

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  50. Chemical substitution towards a rare-earth borate ultraviolet NLO crystal exhibiting a strong SHG response

    Inorganic Chemistry Frontiers · 2024-11-21

    Xianghao Kong, Jing Chai, Huijian Zhao, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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