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RESEARCH PAPER · Journal of Materials Chemistry C · 2021

AZn 2 (BO 3 )Si 2 O 5 (A = Rb, Cs): first examples of KBe 2 BO 3 F 2 structure type in the borosilicate family exhibiting a deep-ultraviolet cutoff edge

Tuohetijiang Baiheti, Abudukadi Tudi, Jian Wei Han, Zhihua Yang, Shilie Pan

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AZn 2 (BO 3 )Si 2 O 5 (A = Rb, Cs): first examples of KBe 2 BO 3 F 2 structure type in the borosilicate family exhibiting a deep-ultraviolet cutoff edgeOriginalLi 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures8Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra36Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe2BO3F2 as the Template95Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15K(NH4)Zn2(PO4)2: a Beryllium-Free Sr2Be2B2O7 Derivative with Enhanced Interlayer Connectivity7Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units3Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates8Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units0NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission3La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy9Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy6Two α‐SiO 2 ‐Related Deep‐Ultraviolet Phase‐Matchable Optical Nonlinear Beryllium Silicate Crystals Na 2 BeSiO 4 and Li 2 BeSiO 4 with Enhanced SHG Effect10Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13Symmetry Breaking via Anion-Molecule Synergy: Fluorine and Crystalline Water Directed Construction of Noncentrosymmetric Sr(IO2F2)2·2H2O0Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal KRb3B6Ge3O17 Composed of [B3O8] Units and [GeO4] Tetrahedra6Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal25Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response2Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge0Zn 4 (BO 3 ) 2 (CO 2 CH 2 NH 2 ) 2 ·H 2 O: An Organic–Inorganic Hybridized KBe 2 BO 3 F 2 -like Ultraviolet Nonlinear Optical Crystal3K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units2

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25 direct citing papers saved.

  1. Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures

    CrystEngComm · 2022-01-01

    Xinlei Li, Yang Zhang, Yang Pan, Yucheng Hao, Yuan Hua Lin, Haijian Li, Minghua Li, Changzeng Fan, Evgeny V. Alekseev

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  2. Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra

    Inorganic Chemistry · 2022-10-28

    Weijie Xie, Zhi Gang Fang, Jiang‐Gao Mao

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  3. Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe2BO3F2 as the Template

    ACS Central Science · 2022-11-11

    Zi‐Jian Li, Wenqi Jin, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  4. Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge

    New Journal of Chemistry · 2023-01-01

    Zhiyuan Zhang, Lihan Deng, Die Xu, Mei Ying Hu, Zhencheng Wu, Xin Su, Yineng Huang

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  5. Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

    Inorganic Chemistry · 2023-12-19

    Guangsheng Xu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

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  6. K(NH4)Zn2(PO4)2: a Beryllium-Free Sr2Be2B2O7 Derivative with Enhanced Interlayer Connectivity

    Inorganic Chemistry · 2023-12-22

    Gangji Yi, Wei Zeng, Yuqiao Zhou, Hongmei Zeng, Zhien Lin, Guohong Zou

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  7. Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units

    New Journal of Chemistry · 2024-01-01

    Aihaimaitijiang Ababaikeri, Xueting Pan, Gulimeikereyi Tuniyazi, Xiangzhan Jiang, Yanhui Zhang, Dilnur Malik

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  8. Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates

    Inorganic Chemistry · 2024-05-08

    Yucheng Hao, Jian Qiu Deng, Chang-Lin Chen, Yuan Hua Lin, Haijian Li, Guangchao Qin, Kunhong Hu

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  9. Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units

    Zeitschrift für anorganische und allgemeine Chemie · 2024-06-19

    Aihaimaitijiang Ababaikeri, Gulimeikereyi Tuniyazi, Yanhui Zhang, Dilnur Malik

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  10. NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission

    Crystal Research and Technology · 2024-07-19

    Luyong Zhang, Shibin Wang, Zhencheng Wu, Xueling Hou, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  11. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  12. (C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy

    Inorganic Chemistry · 2024-07-31

    Yi‐Lei Lv, Liang Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  13. Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy

    Inorganic Chemistry · 2024-10-07

    Zichang Wang, Jianyi Zuo, Qing‐Yu Liu, Xueling Hou, Minqiang Gai

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  14. Two α‐SiO 2 ‐Related Deep‐Ultraviolet Phase‐Matchable Optical Nonlinear Beryllium Silicate Crystals Na 2 BeSiO 4 and Li 2 BeSiO 4 with Enhanced SHG Effect

    Small · 2024-10-29

    Yi-Gang Chen, Xingxing Jiang, Hongxiao Lv, Dajiang Mei, Xia Zhang, Xia Zhang, Yao Guo, Zheshuai Lin, Xian‐Ming Zhang, Xian‐Ming Zhang

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  15. Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships

    Coordination Chemistry Reviews · 2025-04-06

    Junben Huang, Chenglong Zhang, Siying Chen, Ailijiang Abudurusuli

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  16. Symmetry Breaking via Anion-Molecule Synergy: Fluorine and Crystalline Water Directed Construction of Noncentrosymmetric Sr(IO2F2)2·2H2O

    Inorganic Chemistry · 2025-06-09

    Peng Jiang, Wenhu Wang, Juhui Cui, Ping Bai, Hongli Wu, Minqiang Gai

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  17. Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal KRb3B6Ge3O17 Composed of [B3O8] Units and [GeO4] Tetrahedra

    Inorganic Chemistry · 2025-06-27

    Ziqi Guo, Xianchao Zhu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  18. Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal

    Journal of the American Chemical Society · 2025-08-26

    Haonan Liu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  19. Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions

    Chinese Journal of Structural Chemistry · 2025-09-01

    Yangfeifei Ou, Xiaoliang Zhou, You‐Zhao Lan, Jian‐Wen Cheng

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  20. LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-12-11

    Mingyue Gu, Hu Liu, Xianchao Zhu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  21. Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units

    Inorganic Chemistry Frontiers · 2026-01-01

    Yucheng Hao, Qiuhui Zhang, Haoran Yu, Xikai Miu, Simin Cai, Xinnan Li, Fengshan Yu, Yuan Lin, Mingyang Cao

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  22. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

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  23. BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge

    Journal of Molecular Structure · 2026-01-15

    Xiya Wen, Tingwen Han, Yali Cao, Yun Yang

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  24. Zn 4 (BO 3 ) 2 (CO 2 CH 2 NH 2 ) 2 ·H 2 O: An Organic–Inorganic Hybridized KBe 2 BO 3 F 2 -like Ultraviolet Nonlinear Optical Crystal

    Inorganic Chemistry · 2026-01-27

    Yanming Han, Chensheng Lin, Xin Wen, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

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  25. K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units

    Inorganic Chemistry · 2026-05-28

    Xueqing Liu, Xinyue Shi, Yuan Fang, Yipeng Pang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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