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RESEARCH PAPER · Chemistry of Materials · 2020

K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions

Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Hao Zeng, Zhihua Yang, Shilie Pan

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K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate AnionsOriginalBi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material20A new langbeinite-type phosphate K2GdHf(PO4)3: synthesis, crystal structure, band structure and luminescence properties9Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11Synthesis, Structure, and Characterization of d0 Transition-Metal Iodate: BaTi(IO3)6·0.5H2O12Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation34The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity17Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units28Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11Titanium Iodates with a Second-Harmonic-Generation Response8A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance35High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies323Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures2K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units6Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions16BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2Centrosymmetric Rb[Te 2 O 4 (OH) 5 ] and noncentrosymmetric K 2 [Te 3 O 8 (OH) 4 ]: metal tellurates with corner and edge-sharing (Te 4 O 18 ) 12− anion groups8Unprecedented boat-shaped [Mo 2 O 5 (IO 3 ) 4 ] 2− polyanions induced a strong second harmonic generation response31Explorations of New SHG Materials in Mercury Iodate Sulfate System**9General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates15Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br30SrZnGeS 4 : A Dual‐Waveband Nonlinear Optical Material with a Transparency Spanning UV/Vis and Far‐IR Spectral Regions88SrZnGeS4: A Dual‐Waveband Nonlinear Optical Material with a Transparency Spanning UV/Vis and Far‐IR Spectral Regions12NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps12Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence8New layered nonlinear optical iodate Cs 3 Ta(IO 3 ) 8 : topology-symmetry analysis and structure prediction6Growth and Optical Properties of Large-Sized NaVO2(IO3)2(H2O) Crystals for Second-Harmonic Generation Applications12Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase16ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method8Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Single-Crystalline Li2Sn(IO3)6 Microwires: Combining Optical-Waveguiding and Frequency-Doubling Functions5(NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence22A survey of stereoactive oxysalts for linear and nonlinear optical applications40Synthesis and Structure of a New Iodate Cs5[Sc2(IO3)9](IO3)2 with a Complex Framework Based on the Condensation of [Sc(IO3)6] Building Blocks4Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8Iodine speciation in basaltic melts at depth0K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions1Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates0Three Deep-UV Phosphate Optical Materials with Interesting Structural Evolution0Multifactorial directed regulation of anionic units in praseodymium-contained iodates1Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures1KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy7Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design0

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  1. Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material

    Dalton Transactions · 2020-01-01

    Fei‐Fei Mao, Jinyu Hu, Bingxuan Li, Hua Wu

    Read original paper ↗ ·

  2. A new langbeinite-type phosphate K2GdHf(PO4)3: synthesis, crystal structure, band structure and luminescence properties

    Acta Crystallographica Section C Structural Chemistry · 2020-07-22

    Hua Nan, Li Chen, Rui-Juan Zhang, Dan Zhao

    Read original paper ↗ ·

  3. Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution

    Chemistry of Materials · 2020-07-24

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Ru‐Ling Tang, Jin Chen, Zhi Gang Fang, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  4. From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution

    Chemistry - An Asian Journal · 2020-09-25

    Fei‐Fei Mao, Jiadi Liu, Jinyu Hu, Hua Wu

    Read original paper ↗ ·

  5. Synthesis, Structure, and Characterization of d0 Transition-Metal Iodate: BaTi(IO3)6·0.5H2O

    Inorganic Chemistry · 2020-10-05

    Zhen Qian, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  6. Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation

    ACS Applied Materials & Interfaces · 2020-10-22

    Lin Lin, Xingxing Jiang, Chao Wu, Longhua Li, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  7. The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity

    Chemical Communications · 2020-12-17

    Gabriel L. Murphy, Yaxing Wang, Philip Kegler, Yumin Wang, Shuao Wang, Evgeny V. Alekseev

    Read original paper ↗ ·

  8. Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units

    Chemical Communications · 2021-01-01

    Mengmeng Ding, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  9. Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition

    Inorganic Chemistry · 2021-02-11

    Huimin Song, Dequan Jiang, Naizheng Wang, Wenhao Xing, Ruixin Guo, Zheshuai Lin, Jiyong Yao, Yonggang Wang, Heng Tu, Guochun Zhang

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  10. Titanium Iodates with a Second-Harmonic-Generation Response

    Inorganic Chemistry · 2021-03-29

    Yuan‐Bin Fang, Ruibiao Fu, Hong‐Xin Tang, Qirui Shui, Zuju Ma, Xintao Wu

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  11. A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance

    Chemistry of Materials · 2021-04-07

    Xiaohan Zhang, Bing‐Ping Yang, Chun‐Li Hu, Jin Chen, Q. Huang, Jiang‐Gao Mao

    Read original paper ↗ ·

  12. High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies

    Accounts of Chemical Research · 2021-05-27

    Jin Chen, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  13. Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]

    Crystal Growth & Design · 2021-06-24

    Xiaoqing Jiang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  14. The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures

    Crystals · 2021-08-16

    Gabriel L. Murphy, Philip Kegler, Eike M. Langer, Evgeny V. Alekseev

    Read original paper ↗ ·

  15. K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations

    Chemical Science · 2021-12-06

    Jin Chen, Chun‐Li Hu, Yilin Li, Yan Chen, Qianqian Chen, Jiang‐Gao Mao

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  16. K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units

    Inorganic Chemistry · 2021-12-17

    Jun Sun, Tushagu Abudouwufu, Congcong Jin, Zhiyong Guo, Min Zhang

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  17. Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions

    Inorganic Chemistry Frontiers · 2022-01-01

    Jin Chen, Qianqian Chen, Fei‐Fei Mao, Zhen Liu, Bingxuan Li, Xiaohui Wu, Ke‐Zhao Du

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  18. BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups

    New Journal of Chemistry · 2022-01-01

    Wenjuan Ma, Jianlong Huang, Bin Dai, Feng Yu

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  19. Centrosymmetric Rb[Te 2 O 4 (OH) 5 ] and noncentrosymmetric K 2 [Te 3 O 8 (OH) 4 ]: metal tellurates with corner and edge-sharing (Te 4 O 18 ) 12− anion groups

    Inorganic Chemistry Frontiers · 2022-01-01

    Dandan Wang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  20. Unprecedented boat-shaped [Mo 2 O 5 (IO 3 ) 4 ] 2− polyanions induced a strong second harmonic generation response

    Chemical Communications · 2022-01-01

    Wei Zeng, Xuehua Dong, Yao Tian, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  21. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

    Chemistry - A European Journal · 2022-02-14

    Yilin Li, Mengya Ji, Chun‐Li Hu, Jin Chen, Bingxuan Li, Yuan Hua Lin, Jiang‐Gao Mao

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  22. General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates

    Physical Review Materials · 2022-04-28

    Akun Liang, Robin Turnbull, Plácida Rodríguez-Hernández, Alfonso Muñoz, M. Jasmin, Lan-Ting Shi, Daniel Errandonea

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  23. Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br3

    Solid State Sciences · 2022-04-28

    Bao Jiang, Kewang Zhang, Yuchen Yan, Yanhui Zhang, Zhi Su

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  24. SrZnGeS 4 : A Dual‐Waveband Nonlinear Optical Material with a Transparency Spanning UV/Vis and Far‐IR Spectral Regions

    Angewandte Chemie International Edition · 2022-05-05

    Qianqian Liu, Xin Liu, Li‐Ming Wu, Ling Chen

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  25. SrZnGeS4: A Dual‐Waveband Nonlinear Optical Material with a Transparency Spanning UV/Vis and Far‐IR Spectral Regions

    Angewandte Chemie · 2022-05-05

    Qianqian Liu, Xin Liu, Li‐Ming Wu, Ling Chen

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  26. NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps

    Inorganic Chemistry · 2022-07-21

    Jianlong Huang, Fengjiao Guo, Zhiyong Guo, Jianbang Chen, Bin Dai, Feng Yu

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  27. Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence

    Journal of Materials Chemistry C · 2023-01-01

    Wen Dong Song, Jinxuan Ren, Jinwen Tan, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

    Read original paper ↗ ·

  28. New layered nonlinear optical iodate Cs 3 Ta(IO 3 ) 8 : topology-symmetry analysis and structure prediction

    CrystEngComm · 2023-01-01

    Elena L. Belokoneva, Olga Reutova, Olga V. Dimitrova, Anatoly S. Volkov, Sergey Yu. Stefanovich, V. V. Maltsev, Marina F. Vigasina

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  29. Growth and Optical Properties of Large-Sized NaVO2(IO3)2(H2O) Crystals for Second-Harmonic Generation Applications

    Inorganic Chemistry · 2023-01-16

    Xiang Xu, Bingxuan Li, Lingxiong Huang, Bing‐Ping Yang, Ge Zhang, Jiang‐Gao Mao

    Read original paper ↗ ·

  30. Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase

    Inorganic Chemistry · 2023-01-30

    Mingli Liang, Matthew R. Lacroix, Ce Tao, Michael J. Waters, James M. Rondinelli, P. Shiv Halasyamani

    Read original paper ↗ ·

  31. ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method

    Inorganic Chemistry · 2023-04-17

    Dandan Wang, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

    Read original paper ↗ ·

  32. Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions

    ACS Materials Letters · 2023-05-08

    Jiale Chen, Pengcheng Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

    Read original paper ↗ ·

  33. Single-Crystalline Li2Sn(IO3)6 Microwires: Combining Optical-Waveguiding and Frequency-Doubling Functions

    Inorganic Chemistry · 2023-06-05

    Xiang Xu, Bowen Chen, Bowen Chen, Chan Zheng, Li Huang, Bigeng Chen, Bigeng Chen, Jiang‐Gao Mao

    Read original paper ↗ ·

  34. (NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence

    Small · 2023-07-25

    Nan Ma, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  35. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  36. Synthesis and Structure of a New Iodate Cs5[Sc2(IO3)9](IO3)2 with a Complex Framework Based on the Condensation of [Sc(IO3)6] Building Blocks

    Symmetry · 2023-09-17

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  37. Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates

    Chemistry of Materials · 2024-10-04

    Zhenhua Li, Yi Shui, Zhengli Liang, Lehui Liu, Jiahao Wan, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  38. SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap

    Small · 2024-10-27

    Mengya Ji, Yilin Li, Chun‐Li Hu, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

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  39. Iodine speciation in basaltic melts at depth

    Comptes Rendus Géoscience · 2024-12-12

    C. Sanloup, Clémence Leroy, B. Cochain, Tobias Grützner, Qi Chen, Yoshio Kono, Guoyin Shen

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  40. K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions

    New Journal of Chemistry · 2025-01-01

    Min-Quan Lin, M. Duan, Jiang-Gao Mao, Bing‐Ping Yang

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  41. Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates

    SSRN Electronic Journal · 2025-01-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  42. Three Deep-UV Phosphate Optical Materials with Interesting Structural Evolution

    Crystal Growth & Design · 2025-06-25

    Xinglong Liu, Lei Wu, Hongheng Chen, Menglin Zhu, Yi Huang, Qun Jing, Xuebin Yu, Zhaohui Chen

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  43. Multifactorial directed regulation of anionic units in praseodymium-contained iodates

    Journal of Molecular Structure · 2025-09-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Lehui Liu, Xingxing Jiang, Hongming Liu, Hongming Liu

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  44. Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures

    Dalton Transactions · 2025-12-04

    Shenghong Zeng, Mayinuer Maimaiti, Jinche Wu, Tingwen Han, Hui Chai, Fangfang Zhang, Min Zhang

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  45. KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy

    Small · 2025-12-15

    Lei Hou, Siyu Li, Wencong Li, Bingchen Xiao, Yaoqing Chu, Bingbing Zhang, Ying Wang, Xinglong Chen, Lili Liu

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  46. Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design

    Inorganic Chemistry · 2026-07-07

    Yi-Xiang Wang, Shu‐Fang Li, Xin-Ran Hao, Zhixiang Wang, Chu Chu, Bingbing Zhang, Dong Yan

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