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RESEARCH PAPER · Journal of Materials Chemistry C · 2019

A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals

Ya Feng Yang, Kui Wu, Xiaowen Wu, Bingbing Zhang, Lihua Gao

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A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystalsOriginalA review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties59Experimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units15Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra11Structural Tolerance Factor Approach to Defect-Resistant I2-II-IV-X4 Semiconductor Design38(Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template38KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure145Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials130Synthesis, crystal structure, and electronic structure of Li2PbSiS4: a quaternary thiosilicate with a compressed chalcopyrite-like structure4A review on the recently developed promising infrared nonlinear optical materials103Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)21Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond22Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system3Na 2 GaS 2 Cl: a new sodium-rich chalcohalide with two-dimensional [GaS 2 ] ∞ layers and wide interlayer space15Structural and physical properties of 99 complex bulk chalcogenides crystals using first-principles calculations34A review of the structural diversity of [P x S y ] n − motifs and their potential application prospects in metal thiophosphates21Structural, Optical, and Electronic Properties of Two Quaternary Chalcogenide Semiconductors: Ag2SrSiS4 and Ag2SrGeS420Synergistic Effect of π-Conjugated [C(NH 2 ) 3 ] Cation and Sb(III) Lone Pair Stereoactivity on Structural Transformation and Second Harmonic Generation58Cubic Crystal Structure Formation and Optical Properties within the Ag–BII–MIV–X (BII = Sr, Pb; MIV = Si, Ge, Sn; X = S, Se) Family of Semiconductors8Second-Harmonic Generation-Positive Na 2 Ga 2 SiS 6 with a Broad Band Gap and a High Laser Damage Threshold14The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe232A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications114Ternary AGa5S8 (A = K, Rb, Cs): Promising infrared nonlinear optical materials rationally realized by “one-for-multiple substitution” strategy37Rb 2 CdSi 4 S 10 : novel [Si 4 S 10 ] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap79DOUBLE YTTRIUM THIOSILICATES AYSiS4 (A = Rb, Cs): SYNTHESIS, STRUCTURE, OPTICAL PROPERTIES4[Sr 4 Cl 2 ][Si 3 S 9 ]: Ultrawide-bandgap salt-inclusion thiosilicate nonlinear optical material with unprecedented tri-polymerized [Si 3 S 9 ] clusters21Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold39Wide band gaps in nonlinear optical materials AMgAgGa6S11 (A = K, Rb) achieved by the incorporation of dual s-block elements in Ag-based sulfide11BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure6Enhancing second harmonic generation response in infrared nonlinear optical material through Pb substitution: A study of LiPbSiS compound2ZnGa 2 S 4 : an infrared nonlinear optical material with large second‐harmonic generation response and wide band gap28Noncentrosymmetric Na6Pb3P4S16 and Centrosymmetric K2MIIP2S6 (MII = Mg and Zn) Displaying Multiple Membered-Ring Configurations and Strong Optical Anisotropy10Multi-step cation substitution facilitating the exploration of potential infrared nonlinear optical materials6Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Evaluation and prospect of Mid-Infrared nonlinear optical materials in f0 rare earth (RE = Sc, Y, La) chalcogenides44Synthesis, Crystal Structure, and Optical Properties of a New Quaternary Tin Polychalcogenide K2BaSnSe50Moisture-Stable Chalcogenide Solid Electrolytes in Li2BMQ4 (B = Ca, Sr, and Ba; M = Si, Ge, and Sn; Q = O, S, and Se) Systems20Large Mid-Infrared Second-Harmonic Generation in Eu(II)-Based Quaternary Chalcogenides19Enhancement of Crystal Growth in Molten Salts by a Cocrystallization Agent: Synthesis and Luminescent Properties of Ce3+- and Eu2+-Doped La3(SiS4)2I4Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate12Eu(II)‐Based Quaternary Chalcogenides with Noncentrosymmetric Structures Stabilized by Site Disorder of d10 Metal Cations4Research progress and future prospect of chalcogenides with large optical anisotropy46Enhanced Thermoelectric Performance from Li2SrSiS4 to Li2PbSiS4 Driven by Band Degeneracy and Antibonding-Induced Ultralow Thermal Conductivity2Ba 4 Al 4 SnS 12 : balancing bandgap and nonlinear optical performance in thioaluminate via multifunctional group engineering0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0Hydrothermal Synthesis and Electronic and Optical Characterization of Ag 2 (NH 4 )AsS 40Structure–Optical Property Relationships in AMM′Q 3 Chalcogenides0Layered RbLnGeS4 (ln = Ce, Pr, Nd, Sm, Gd): crystal structures, Rb-site disorder–order transition, and structure–property correlations0

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  1. A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties

    Chemical Communications · 2020-01-01

    Guangmao Li, Zhihua Yang, Junjie Li, Shilie Pan

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  2. Experimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units

    Dalton Transactions · 2020-01-01

    Peng Wang, Maierhaba Abudoureheman, Zhaohui Chen

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  3. Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra

    Dalton Transactions · 2020-01-01

    Jun Sun, Miriding Mutailipu, Shichao Cheng, Zhihua Yang, Shilie Pan

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  4. Structural Tolerance Factor Approach to Defect-Resistant I2-II-IV-X4 Semiconductor Design

    Chemistry of Materials · 2020-01-30

    Jon‐Paul Sun, Garrett C. McKeown Wessler, Tianlin Wang, Tong Zhu, Volker Blüm, David B. Mitzi

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  5. (Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template

    Inorganic Chemistry · 2020-03-03

    Yanan Li, Huaiguo Xue, Sheng‐Ping Guo

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  6. KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units

    Inorganic Chemistry · 2020-04-21

    Xiaohui Li, Yiting Chen, Huaiguo Xue, Sheng‐Ping Guo

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  7. HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure

    Chemistry of Materials · 2020-04-24

    Mengyue Li, Zuju Ma, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  8. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2020-06-29

    Weikang Wang, Dajiang Mei, Fei Liang, Jun Zhao, Yuandong Wu, Zheshuai Lin

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  9. Synthesis, crystal structure, and electronic structure of Li2PbSiS4: a quaternary thiosilicate with a compressed chalcopyrite-like structure

    Acta Crystallographica Section C Structural Chemistry · 2020-12-04

    Stanislav S. Stoyko, Andrew J. Craig, Joshua W. Kotchey, Jennifer A. Aitken

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  10. A review on the recently developed promising infrared nonlinear optical materials

    Dalton Transactions · 2021-01-01

    Ailijiang Abudurusuli, Junjie Li, Shilie Pan

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  11. Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)

    Inorganic Chemistry Frontiers · 2021-01-01

    Gary Cicirello, Kui Wu, Bingbing Zhang, Jian Wang

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  12. Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond

    Dalton Transactions · 2021-01-01

    Jennifer R. Glenn, Jeong Bin Cho, Yiqun Wang, Andrew J. Craig, Jian‐Han Zhang, Marvene Cribbs, Stanislav S. Stoyko, Kate E. Rosello, Christopher Barton, Allyson Bonnoni, P. Grima, Joseph H. MacNeil, James M. Rondinelli, Joon Ik Jang, Jennifer A. Aitken

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  13. Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system

    Dalton Transactions · 2021-01-01

    Huanhuan Cheng, Abudukadi Tudi, Peng Wang, Kewang Zhang, Zhihua Yang, Shilie Pan

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  14. Na 2 GaS 2 Cl: a new sodium-rich chalcohalide with two-dimensional [GaS 2 ] ∞ layers and wide interlayer space

    Dalton Transactions · 2021-01-01

    Xiaoshuang Li, Fei Liang, Tianpeng Liu, Haifeng Li

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  15. Structural and physical properties of 99 complex bulk chalcogenides crystals using first-principles calculations

    Scientific Reports · 2021-05-10

    Sahib Hasan, Khagendra Baral, Neng Li, W. Y. Ching

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  16. A review of the structural diversity of [P x S y ] n − motifs and their potential application prospects in metal thiophosphates

    Journal of Physics D Applied Physics · 2021-07-16

    Ya Yang, Miao Song, Xiaowen Wu, Kui Wu

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  17. Structural, Optical, and Electronic Properties of Two Quaternary Chalcogenide Semiconductors: Ag2SrSiS4 and Ag2SrGeS4

    Inorganic Chemistry · 2021-07-28

    Garrett C. McKeown Wessler, Tianlin Wang, Jon‐Paul Sun, Yuheng Liao, Martin C. Fischer, Volker Blüm, David B. Mitzi

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  18. Synergistic Effect of π-Conjugated [C(NH 2 ) 3 ] Cation and Sb(III) Lone Pair Stereoactivity on Structural Transformation and Second Harmonic Generation

    Inorganic Chemistry · 2021-11-19

    Man Zhang, Bingbing Zhang, Daqing Yang, Ying Wang

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  19. Cubic Crystal Structure Formation and Optical Properties within the Ag–BII–MIV–X (BII = Sr, Pb; MIV = Si, Ge, Sn; X = S, Se) Family of Semiconductors

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  20. Second-Harmonic Generation-Positive Na 2 Ga 2 SiS 6 with a Broad Band Gap and a High Laser Damage Threshold

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  21. The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe2

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  22. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

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  23. Ternary AGa5S8 (A = K, Rb, Cs): Promising infrared nonlinear optical materials rationally realized by “one-for-multiple substitution” strategy

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    Wen‐Fa Chen, Xiao‐Ming Jiang, Shao‐Min Pei, Ming‐Shu Zhang, Bin‐Wen Liu, Guo‐Cong Guo

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  24. Rb 2 CdSi 4 S 10 : novel [Si 4 S 10 ] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap

    Materials Horizons · 2022-11-25

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  25. DOUBLE YTTRIUM THIOSILICATES AYSiS4 (A = Rb, Cs): SYNTHESIS, STRUCTURE, OPTICAL PROPERTIES

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  26. [Sr 4 Cl 2 ][Si 3 S 9 ]: Ultrawide-bandgap salt-inclusion thiosilicate nonlinear optical material with unprecedented tri-polymerized [Si 3 S 9 ] clusters

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  27. Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold

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  28. Wide band gaps in nonlinear optical materials AMgAgGa6S11 (A = K, Rb) achieved by the incorporation of dual s-block elements in Ag-based sulfide

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  29. BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure

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  30. Enhancing second harmonic generation response in infrared nonlinear optical material through Pb substitution: A study of LiPbSiS compound

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  31. ZnGa 2 S 4 : an infrared nonlinear optical material with large second‐harmonic generation response and wide band gap

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  32. Noncentrosymmetric Na6Pb3P4S16 and Centrosymmetric K2MIIP2S6 (MII = Mg and Zn) Displaying Multiple Membered-Ring Configurations and Strong Optical Anisotropy

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  33. Multi-step cation substitution facilitating the exploration of potential infrared nonlinear optical materials

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  34. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

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  35. Evaluation and prospect of Mid-Infrared nonlinear optical materials in f0 rare earth (RE = Sc, Y, La) chalcogenides

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  37. Moisture-Stable Chalcogenide Solid Electrolytes in Li2BMQ4 (B = Ca, Sr, and Ba; M = Si, Ge, and Sn; Q = O, S, and Se) Systems

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  38. Large Mid-Infrared Second-Harmonic Generation in Eu(II)-Based Quaternary Chalcogenides

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  39. Enhancement of Crystal Growth in Molten Salts by a Cocrystallization Agent: Synthesis and Luminescent Properties of Ce3+- and Eu2+-Doped La3(SiS4)2I

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  40. Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate

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  41. Eu(II)‐Based Quaternary Chalcogenides with Noncentrosymmetric Structures Stabilized by Site Disorder of d10 Metal Cations

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  42. Research progress and future prospect of chalcogenides with large optical anisotropy

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  43. Enhanced Thermoelectric Performance from Li2SrSiS4 to Li2PbSiS4 Driven by Band Degeneracy and Antibonding-Induced Ultralow Thermal Conductivity

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  44. Ba 4 Al 4 SnS 12 : balancing bandgap and nonlinear optical performance in thioaluminate via multifunctional group engineering

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  45. SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice

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  46. Hydrothermal Synthesis and Electronic and Optical Characterization of Ag 2 (NH 4 )AsS 4

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  48. Layered RbLnGeS4 (ln = Ce, Pr, Nd, Sm, Gd): crystal structures, Rb-site disorder–order transition, and structure–property correlations

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