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RESEARCH PAPER · Inorganic Chemistry · 2020

KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold

Xin Lian, Wen‐Dong Yao, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage ThresholdOriginal[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42K 3 Na(TaF 7 )(SiF 6 ): a mixed-anion pentanary fluoride with zero-dimensional anions exhibiting a large band gap14Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups18A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance35Anion-Tuned Synthesis of Ag Coordination Compounds: Approaches for Optimizing Second-Harmonic-Generation (SHG) Response5Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties24Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties145BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect32Pb 3 SBrI 3 : the first Pb-based chalcohalide with multiple halogens features a unique two-dimensional structure composed of diverse Pb-centered polyhedra12Sc 2 F 2 (B 2 O 5 ): a deep ultraviolet scandium borate fluoride exhibiting large birefringence induced by the synergistic effect of B 2 O 5 and ScO n F 2 groups38Study of the length and influencing factors of air plasma ignition time3HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe232From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**22NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges8Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra17From Ba3Nb2O2F12(H2O)2 to Ba0.5NbO2F2(H2O): Achieving Balanced Nonlinear Optical Performance by O/F Ratio Regulation18Decagram-scale synthesis of heterometallic Ag/Ti cluster as sustainable catalyst for selective oxidation of sulfides13Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Study on the impulse mechanism of optical films formed by laser plasma shock waves1Study on the mechanism of surface pressure of optical films formed by laser plasma shock wave1SrCl2·6H2O: An Alkaline-Earth-Metal Chloride Hexahydrate as Deep-Ultraviolet Nonlinear-Optical Crystal with the {[Sr(H2O)6]2+}∞ Cationic Framework8Study on the Duration of Laser-Induced Thin Film Plasma Flash1Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis -[Zr 6 F 34 ] 10− clusters48Tri-state logic computation by activating DNA origami chains6From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge19Structural transformation from Waugh‐type to Keggin‐type polyoxomolybdate‐based crystalline material for photo/electrocatalysis25Polymorphisms in M2+AlF5(H2O)7 (M2+ = Fe2+, Co2+, or Ni2+): Syntheses, Crystal Structures, and Characterization of New Mixed Metal Fluoride Hydrates0Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design17Complexity of the KNa2ZrF7, KNa2HfF7, and KNa2(Hf,Zr)F7 compounds4Three types of promising functional building units for designing metal halide nonlinear optical crystals20From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity11Fluorescence detection of Al3+ and mechanism exploration based on La-MOF13CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”11Study on the duration of laser-induced air plasma flash near thin film surface0LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations6A First-Principles Analysis of Metal Fluorides with Polar Crystal Structures as Candidates for New Ferroelectric Materials0KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation0Imparting Biodegradability to Highly‐Efficient Upconversion Nanoparticles via Facet‐Selective Zirconium Doping0Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2

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  1. [GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution

    Chemical Science · 2021-01-01

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Zhi Gang Fang, Yuan Hua Lin, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

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  2. K 3 Na(TaF 7 )(SiF 6 ): a mixed-anion pentanary fluoride with zero-dimensional anions exhibiting a large band gap

    Dalton Transactions · 2021-01-01

    Ru‐Ling Tang, Xin Lian, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  3. Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups

    Inorganic Chemistry · 2021-04-06

    Liling Cao, Shengzi Zhang, Dan Zhao, Bingxuan Li, Tao Yan, Guangsai Yang, Zheshuai Lin, Min Luo, Ning Ye

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  4. A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance

    Chemistry of Materials · 2021-04-07

    Xiaohan Zhang, Bing‐Ping Yang, Chun‐Li Hu, Jin Chen, Q. Huang, Jiang‐Gao Mao

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  5. Anion-Tuned Synthesis of Ag Coordination Compounds: Approaches for Optimizing Second-Harmonic-Generation (SHG) Response

    Crystal Growth & Design · 2021-12-21

    Shanyue Wei, Mingxue Yang, Tao Zuo, Lingyi Meng, Jing Chen, Ting Hu, Can‐Zhong Lu, Yiming Xie

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  6. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

    Angewandte Chemie · 2021-12-24

    Xiaohui Li, Zhi‐Hui Shi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  7. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2021-12-24

    Xiaohui Li, Zhi‐Hui Shi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  8. BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect

    Inorganic Chemistry Frontiers · 2022-01-01

    Ru‐Ling Tang, Gang-Xiang Liu, Wen‐Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng‐Ping Guo

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  9. Pb 3 SBrI 3 : the first Pb-based chalcohalide with multiple halogens features a unique two-dimensional structure composed of diverse Pb-centered polyhedra

    Dalton Transactions · 2022-01-01

    Mei Yan, Ru‐Ling Tang, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  10. Sc 2 F 2 (B 2 O 5 ): a deep ultraviolet scandium borate fluoride exhibiting large birefringence induced by the synergistic effect of B 2 O 5 and ScO n F 2 groups

    Inorganic Chemistry Frontiers · 2022-01-01

    Ru‐Ling Tang, Wei Xu, Weijie Xie, Chun‐Li Hu

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  11. Study of the length and influencing factors of air plasma ignition time

    Open Physics · 2022-01-01

    Guixia Wang, Junhong Su

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  12. HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups

    Inorganic Chemistry · 2022-01-14

    Ru‐Ling Tang, Mei Yan, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  13. The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe2

    Journal of Alloys and Compounds · 2022-05-13

    Daniel J. Clark, Jian‐Han Zhang, Andrew J. Craig, Ashley Weiland, Jacilynn A. Brant, Jeong Bin Cho, Yong Soo Kim, Joon Ik Jang, Jennifer A. Aitken

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  14. From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**

    Chemistry - A European Journal · 2022-06-21

    Ru‐Ling Tang, Xin Lian, Xiaohui Li, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  15. NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2022-07-05

    Weijie Xie, Chun‐Li Hu, Zhi Gang Fang, Ming‐Yang Cao, Yuan Hua Lin, Jiang‐Gao Mao

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  16. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra

    Inorganic Chemistry · 2022-08-17

    Mei Yan, Ru‐Ling Tang, Gang-Xiang Liu, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  17. From Ba3Nb2O2F12(H2O)2 to Ba0.5NbO2F2(H2O): Achieving Balanced Nonlinear Optical Performance by O/F Ratio Regulation

    Inorganic Chemistry · 2022-12-07

    Mei Yan, Ru‐Ling Tang, Wenlong Liu, Sheng‐Ping Guo

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  18. Decagram-scale synthesis of heterometallic Ag/Ti cluster as sustainable catalyst for selective oxidation of sulfides

    Journal of Catalysis · 2022-12-10

    Kai Sheng, Xianqiang Huang, Ran Wang, Wei-Zhe Wang, Zhiyong Gao, Chen‐Ho Tung, Di Sun

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  19. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

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  20. Study on the impulse mechanism of optical films formed by laser plasma shock waves

    Open Physics · 2023-01-01

    Guixia Wang, Junhong Su

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  21. Study on the mechanism of surface pressure of optical films formed by laser plasma shock wave

    Physica Scripta · 2023-01-06

    Guixia Wang, Junhong Su

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  22. SrCl2·6H2O: An Alkaline-Earth-Metal Chloride Hexahydrate as Deep-Ultraviolet Nonlinear-Optical Crystal with the {[Sr(H2O)6]2+}∞ Cationic Framework

    Inorganic Chemistry · 2023-06-23

    Wei Xu, Ru‐Ling Tang, Yu-Long Wei, Jinming Wang, Yuqing Zhang, Wenlong Liu, Sheng‐Ping Guo

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  23. Study on the Duration of Laser-Induced Thin Film Plasma Flash

    Coatings · 2023-07-27

    Guixia Wang, Junhong Su, Qingsong Wang

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  24. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  25. Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis -[Zr 6 F 34 ] 10− clusters

    Chemical Science · 2024-01-01

    Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  26. Tri-state logic computation by activating DNA origami chains

    Nanoscale · 2024-01-01

    Kun Wang, Qiuyan Huang, Mohammed Ragab Elshaer, Brian Knorr, P. M. Chaikin, Guolong Zhu

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  27. From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2024-01-17

    Yue‐Qi Wei, Wei Xu, Lei Huai, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  28. Structural transformation from Waugh‐type to Keggin‐type polyoxomolybdate‐based crystalline material for photo/electrocatalysis

    Rare Metals · 2024-01-21

    Pei-Sen Wang, Zitong Wang, Yaya Tan, Peng Chen, Xuecheng Zhang, Lunan Zhang, Yongge Wei, Lubin Ni

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  29. Polymorphisms in M2+AlF5(H2O)7 (M2+ = Fe2+, Co2+, or Ni2+): Syntheses, Crystal Structures, and Characterization of New Mixed Metal Fluoride Hydrates

    Crystals · 2024-02-17

    Jun Min Seo, Hongil Jo, Myung Ho Choi, Kang Min Ok, Hong Young Chang, Sun Woo Kim

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  30. Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design

    Inorganic Chemistry · 2024-03-06

    Mei Yan, Ru‐Ling Tang, Wei Xu, Wenlong Liu, Sheng‐Ping Guo

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  31. Complexity of the KNa2ZrF7, KNa2HfF7, and KNa2(Hf,Zr)F7 compounds

    Journal of Solid State Chemistry · 2024-03-11

    Oksana Matselko, Morgane Poupon, Erika Samoľová, Zuzana Vasková, Blanka Kubíková, Zuzana Netriová, Matej Mičušík, Miroslav Boča

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  32. Three types of promising functional building units for designing metal halide nonlinear optical crystals

    Chinese Journal of Structural Chemistry · 2024-04-01

    Jiajing Wu, Ru‐Ling Tang, Sheng‐Ping Guo

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  33. From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity

    Inorganic Chemistry · 2024-06-04

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  34. Fluorescence detection of Al3+ and mechanism exploration based on La-MOF

    Journal of Solid State Chemistry · 2024-08-05

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  35. CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”

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  36. Study on the duration of laser-induced air plasma flash near thin film surface

    Open Physics · 2025-01-01

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  37. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

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  38. K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations

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  39. A First-Principles Analysis of Metal Fluorides with Polar Crystal Structures as Candidates for New Ferroelectric Materials

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  40. KNa2(Hf,Zr)F7 and KNa2HfF7: isostructural fluorides with phase-matchable second-harmonic generation

    Materials Today Chemistry · 2026-03-31

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  41. Imparting Biodegradability to Highly‐Efficient Upconversion Nanoparticles via Facet‐Selective Zirconium Doping

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  42. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

    Inorganic Chemistry · 2026-06-26

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