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RESEARCH PAPER · Chemistry - A European Journal · 2024

Two Hydroxyfluorooxoborates Achieving Deep‐Ultraviolet Cutoff Edges and Moderate Birefringence by Assembling Multi‐Anionic Groups

Huanhuan Cheng, Xiaojing Li, Shilie Pan, Shilie Pan, Zhihua Yang

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Two Hydroxyfluorooxoborates Achieving Deep‐Ultraviolet Cutoff Edges and Moderate Birefringence by Assembling Multi‐Anionic GroupsOriginalA nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [B 3 O 3 F 4 (OH)] 2−14(C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation25C2H12N6C4O4·2H2O and Na2C4O4·3H2O: Two Ultraviolet Birefringent Compounds with the [C4O4]2– Group3Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates0Fluorination‐Driven Molecular Polarization Engineering in Hydroxyfluorooxoborates for Generating Strong Short‐Wavelength Nonlinear Optical Responses0

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  1. A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [B 3 O 3 F 4 (OH)] 2−

    New Journal of Chemistry · 2024-01-01

    Tao Ouyang, Chen Xu, Shanshan Chen, Yanqiang Li, Xiaoying Shang, Zhiyong Bai, Ningtao Jiang, Zhishuo Yan, Junhua Luo, Sangen Zhao

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  2. (C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation

    Small Structures · 2024-07-28

    Chenhui Hu, Chunjie Shen, Huan Zhou, Jian Wei Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Feng Zhang, Shilie Pan

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  3. C2H12N6C4O4·2H2O and Na2C4O4·3H2O: Two Ultraviolet Birefringent Compounds with the [C4O4]2– Group

    Inorganic Chemistry · 2024-09-10

    Xiaodong Zhang, Bohui Xu, Deshuai Xiao, Linfeng Dong, Xinyuan Zhang, Pifu Gong, Zheshuai Lin

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  4. Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)

    Chemistry of Materials · 2024-11-25

    Huan Pei, Luyong Zhang, Huanhuan Cheng, Shi‐Bin Wang, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  5. From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates

    Small · 2026-08-03

    Chunjie Shen, Junwei Feng, Zhihua Yang, Shilie Pan, Feng Zhang

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  6. Fluorination‐Driven Molecular Polarization Engineering in Hydroxyfluorooxoborates for Generating Strong Short‐Wavelength Nonlinear Optical Responses

    Advanced Functional Materials · 2026-10-09

    Hongkang Su, Juhui Cui, chenxu li, Xiaona Li, Minqiang Gai, Zhihua Yang, Shilie Pan, Min Zhang

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