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RESEARCH PAPER · Dalton Transactions · 2019

Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 12

Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 12OriginalDesign, synthesis, crystal structure and luminescent properties introduced by Eu 3+ of a new type of rare-earth borophosphate CsNa 2 REE 2 (BO 3 )(PO 4 ) 2 (REE = Y, Gd)23AB 11 O 16 (OH) 2 (A = K and Cs): interpenetrating 2D layers with large birefringence7Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups10Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer11Two deep-ultraviolet nonlinear optical barium borates framework: Alkali metal enhances the second-harmonic generation response13Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer9CsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group8A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice11Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window62Two New Nonaborates with {B9} Cluster Open-Frameworks and Short Cutoff Edges4Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge2La2B3O4(OH)3(SO4)2: A new rare-earth borate-sulfate with second-harmonic generation response5Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties9Ba 4 B 14 O 25 : A Deep Ultraviolet Transparent Nonlinear Optical Crystal with Strong Second Harmonic Generation Response Achieved by a Boron‐Rich Closed‐Loop Strategy12Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+2RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence1NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains1Hydroxyl-induced structural reconstruction: two new potassium hepta-borates with deep-UV transparency and enhanced birefringence1Ba 5 Zn 4 (B 3 O 6 ) 2 (B 12 O 24 ): A Borate with Edge-Sharing [BO 4 ] Tetrahedral Connection by Introducing Zn into β-BaB 2 O 42

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  1. Design, synthesis, crystal structure and luminescent properties introduced by Eu 3+ of a new type of rare-earth borophosphate CsNa 2 REE 2 (BO 3 )(PO 4 ) 2 (REE = Y, Gd)

    Dalton Transactions · 2020-01-01

    Dan Zhao, Yali Xue, Ruijuan Zhang, Yan-Ping Fan, Baozhong Liu, Yanan Li, Shirui Zhang

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  2. AB 11 O 16 (OH) 2 (A = K and Cs): interpenetrating 2D layers with large birefringence

    CrystEngComm · 2020-11-19

    Zhen Chen, Jingyu Guo, Shujuan Han, Hao Zeng, Zhihua Yang, Shilie Pan

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  3. Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups

    Inorganic Chemistry · 2020-12-29

    Siru Guo, Wen-Bin Zhang, Min Zhang, Zhihua Yang, Shilie Pan

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  4. Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Guo‐Yu Yang

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  5. Two deep-ultraviolet nonlinear optical barium borates framework: Alkali metal enhances the second-harmonic generation response

    Journal of Solid State Chemistry · 2021-06-06

    Qi–Ming Qiu, Guo‐Yu Yang

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  6. Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer

    Journal of Alloys and Compounds · 2021-12-09

    Kaitong Liu, Jian Wei Han, Fuming Li, Congcong Jin, Zhihua Yang, Miriding Mutailipu, Shilie Pan

    Read original paper ↗ ·

  7. CsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group

    Dalton Transactions · 2022-01-01

    Xinyue Wang, Bingbing Zhang, Daqing Yang, Ying Wang

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  8. A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice

    Solid State Sciences · 2022-01-31

    Sergey N. Volkov, Dmitri O. Charkin, Lev S. Manelis, M. Yu. Arsent’ev, Valentina A. Yukhno, Alexey V. Povolotskiy, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Vera A. Firsova, Sergey M. Aksenov, Р. С. Бубнова

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  9. Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window

    Science China Chemistry · 2022-03-10

    Yanhui Zhang, Fuming Li, Rong Yang, Yun Mo Yang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  10. Two New Nonaborates with {B9} Cluster Open-Frameworks and Short Cutoff Edges

    Molecules · 2022-08-18

    Chong‐An Chen, Guo‐Yu Yang

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  11. Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge

    Inorganica Chimica Acta · 2022-10-19

    Aixin Zhu, Jianbang Chen, Yanhui Zhang, Zhi Guo Su

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  12. La2B3O4(OH)3(SO4)2: A new rare-earth borate-sulfate with second-harmonic generation response

    Journal of Solid State Chemistry · 2022-11-11

    Hui Yang, Ziyu Wang, Cuixia Xu, Yuan Hua Lin, Guoliang Liu

    Read original paper ↗ ·

  13. Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties

    Inorganic Chemistry · 2023-08-21

    Chong‐An Chen, Guo‐Yu Yang

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  14. Ba 4 B 14 O 25 : A Deep Ultraviolet Transparent Nonlinear Optical Crystal with Strong Second Harmonic Generation Response Achieved by a Boron‐Rich Closed‐Loop Strategy

    Small · 2023-11-08

    Weijie Xie, Ru‐Ling Tang, Shengnan Yan, Nan Ma, Chun‐Li Hu, Jiang‐Gao Mao

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  15. Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+

    Journal of Materials Chemistry C · 2025-01-01

    Xintong Cai, Kaitong Liu, Yanhui Zhang

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  16. RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence

    Dalton Transactions · 2025-01-01

    Yujing Zheng, Ke Li, Ling Huang, Fangfang Zhang

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  17. NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains

    Inorganic Chemistry · 2025-07-17

    Xueli Du, Haoran Wang, Haoran Liu, Qingyu Liu, Wenhu Wang, Jiahao Jiao, Yuchen Yan, Xueyan Wu, Min Zhang

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  18. Hydroxyl-induced structural reconstruction: two new potassium hepta-borates with deep-UV transparency and enhanced birefringence

    Inorganic Chemistry Frontiers · 2025-11-15

    Meng Cheng, Wenbin Zhang, Wenqi Jin, Артем Ромаевич Оганов, Zhihua Yang, Shilie Pan

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  19. Ba 5 Zn 4 (B 3 O 6 ) 2 (B 12 O 24 ): A Borate with Edge-Sharing [BO 4 ] Tetrahedral Connection by Introducing Zn into β-BaB 2 O 4

    Inorganic Chemistry · 2026-02-05

    Kaitong Liu, Yuan Rao, Zhaoxue Li, Shihang Zhou, Zhizhong Zhang, Yanhui Zhang

    Read original paper ↗ ·
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