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RESEARCH PAPER · Science China Chemistry · 2022

Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window

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Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission windowOriginalA 2 B 6 O 9 F 2 (A = NH 4 , K): new members of A 2 B 6 O 9 F 2 family with deep-UV cutoff edges and moderate birefringence17Ba 10 LuB 18 O 32 F 13 : the first example of borate in the Lu–B–O–F system with the unprecedented FBB [B 9 O 22 ]12BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB18Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Two layered galloborates from centric to acentric structures: syntheses and NLO properties27NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge9Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge2ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups14Enhancement of birefringence and refractive index dispersion optimization from iodates to fluorooxoiodates1Linear π-conjugated units of the D ∞h point group as superior ultraviolet birefringent units1Mg assists in modulating the dimensionalities of the anionic frameworks of borates1Syntheses, characterization and theoretical calculation of the first alkali magnesium pyrophosphate fluorides with a short cutoff edge4Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units18Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge14Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure6Na2Mg2P2O7F2: A new diphosphate of the cuspidine family without disorder designed by targeted structural modulation1Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6HgBr 2 : an easily growing wide-spectrum birefringent crystal38New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O3NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges6An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution33An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution1M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10About compounds containing 16-valence electron anions [XYZ] n− – a brief and current overview including some properties of such anions0Halogen Bond Unlocks Ultra‐High Birefringence73Halogen Bond Unlocks Ultra‐High Birefringence14A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range8Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units19Cu(I)‐Induced ‘Click Reaction’ Involving Coordination and Covalent Assembly of Hybrid Borates for the Electrocatalytic CO 2 Reduction4Cu(I)‐Induced ‘Click Reaction’ Involving Coordination and Covalent Assembly of Hybrid Borates for the Electrocatalytic CO 2 Reduction11Chemical substitution towards a rare-earth borate ultraviolet NLO crystal exhibiting a strong SHG response17Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement1CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge3Li 2 CeRbB 18 O 30 and Li 2 Cs 2 SrB 18 O 30 : promising low-birefringence materials for UV and deep UV zero-order waveplates4Na 2 PbB 6 O 10 SO 4 and Ca 2.58 Pb 0.42 B 6 O 11 SO 4 : first borate–sulfates featuring 3D porous borate anionic frameworks0Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+2RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence1Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal6Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F34Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge1In Silico Studies Show that –OBO Units Bound to Stable Boron Cages in YB11(OBO)12−$ \mathbf{Y} {\mathbf{B}}_{11} ( \mathbf{O} \mathbf{B} \mathbf{O} {)}_{12}^{-} $ (Y = C/Si) Anions Provide a Desirable Borate‐Rich Solid Electrolyte Interface in Ca‐Ion Batteries1Recent progress in structural design strategies of high-birefringence optical crystals54Breaking the Birefringence Barrier in B–O Crystals via B–C π-scaffolding36CsGaGe₃Se₈: Enhanced optical anisotropy and bandgap via cation-substitution-driven dimensionality reduction0Cation regulation achieves symmetry breaking: from centrosymmetric M 2 Cs 2 B 10 O 17 (M = Na, K) to noncentrosymmetric Na 3 CsB 10 O 172Novel [BO 2 ] superhalogen module-enabled deep-ultraviolet nonlinear optical material: rational design for tailored birefringence and phase matching0Probing structural trends in neutral boron oxide clusters by potassium-tagged infrared photodissociation spectroscopy0Truss bridge-like anhydrous stacking in hybrid crystals triggers ultra-high stability and robust birefringence0Ba 5 Zn 4 (B 3 O 6 ) 2 (B 12 O 24 ): A Borate with Edge-Sharing [BO 4 ] Tetrahedral Connection by Introducing Zn into β-BaB 2 O 42Pyrazole‐Protected Heteronuclear Rare‐Earth Boron‐Oxo Cluster Cage With Tunable Luminescence0K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units2

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  2. Ba 10 LuB 18 O 32 F 13 : the first example of borate in the Lu–B–O–F system with the unprecedented FBB [B 9 O 22 ]

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  3. BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups

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  4. Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB

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  5. Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges

    New Journal of Chemistry · 2022-01-01

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  6. Two layered galloborates from centric to acentric structures: syntheses and NLO properties

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  7. NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge

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  8. Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge

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  9. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

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  10. Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups

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  11. Enhancement of birefringence and refractive index dispersion optimization from iodates to fluorooxoiodates

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  12. Linear π-conjugated units of the D ∞h point group as superior ultraviolet birefringent units

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  13. Mg assists in modulating the dimensionalities of the anionic frameworks of borates

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  14. Syntheses, characterization and theoretical calculation of the first alkali magnesium pyrophosphate fluorides with a short cutoff edge

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  15. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

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  16. Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units

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  17. Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge

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  18. Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure

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  19. Na2Mg2P2O7F2: A new diphosphate of the cuspidine family without disorder designed by targeted structural modulation

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  20. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

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  21. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

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  23. Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F2

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  24. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

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  30. NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges

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  42. Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)

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  46. Na 2 PbB 6 O 10 SO 4 and Ca 2.58 Pb 0.42 B 6 O 11 SO 4 : first borate–sulfates featuring 3D porous borate anionic frameworks

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  49. Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal

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  50. Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F3

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