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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2022

BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect

Ru‐Ling Tang, Gang-Xiang Liu, Wen‐Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng‐Ping Guo

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BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effectOriginalPhosphites: A Nonlinear Optical Materials System with a Wide Band Gap and Moderate Second-Harmonic Generation Effect28A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures13Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses6Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence18Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Recent progress of newly developed functional building units and corresponding nonlinear optical materials14(NH4)3(H3O)Zn4(PO4)4: A nonlinear optical zinc orthophosphate crystal9From Centrosymmetry to Noncentrosymmetry: Precise Structural Regulation and Characterization on ZnHPO3·2H2O Polymorphs13CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework25Successive magnetic transitions and frustrated magnetism in Fe2(HPO3)3 ⋅ 4H2O1Unleashing the potential of π-conjugated [B2O3(OH)2] to enhance birefringence in DUV crystals9Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence12Centric Sc(HPO3)(H2PO3)(H2O) and Acentric Sc(H2PO3)3: Two Ultraviolet Scandium Phosphite Optical Crystals13HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect1MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence7From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units13Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement13Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability4Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27Novel lithium titanium phosphite LiTi(HPO3)2 as low voltage anode material for lithium-ion batteries4Bazn2(Hpo3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge0Highly Polarizable Phosphorus‐Centered Tetrahedra and π‐Conjugated Carbon‐Centered Triangular Moieties Inducing Large Anisotropy and Short‐Wavelength Phase‐Matching23New hybrid phosphite (N2H5)2Co(H2PO3)4.2H2O: Synthesis, crystal structure, Hirshfeld surface analysis, characterization, and dye removal studies3BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge2Unveiling the role of Sn doping on the electrochemical performances of LiTi(HPO3)2 phosphite anode for Lithium-ion batteries0Pioneering sulfophosphite crystals: Co-assembly of phosphite and sulfate units in novel inorganic architectures0(C 4 H 8 N 5 )(PhPHO 2 )·H 2 O: a polar ionic cocrystal with strong second-harmonic generation and high birefringence0Regulating the packing of π-conjugated ligands toward exceptional birefringence in magnesium phosphite hybrids0Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity0Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly1Synthesis, crystal structure elucidation, Hirshfeld surface analysis, and computational studies of a novel phosphite [Na2Zn(HPO3)2 3H2O]0(C 2 N 4 H 7 S)(H 2 PO 3 ): Optical Properties Study of a Metal‐Free Amidinothiourea Phosphite0

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  1. Phosphites: A Nonlinear Optical Materials System with a Wide Band Gap and Moderate Second-Harmonic Generation Effect

    Inorganic Chemistry · 2022-11-08

    Jingjing Zhang, Xiaomin Zhang, Ying Wang, Kui Wu, Bingbing Zhang

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  2. A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures

    CrystEngComm · 2023-01-01

    Yucheng Hao, Yang Zhang, Yuying Zhang, Zixiang Fu, Chunyang Heng, Junjie Li, Jiatian You, Kunhong Hu, Yuan Hua Lin, Haijian Li

    Read original paper ↗ ·

  3. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

    Read original paper ↗ ·

  4. Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Lisiteng Luo, Xuemei Wen, Juan Cheng, Jing Li, Hongmei Zeng, Guohong Zou, Zhien Lin

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  5. Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence

    Inorganic Chemistry · 2023-01-09

    Gang-Xiang Liu, Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  6. Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response

    Chinese Journal of Structural Chemistry · 2023-02-13

    Boxuan Zhang, Zhaohui Chen

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  7. Recent progress of newly developed functional building units and corresponding nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-05-11

    Wenjing Tan, Chenyang Zhang, Chenyang Zhang, Tingting Huang, Bingbing Zhang

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  8. (NH4)3(H3O)Zn4(PO4)4: A nonlinear optical zinc orthophosphate crystal

    Journal of Solid State Chemistry · 2023-06-22

    Yueling Sun, Gang-Xiang Liu, Yi‐Lei Lv, Liang Ma, Wen‐Dong Yao, Ru‐Ling Tang

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  9. From Centrosymmetry to Noncentrosymmetry: Precise Structural Regulation and Characterization on ZnHPO3·2H2O Polymorphs

    Inorganic Chemistry · 2023-07-02

    Xinyu Wei, Xiaoying Wang, Yu Zhang, Shao‐Ming Ying, Jian‐Han Zhang

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  10. CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework

    Scripta Materialia · 2023-12-14

    Liang Ma, Wei Xu, Liyuanyue Xu, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  11. Successive magnetic transitions and frustrated magnetism in Fe2(HPO3)3 ⋅ 4H2O

    European Journal of Inorganic Chemistry · 2024-01-29

    Xiaomeng Cheng, Chengxiang Lv, Shufang Zhang, Ming‐Cui Ding, Bingying Pan

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  12. Unleashing the potential of π-conjugated [B2O3(OH)2] to enhance birefringence in DUV crystals

    Materials Today Chemistry · 2024-03-17

    Wenbin Zhang, Xuping Shi, Ran An, Abudukadi Tudi, Zhihua Yang, Shujuan Han, Shilie Pan

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  13. Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence

    Inorganic Chemistry · 2024-03-28

    Yi‐Lei Lv, Wei Xu, Wen‐Dong Yao, Miao‐Bin Xu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  14. Centric Sc(HPO3)(H2PO3)(H2O) and Acentric Sc(H2PO3)3: Two Ultraviolet Scandium Phosphite Optical Crystals

    Inorganic Chemistry · 2024-04-11

    Liang Ma, Yi‐Lei Lv, Xiao-Fang Ao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  15. HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect

    Inorganic Chemistry Communications · 2024-04-17

    Yueling Sun, An-Hua Gong

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  16. MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence

    Journal of Solid State Chemistry · 2024-05-12

    Yueling Sun, Lei Huai, An-Hua Gong

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  17. From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units

    Inorganic Chemistry · 2024-07-08

    Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  18. Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement

    Advanced Optical Materials · 2024-08-29

    Haotian Qiu, Ran An, Junjie Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  19. Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability

    Inorganic Chemistry · 2024-09-25

    Zhi Gang Fang, Chao-Qian Li, Bing‐Ping Yang, Meihong Duan

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  20. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  21. Novel lithium titanium phosphite LiTi(HPO3)2 as low voltage anode material for lithium-ion batteries

    Materials Research Bulletin · 2024-12-16

    Abdelfettah Lallaoui, Ikrame Taoufik, M’hamed Oubla, Mickaël Mateos, Zineb Edfouf, Fouzia Cherkaoui El Moursli

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  22. Bazn2(Hpo3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

    SSRN Electronic Journal · 2025-01-01

    Yueling Sun, Jian-Cheng Qiao, An-Hua Gong

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  23. Highly Polarizable Phosphorus‐Centered Tetrahedra and π‐Conjugated Carbon‐Centered Triangular Moieties Inducing Large Anisotropy and Short‐Wavelength Phase‐Matching

    Advanced Optical Materials · 2025-01-28

    Wen-Bin Zhang, Muhammad Arif, Huan Zhou, Ran An, Zhihua Yang, Xueling Hou, Shilie Pan, Shujuan Han

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  24. New hybrid phosphite (N2H5)2Co(H2PO3)4.2H2O: Synthesis, crystal structure, Hirshfeld surface analysis, characterization, and dye removal studies

    Inorganic Chemistry Communications · 2025-07-30

    Asmae Ben Abdelhadi, Mohammed Zerrouk, Hicham Oudghiri Hassani, Michal Dušek, Václav Eigner, Rachid Ouarsal, Mohammed Lachkar, Brahim El Bali

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  25. BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

    European Journal of Inorganic Chemistry · 2025-08-27

    Yueling Sun, Anhua Gong

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  26. Unveiling the role of Sn doping on the electrochemical performances of LiTi(HPO3)2 phosphite anode for Lithium-ion batteries

    Journal of Physics and Chemistry of Solids · 2025-08-27

    Hassna Belhaj, M’hamed Oubla, Fouzia Cherkaoui El Moursli, Zineb Edfouf

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  27. Pioneering sulfophosphite crystals: Co-assembly of phosphite and sulfate units in novel inorganic architectures

    Journal of Solid State Chemistry · 2025-08-29

    Zong-Jie Zhao, Fuxing Lin, Kun Hu, Cheng He, Shufeng Yan, Wangchuan Xiao, Jian‐Han Zhang

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  28. (C 4 H 8 N 5 )(PhPHO 2 )·H 2 O: a polar ionic cocrystal with strong second-harmonic generation and high birefringence

    Journal of Materials Chemistry C · 2026-01-01

    Peng Zhuang, Bing‐Ping Yang, Jiang‐Gao Mao

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  29. Regulating the packing of π-conjugated ligands toward exceptional birefringence in magnesium phosphite hybrids

    Dalton Transactions · 2026-01-01

    Luxin Yang, Xuemei Wen, Guohong Zou, 林之恩, Kang Min Ok

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  30. Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity

    Materials Chemistry Frontiers · 2026-01-01

    Peng Zhuang, Chun‐Li Hu, Bing‐Ping Yang, Jiang‐Gao Mao

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  31. Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly

    Chemistry of Materials · 2026-04-21

    Yiran Zhang, Qiao Xia, Xiaotian Zhang, Zhipeng Huang, Mark Graeme Humphrey, Liming Cheng, Kasper Moth‐Poulsen, Chi Zhang, Chao Wu

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  32. Synthesis, crystal structure elucidation, Hirshfeld surface analysis, and computational studies of a novel phosphite [Na2Zn(HPO3)2 3H2O]

    Journal of Molecular Structure · 2026-06-01

    Mohammed Zerrouk, Mohammed Er-Rajy, Morgane Poupon, Michal Dušek, Rachid Ouarsal, Mohammed Lachkar, Brahim El Bali

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  33. (C 2 N 4 H 7 S)(H 2 PO 3 ): Optical Properties Study of a Metal‐Free Amidinothiourea Phosphite

    European Journal of Inorganic Chemistry · 2026-06-02

    Yueling Sun, An-Hua Gong

    Read original paper ↗ ·
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