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RESEARCH PAPER · Chemical Communications · 2020

PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringence

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PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringenceOriginal2(C 3 H 7 N 6 ) + ·2Cl − ·H 2 O: an ultraviolet nonlinear optical crystal with large birefrigence and strong second-harmonic generation78An antimony( iii ) borate with large birefringence exhibiting unwonted [B 5 O 11 ] fundamental building blocks and dimeric [Sb 2 O 6 ] clusters26Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 254First chiral fluorinated lead vanadate selenite Pb 2 (V 2 O 4 F)(VO 2 )(SeO 3 ) 3 with five asymmetric motifs and large optical properties24From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH 4 ) n−2 AE(PO 2 F 2 ) n (AE = Mg, Sr and Ba; n = 2, 3 and 4)9LaTeBO 5 : a new borotellurite with a large birefringence activated by the highly distorted [Te (iv) O 4 ] group16Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)214AZn 2 (BO 3 )Si 2 O 5 (A = Rb, Cs): first examples of KBe 2 BO 3 F 2 structure type in the borosilicate family exhibiting a deep-ultraviolet cutoff edge25BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect32HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36“Removing Center”─An Effective Structure Design Strategy for Nonlinear Optical Crystals37Cs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and Birefringence43Balance of Deep-Ultraviolet Transparency and Large Second Harmonic Generation Response in a Silicate Crystal9Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds37Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra17Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O32Three polar indium phosphites exhibiting diverse structural networks and SHG-activity9Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2Searching for silicate nonlinear optical materials by combining calculation and experiment17A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 331Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal16Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li 3 (OH)PbSiO 463Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units3Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals33LiASi2O5 (A = K, Rb): Effects of cations on crystal structure and optical properties1Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers3PbBeB2O5: A High-Performance Ultraviolet Nonlinear-Optical Crystal with Functional [BeB2O8]8– Group3Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units0Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response1LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response2立体化学活性孤对电子与极性基元协同构筑高性能紫外非线性光学晶体(NH4)2Sb3F9SeO4(特邀)0BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge0K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units2

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  1. 2(C 3 H 7 N 6 ) + ·2Cl − ·H 2 O: an ultraviolet nonlinear optical crystal with large birefrigence and strong second-harmonic generation

    Chemical Communications · 2020-01-01

    Lehui Liu, Chun‐Li Hu, Zhiyong Bai, Feifei Yuan, Yisheng Huang, Lizhen Zhang, Zhoubin Lin

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  2. An antimony( iii ) borate with large birefringence exhibiting unwonted [B 5 O 11 ] fundamental building blocks and dimeric [Sb 2 O 6 ] clusters

    Inorganic Chemistry Frontiers · 2021-01-01

    Zhen Chen, Hao Zeng, Shujuan Han, Zhihua Yang, Shilie Pan

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  3. Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Lei Wang, Hongmei Wang, Die Zhang, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  4. First chiral fluorinated lead vanadate selenite Pb 2 (V 2 O 4 F)(VO 2 )(SeO 3 ) 3 with five asymmetric motifs and large optical properties

    Dalton Transactions · 2021-01-01

    Lin Lin, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  5. From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH 4 ) n−2 AE(PO 2 F 2 ) n (AE = Mg, Sr and Ba; n = 2, 3 and 4)

    Dalton Transactions · 2021-01-01

    Wenyao Zhang, Wenqi Jin, Meng Cheng, Ruonan Zhang, Zhihua Yang, Shilie Pan

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  6. LaTeBO 5 : a new borotellurite with a large birefringence activated by the highly distorted [Te (iv) O 4 ] group

    Dalton Transactions · 2021-01-01

    Jiankang Wang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  7. Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]

    Crystal Growth & Design · 2021-06-24

    Xiaoqing Jiang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  8. Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)2

    Crystal Growth & Design · 2021-09-17

    Yunqiao Guo, Die Zhang, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  9. AZn 2 (BO 3 )Si 2 O 5 (A = Rb, Cs): first examples of KBe 2 BO 3 F 2 structure type in the borosilicate family exhibiting a deep-ultraviolet cutoff edge

    Journal of Materials Chemistry C · 2021-12-24

    Tuohetijiang Baiheti, Abudukadi Tudi, Jian Wei Han, Zhihua Yang, Shilie Pan

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  10. BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect

    Inorganic Chemistry Frontiers · 2022-01-01

    Ru‐Ling Tang, Gang-Xiang Liu, Wen‐Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng‐Ping Guo

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  11. HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups

    Inorganic Chemistry · 2022-01-14

    Ru‐Ling Tang, Mei Yan, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  12. “Removing Center”─An Effective Structure Design Strategy for Nonlinear Optical Crystals

    Chemistry of Materials · 2022-02-15

    Shuzhao Huang, Yun Mo Yang, Jianbang Chen, Wenqi Jin, Shichao Cheng, Zhihua Yang, Shilie Pan

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  13. Cs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and Birefringence

    Chemistry of Materials · 2022-03-22

    Wenli Zhao, Conggang Li, Tao Han, Jinmiao Jiao, Yuheng She, Dianxing Ju, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu

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  14. Balance of Deep-Ultraviolet Transparency and Large Second Harmonic Generation Response in a Silicate Crystal

    Crystal Growth & Design · 2022-04-04

    Zheyao Xiong, Jing Xu, Haotian Tian, Hongyuan Sha, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  15. Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds

    Inorganic Chemistry · 2022-06-16

    Shu‐Fang Li, Liang Hu, Yao Ma, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Dong Yan

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  16. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra

    Inorganic Chemistry · 2022-08-17

    Mei Yan, Ru‐Ling Tang, Gang-Xiang Liu, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  17. Synthesis, structure, characterization, and electronic structure calculation of a new molecule-inclusion strontium gallate Sr6(Ga12O24)·Bi2O3

    Journal of Solid State Chemistry · 2022-10-06

    Lei Huai, Lunan Zhang, Beibei Zhang, Guangan Jia, Wen‐Dong Yao, Wenlong Liu, Ru‐Ling Tang

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  18. Three polar indium phosphites exhibiting diverse structural networks and SHG-activity

    Journal of Solid State Chemistry · 2022-10-10

    Gang-Xiang Liu, Yu-Long Wei, Li-Nan Zhang, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  19. Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge

    New Journal of Chemistry · 2023-01-01

    Zhiyuan Zhang, Lihan Deng, Die Xu, Mei Ying Hu, Zhencheng Wu, Xin Su, Yineng Huang

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  20. Searching for silicate nonlinear optical materials by combining calculation and experiment

    Inorganic Chemistry Frontiers · 2023-01-01

    Jingjing Zhang, Ruqing Wei, Daqing Yang, Ying Wang, Bingbing Zhang

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  21. A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 3

    Small · 2023-02-09

    Zhiyong Bai, Jihyun Lee, Heewon Kim, Yunseung Kuk, Myung‐Ho Choi, Chun‐Li Hu, Kang Min Ok

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  22. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  23. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  24. Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal

    Crystal Growth & Design · 2023-06-27

    Wen Zhi Yang, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin

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  25. Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li 3 (OH)PbSiO 4

    Journal of the American Chemical Society · 2023-10-09

    Yuanyu Yang, Yan Xiao, Bingxuan Li, Yi-Gang Chen, Penghui Guo, Bingbing Zhang, Xian‐Ming Zhang

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  26. Ba 5 Y 12 Zn[O(SiO 4 )] 8 : a novel non-centrosymmetric silicate with a short ultraviolet cut-off edge featuring [ZnSi 4 O 16 ] and [SiO 4 ] units

    New Journal of Chemistry · 2024-01-01

    Aihaimaitijiang Ababaikeri, Xueting Pan, Gulimeikereyi Tuniyazi, Xiangzhan Jiang, Yanhui Zhang, Dilnur Malik

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  27. Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals

    Chemical Science · 2024-01-01

    Yang Li, Kang Min Ok

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  28. LiASi2O5 (A = K, Rb): Effects of cations on crystal structure and optical properties

    Optical Materials · 2024-01-08

    Jun Sun, Bo Ran, Ping Hu, Zhaofeng Wu, Ming‐Hsien Lee, Haiming Duan

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  29. Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers

    Inorganic Chemistry · 2024-03-06

    Binqiang Chai, Shutong Jiang, Bohuai Shao, Shifu Xiong, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  30. PbBeB2O5: A High-Performance Ultraviolet Nonlinear-Optical Crystal with Functional [BeB2O8]8– Group

    Inorganic Chemistry · 2024-05-17

    Fang Wang, Mengke Zi, Qin Chen, Zixu Wang, Jianguang Wang, Xingxing Jiang, Yi-Gang Chen, Yao Guo, Zheshuai Lin, Xian‐Ming Zhang

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  31. Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units

    Zeitschrift für anorganische und allgemeine Chemie · 2024-06-19

    Aihaimaitijiang Ababaikeri, Gulimeikereyi Tuniyazi, Yanhui Zhang, Dilnur Malik

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  32. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

    Inorganic Chemistry Frontiers · 2025-01-01

    Jingdong Yan, Xiangran Kong, Shichao Cheng, Tao Liu, Hongwei Leng, Yunfei Shang, Zuotao Lei, Chunhui Yang

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  33. Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-01-04

    Meihui Chen, Wei Wei, Jiawei Zhao, Juanjuan Lu, Donghai An, Yanna Chen

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  34. LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-12-11

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  35. 立体化学活性孤对电子与极性基元协同构筑高性能紫外非线性光学晶体(NH4)2Sb3F9SeO4(特邀)

    Chinese Journal of Lasers · 2026-01-01

    鄢雨欣 Yan Yuxin, 董雪华 Dong Xuehua, 黄玲 Huang Ling, Zou Guohong

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  36. BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge

    Journal of Molecular Structure · 2026-01-15

    Xiya Wen, Tingwen Han, Yali Cao, Yun Yang

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  37. K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units

    Inorganic Chemistry · 2026-05-28

    Xueqing Liu, Xinyue Shi, Yuan Fang, Yipeng Pang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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