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RESEARCH PAPER · Inorganic Chemistry · 2005

Examining the Out-of-Center Distortion in the [NbOF5]2- Anion

Heather K. Izumi, Janet E. Kirsch, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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Examining the Out-of-Center Distortion in the [NbOF5]2- AnionOriginalAg4V2O6F2: An Electrochemically Active and High Silver Density Phase84Mixed-Metal Tellurites: Synthesis, Structure, and Characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16126Ethylenediaminium niobium oxyfluoride7Diaquabis(1,10-phenanthroline-κ2N,N′)zinc(II) pentafluorooxoniobate(V)3Diaquabis(1,10-phenanthroline-κ2N,N′)cadmium(II) pentafluorooxoniobate(V)2Evidence for Nonpolar Alignment of [NbOF5]2- Anions in Cd(pyridine)4NbOF5 Chains24New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O125Synthesis, structure, and characterization of a new one-dimensional tellurite phosphate, Ba2TeO(PO4)247Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties232Diaquabis(1,10-phenanthroline-κ2 N,N′)manganese(II) pentafluorooxoniobate(V)2Synthesis, structure and characterization of a new inorganic-organic hybrid complex (C3H5N2)2[Cd(C3H4N2)2Nb2O3F8]·2H2O1Metallacycles of Iron, Zinc, and Cadmium Assembled by Polytopic Bis(pyrazolyl)methane Ligands and Fluoride Abstraction from BF4-59Two Organically Templated Niobium and Zinconiobium Fluorophosphates: Low Temperature Hydrothermal Syntheses of NbOF(PO4)2(C2H10N2)2 and Zn3(NbOF)(PO4)4(C2H10N2)217Synthesis, structure, and characterization of a new two-dimensional lead(II) vanadate, Ba3PbV4O1415Binuclear Fluoro-Bridged Zinc and Cadmium Complexes of a Schiff Base Expanded Porphyrin: Fluoride Abstraction from the Tetrafluoroborate Anion77Biosynthesis and biological activity of enniatins49Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5115(NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties88Cation−Anion Interactions and Polar Structures in the Solid State196Noncentrosymmetry in Mixed Metal Oxide-Fluorides, Can We Control It?0A rare multi-coordinate tellurite, NH4ATe4O9·2H2O (ARb or Cs): The occurrence of TeO3, TeO4, and TeO5 Polyhedra in the same material66Crown-templated assembling of the inorganic binuclear fluoro-containing anions in the system ZrO2/HfO2 (Nb2O5/Ta2O5)–HF–H2O-azacrown ether16Orientational disorder and phase transitions in crystals of (NH4)2NbOF517Disordering of the [NbOF5]2−complex anions in bis(glycinium) pentafluoridooxidoniobate(V) and bis(β-alaninium) pentafluoridooxidoniobate(V) dihydrate11Disorder in crystals of dioxofluorotungstates, (NH4)2WO2F4 and Rb2WO2F429A New Organically Templated Noncentrosymmetric Bismuth Chloride: Synthesis, Structure, and Characterization of [N(CH3)2H2][(CH3)2NH(CH2)2NH(CH3)2][BiCl6]7New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12125Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions46Molecular structure and DFT study of hydrothermally synthesized niobium oxide fluoride5Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)307New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra63Recent Developments in the Methods and Applications of the Bond Valence Model1246Synthesis, Structure, and Characterization of a Layered Mixed Metal Oxychloride, PbVO3Cl8Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl529Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates57Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl1446First-principles study of electronic structures and nonlinear optical properties of AMoO3(IO3) (A = Li, Rb and Cs) crystals13Thermal expansion, phase diagrams and barocaloric effects in (NH4)2NbOF525Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8Hydrothermal syntheses, crystal structures and characterizations of two new metal-fluorides based on niobium and tantalum19New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)295A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Cd1−xBix(Cd1+xIn1−x)VO6 (0 ≤ x ≤ 0.14): A New Polar Oxide with Second-Harmonic Generation22A new layered indium selenium oxychloride material: Synthesis, structure, and characterization of InSeO3Cl20Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates45A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System37Crystal structures of MnNbOF5 · 4H2O at 153 and 297 K4Vanadium fluoroarsenates—folding sheets into highly corrugated layers and crystalline arrays of large inorganic tubes5New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)43Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System267New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O887Synthesis, structure, ion-exchange and fluorescence of a novel two-dimensional niobium fluorophosphate with 4.8-net layer6[R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers34Intramolecular mobility and phase transitions in ammonium oxofluoroniobates (NH4)2NbOF5 and (NH4)3NbOF6, a NMR and DFT study20Hydrothermal synthesis, crystal structure and property of a barbell-like copper complex with {(μ-F)[(μ-O)2(NbF4)2]} as the handle bar4Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response507Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Synthesis, Structure, and Thermally Stable Luminescence of Eu2+-Doped Ba2Ln(BO3)2Cl (Ln = Y, Gd and Lu) Host Compounds315Centrosymmetric [N(CH3)4]2TiF6 vs. noncentrosymmetric polar [C(NH2)3]2TiF6: A hydrogen-bonding effect on the out-of-center distortion of TiF6 octahedra31A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement113A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222MgTeMoO6: A neutral layered material showing strong second-harmonic generation110PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environments37PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Syntheses, crystal structures and SHG properties of a series of polar alkali-metal molybdenum(vi) selenites based on strandberg-type [Mo5O15(SeO3)2]4− polyanion28UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Structure, growth and properties of a novel polar material, KSr4B3O921Orientational order of [VOF5]2− and [NbOF5]2− polar units in chains40Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures139Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks17Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)7Influence of the Cation Size on the Framework Structures and Space Group Centricities in AMo2O5(SeO3)2 (A = Sr, Pb, and Ba)93Syntheses, crystal structures and characterizations of new vanadium arsenites and arsenates4The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)8Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)450Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)28Inorganic Polar Blocks into Controlled Acentric Assemblies18Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Structure–Property Relationships in Solid Solutions of Noncentrosymmetric Aurivillius Phases, Bi4–xLaxTi3O12 (x = 0–0.75)33Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units81Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks26A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Chemistry of Polar Transition-Metal Oxides1Growth, optical and electrical properties of a nonlinear optical crystal NaBa4Al2B8O18Cl315Ln3GaS6 (Ln = Dy, Y): new infrared nonlinear optical materials with high laser induced damage thresholds75Solid-state synthesis, structure, second-harmonic generation, and luminescent properties of noncentrosymmetric BaSi7N10:Eu2+ phosphors17ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53Structure-Directing Self-Assembly, Structures and Characterization of Four d0-Transition Metal Oxide/Fluoride Compounds Constructed with Imidazole/1-Methylimidazole/1-Vinylimidazole and Copper(II)/Zinc(II)16Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO69Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Ba2YFeO5.5: A Ferromagnetic Pyroelectric Phase Prepared by Topochemical Oxidation.17New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles56New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76Bonding and Structure of Oxofluoroniobate-Based Glasses7AgNa(VO2F2)2: A Trioxovanadium Fluoride with Unconventional Electrochemical Properties22Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Pb2B3O5.5(OH)2 and [Pb3(B3O7)](NO3): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems57catena-Poly[bis(μ-2,2′-bipyridin-6-olato)-κ3N,N′:O;O:N,N′-dicopper(I,II) [[tetrafluoridoniobium(V)]-μ-oxido]]3Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model16Formation Principles for Templated Vanadium Selenite Oxalates22New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Noncentrosymmetric Cubic CsCdBO3 with Bichromophore23Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment22From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61Spin Frustration from cis-Edge or -Corner Sharing Metal-Centered Octahedra29From Solution to the Solid State: Control of Niobium Oxide–Fluoride [NbO x F y ] n − Species26Polar Alignment of Λ-Shaped Basic Building Units within Transition Metal Oxide Fluoride Materials15Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 619Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency101β-BaGa[B 4 O 8 (OH)](H 2 O) and Ba 4 Ga[B 10 O 18 (OH) 5 ](H 2 O): new barium galloborates featuring unusual [B 4 O 8 (OH)] 5− and [B 10 O 18 (OH) 5 ] 11− clusters26Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response360A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response57Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability46New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O21Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework37Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations9Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O833Formation Principles for Vanadium Selenites: The Role of pH on Product Composition12Designing the syntheses and photophysical simulations of noncentrosymmetric compounds17Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O823Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units55New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O813Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties79Series of SHG Materials Based on Lanthanide Borate–Acetate Mixed Anion Compounds39Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 525New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10Pb4(OH)4(BrO3)3(NO3): An Example of SHG Crystal in Metal Bromates Containing π-Conjugated Planar Triangle59A series of new silver selenites with d 0 -TM cations19K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18

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  1. Ag4V2O6F2: An Electrochemically Active and High Silver Density Phase

    Journal of the American Chemical Society · 2005-04-07

    Erin M. Sorensen, Heather K. Izumi, John T. Vaughey, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  2. Mixed-Metal Tellurites: Synthesis, Structure, and Characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16

    Inorganic Chemistry · 2005-05-01

    Kang Min Ok, P. Shiv Halasyamani

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  3. Ethylenediaminium niobium oxyfluoride

    Acta Crystallographica Section C Crystal Structure Communications · 2005-06-22

    Nicholas F. Stephens, Philip Lightfoot

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  4. Diaquabis(1,10-phenanthroline-κ2N,N′)zinc(II) pentafluorooxoniobate(V)

    Acta Crystallographica Section E Structure Reports Online · 2005-07-16

    Gang Zhu, Yu-Ying Liu, Gang Wang, Zong‐Xun Tang

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  5. Diaquabis(1,10-phenanthroline-κ2N,N′)cadmium(II) pentafluorooxoniobate(V)

    Acta Crystallographica Section E Structure Reports Online · 2005-09-28

    Gang Zhu, Zong‐Xun Tang

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  6. Evidence for Nonpolar Alignment of [NbOF5]2- Anions in Cd(pyridine)4NbOF5 Chains

    Crystal Growth & Design · 2005-10-29

    P. Guillory, Janet E. Kirsch, Heather K. Izumi, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  7. New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O

    Inorganic Chemistry · 2005-11-01

    Kang Min Ok, P. Shiv Halasyamani

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  8. Synthesis, structure, and characterization of a new one-dimensional tellurite phosphate, Ba2TeO(PO4)2

    Journal of Solid State Chemistry · 2006-02-25

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  9. Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties

    Chemistry of Materials · 2006-03-28

    Eun Ok Chi, Kang Min Ok, Yetta Porter, P. Shiv Halasyamani

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  10. Diaquabis(1,10-phenanthroline-κ2 N,N′)manganese(II) pentafluorooxoniobate(V)

    Acta Crystallographica Section E Structure Reports Online · 2006-04-11

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  11. Synthesis, structure and characterization of a new inorganic-organic hybrid complex (C3H5N2)2[Cd(C3H4N2)2Nb2O3F8]·2H2O

    Journal of Chemical Crystallography · 2006-06-26

    Gang Zhu, Xingling Xu, Zong‐Xun Tang

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  12. Metallacycles of Iron, Zinc, and Cadmium Assembled by Polytopic Bis(pyrazolyl)methane Ligands and Fluoride Abstraction from BF4-

    Inorganic Chemistry · 2006-11-08

    Daniel L. Reger, Russell P. Watson, J.R. Gardinier, Mark D. Smith, Perry J. Pellechia

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  13. Two Organically Templated Niobium and Zinconiobium Fluorophosphates: Low Temperature Hydrothermal Syntheses of NbOF(PO4)2(C2H10N2)2 and Zn3(NbOF)(PO4)4(C2H10N2)2

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  14. Synthesis, structure, and characterization of a new two-dimensional lead(II) vanadate, Ba3PbV4O14

    Solid State Sciences · 2007-03-22

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  15. Binuclear Fluoro-Bridged Zinc and Cadmium Complexes of a Schiff Base Expanded Porphyrin: Fluoride Abstraction from the Tetrafluoroborate Anion

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  16. Biosynthesis and biological activity of enniatins

    Die Pharmazie · 2007-08-01

    S Firáková, Bohumil Proksa, M. Šturdíková

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  17. Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5

    Chemistry of Materials · 2007-08-21

    T. Sivakumar, Hong Chang, Jaewook Baek, P. Shiv Halasyamani

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  18. (NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties

    Chemistry of Materials · 2007-10-09

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  19. Cation−Anion Interactions and Polar Structures in the Solid State

    Journal of the American Chemical Society · 2007-10-18

    Michael R. Marvel, Julien Lesage, Jaewook Baek, P. Shiv Halasyamani, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  20. Noncentrosymmetry in Mixed Metal Oxide-Fluorides, Can We Control It?

    MRS Proceedings · 2008-01-01

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  21. A rare multi-coordinate tellurite, NH4ATe4O9·2H2O (ARb or Cs): The occurrence of TeO3, TeO4, and TeO5 Polyhedra in the same material

    Journal of Solid State Chemistry · 2008-05-08

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  22. Crown-templated assembling of the inorganic binuclear fluoro-containing anions in the system ZrO2/HfO2 (Nb2O5/Ta2O5)–HF–H2O-azacrown ether

    Polyhedron · 2008-05-10

    Marina S. Fonarı, Victor Kravtsov, Yurii A. Simonov, Stepan S. Basok, Eduard V. Ganin, V.O. Gelmboldt, Kinga Suwinska, Janusz S. Lipkowski, Olga A. Alekseeva, Nina G. Furmanova

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  23. Orientational disorder and phase transitions in crystals of (NH4)2NbOF5

    Acta Crystallographica Section B Structural Science · 2008-09-05

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  24. Disordering of the [NbOF5]2−complex anions in bis(glycinium) pentafluoridooxidoniobate(V) and bis(β-alaninium) pentafluoridooxidoniobate(V) dihydrate

    Acta Crystallographica Section C Crystal Structure Communications · 2008-10-03

    Andrey V. Gerasimenko, M.A. Pushilin, R.L. Davidovich

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  25. Disorder in crystals of dioxofluorotungstates, (NH4)2WO2F4 and Rb2WO2F4

    Acta Crystallographica Section B Structural Science · 2008-11-13

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  26. A New Organically Templated Noncentrosymmetric Bismuth Chloride: Synthesis, Structure, and Characterization of [N(CH3)2H2][(CH3)2NH(CH2)2NH(CH3)2][BiCl6]

    Bulletin of the Korean Chemical Society · 2008-11-20

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  27. New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12

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    Hong Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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  28. Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions

    Zeitschrift für anorganische und allgemeine Chemie · 2009-04-08

    Michael R. Marvel, Rachelle Ann F. Pinlac, Julien Lesage, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  29. Molecular structure and DFT study of hydrothermally synthesized niobium oxide fluoride

    Journal of Molecular Structure · 2009-04-09

    Zhifeng Zhao, Baibin Zhou, Zhanhua Su, Jingxiang Zhao, Zhonghua Li

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  30. Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)

    Journal of the American Chemical Society · 2009-04-22

    Hong‐Young Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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  31. New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra

    Inorganic Chemistry · 2009-08-05

    Myung‐Ho Choi, Sang‐Hwan Kim, Hong‐Young Chang, P. Shiv Halasyamani, Kang Min Ok

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  32. Recent Developments in the Methods and Applications of the Bond Valence Model

    Chemical Reviews · 2009-09-03

    Ian David Brown

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  33. Synthesis, Structure, and Characterization of a Layered Mixed Metal Oxychloride, PbVO3Cl

    Bulletin of the Korean Chemical Society · 2009-09-20

    Vinna Jo

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  34. Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5

    Dalton Transactions · 2010-01-01

    Min Kyung Kim, Vinna Jo, Dong Woo Lee, Kang Min Ok

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  35. Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates

    Dalton Transactions · 2010-01-01

    Chuan‐Fu Sun, Ting Hu, Xiang Xu, Jiang‐Gao Mao

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  36. Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14

    Inorganic Chemistry · 2010-02-11

    Vinna Jo, Min Kyung Kim, Dong Woo Lee, Il‐Wun Shim, Kang Min Ok

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  37. First-principles study of electronic structures and nonlinear optical properties of AMoO3(IO3) (A = Li, Rb and Cs) crystals

    Journal of Physics Condensed Matter · 2010-03-29

    Chun‐Li Hu, Jiang‐Gao Mao

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  38. Thermal expansion, phase diagrams and barocaloric effects in (NH4)2NbOF5

    Journal of Physics Condensed Matter · 2010-04-15

    М. В. Горев, Evgeniy V. Bogdanov, Igor N. Flerov, Nataly Laptash

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  39. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

    Unknown journal · 2010-06-11

    P. Shiv Halasyamani

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  40. Hydrothermal syntheses, crystal structures and characterizations of two new metal-fluorides based on niobium and tantalum

    Inorganic Chemistry Communications · 2010-06-18

    Yuquan Feng, Zhaohui Meng, Qunzeng Huang, Dongfang Qiu, Hengzhen Shi

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  41. New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)2

    Inorganic Chemistry · 2010-06-29

    Min Kyung Kim, Sang‐Hwan Kim, Hong‐Young Chang, P. Shiv Halasyamani, Kang Min Ok

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  42. A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

    Inorganic Chemistry · 2010-07-07

    Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  43. Cd1−xBix(Cd1+xIn1−x)VO6 (0 ≤ x ≤ 0.14): A New Polar Oxide with Second-Harmonic Generation

    Chemistry of Materials · 2010-07-27

    Tao Yang, Junliang Sun, Jeongho Yeon, P. Shiv Halasyamani, Shiliang Huang, J. Hemberger, M. Greenblatt

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  44. A new layered indium selenium oxychloride material: Synthesis, structure, and characterization of InSeO3Cl

    Solid State Sciences · 2010-09-13

    Dong Woo Lee, Kang Min Ok

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  45. Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates

    Inorganic Chemistry · 2010-09-20

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  46. A Series of New Ternary and Quaternary Compounds in the LiI−GaIII−TeIV−O System

    Inorganic Chemistry · 2010-11-15

    Fang Kong, Xiang Xu, Jiang‐Gao Mao

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  47. Crystal structures of MnNbOF5 · 4H2O at 153 and 297 K

    Russian Journal of Inorganic Chemistry · 2010-12-01

    Andrey V. Gerasimenko, И. А. Ткаченко, Evgeniy B. Merkulov, Т. Ф. Антохина

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  48. Vanadium fluoroarsenates—folding sheets into highly corrugated layers and crystalline arrays of large inorganic tubes

    Chemical Communications · 2011-01-01

    Eleni Kotsapa, Mark T. Weller

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  49. New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)

    Crystals · 2011-03-18

    Rachelle Ann F. Pinlac, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  50. Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System

    Journal of the American Chemical Society · 2011-03-23

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

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