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RESEARCH PAPER · Journal of the American Chemical Society · 2007

Cation−Anion Interactions and Polar Structures in the Solid State

Michael R. Marvel, Julien Lesage, Jaewook Baek, P. Shiv Halasyamani, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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Cation−Anion Interactions and Polar Structures in the Solid StateOriginalNoncentrosymmetry in Mixed Metal Oxide-Fluorides, Can We Control It?0ChemInform Abstract: Cation—Anion Interactions and Polar Structures in the Solid State.0Two bimetallic tetranuclear three-blade propeller shaped complexes with helical water chains: Crystal structures, second-order nonlinear optical (NLO) properties and thermal decomposition mechanisms12Orientational disorder and phase transitions in crystals of (NH4)2NbOF517Synthetic Approaches for Noncentrosymmetric Molybdates59Disorder in crystals of dioxofluorotungstates, (NH4)2WO2F4 and Rb2WO2F429Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions46Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)307Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6112Cocrystallized Dinuclear−Mononuclear CuII3NaI and Double-Decker−Triple-Decker CuII5KI3 Complexes Derived from N,N′-Ethylenebis(3-ethoxysalicylaldimine)74A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra63Recent Developments in the Methods and Applications of the Bond Valence Model1246Syntheses and crystal structures of CuIIBiIII, CuIIBaIICuII, [CuIIPbII]2 and cocrystallized (U VI O 2 ) 2 .4Cu II complexes: structural diversity of the coordination compounds derived from N,N′-ethylenebis(3-ethoxysalicylaldiimine)61Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships148Noncentrosymmetry in New Templated Gallium Fluorophosphates34A unique example of a three component cocrystal of metal complexes64Syntheses, Crystal Structures and Mass Spectrometry of Mononuclear NiII Inclusion Product and Self‐Assembled [2 × 1+1 × 2] NiII3MII (M = Cu, Ni, Co, Fe or Mn) Cocrystals Derived from N,N′‐Ethylenebis(3‐ethoxysalicylaldimine)56Unprecedented coordination modes for PDC (pyridine-2,5-dicarboxylate) in polymorphic 3D heterobimetallic compounds α- and β-[MNa2(PDC)2(H2O)4], with M = Ni, Co11Cation Coordination Control of Anionic Group Alignment to Maximize SHG Effects in the BaMBO3F (M = Zn, Mg) Series128Microporosity, Optical Bandgap Sizes, and Photocatalytic Activity of M(I)-Nb(V) (M = Cu, Ag) Oxyfluoride Hybrids34Thermal expansion, phase diagrams and barocaloric effects in (NH4)2NbOF525Synthesis and characterization of new ammonium-containing niobium fluoro complexes of composition NH4NaNbF7 and NH4MNbOF5 (M = Li and Na)0Low-temperature synthesis and structural properties of ferroelectric K3WO3F3 elpasolite12Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8Alkali metal cation complexation and solvent interactions by robust chromium(III) fluoride complexes27A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Cd1−xBix(Cd1+xIn1−x)VO6 (0 ≤ x ≤ 0.14): A New Polar Oxide with Second-Harmonic Generation22Nearly Monodisperse Ferroelectric BaTiO3 Hollow Nanoparticles: Size-Related Solid Evacuation in Ostwald-Ripening-Induced Hollowing Process45Syntheses, crystal structures and magnetic properties of trinuclear and [3 × 1 + 1 × 2] pentanuclear complexes derived from a compartmental ligand: Role of solvent on nuclearity and number of components27Syntheses and crystal structures of dinuclear, trinuclear [2 × 1 + 1 × 1] and tetranuclear [2 × 1 + 1 × 2] copper( ii )–d 10 complexes (d 10 ⇒ Zn II , Cd II , Hg II and Ag I ) derived from N,N′-ethylenebis(3-ethoxysalicylaldimine)47A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)43Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)217[R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers34Intramolecular mobility and phase transitions in ammonium oxofluoroniobates (NH4)2NbOF5 and (NH4)3NbOF6, a NMR and DFT study20K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge673Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Stabilization of Noncondensed (AsIIIS3)3– Anions by Coordinating to [MnII(phen)]2+ Complex Cations: a Mixed-Valent Thioarsenate (III, V) {[Mn(phen)]3(AsVS4)(AsIIIS3)}n·nH2O Showing the Coexistence of Antiferromagnetic Order, Photoluminescence, and Nonlinear Optical Properties60Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response507Dipotassium sodium niobium dioxide tetrafluoride, K2NaNbO2F4, crystal structure and characterization1Synthesis and crystal structure of a new tetradecker complex: Tetra(μ4-N,N′-Ethylen-bis(3-Methoxysalicylideneamine)-bis(μ2-perchlorato-O,O′)-tetranickel(II)-tripotassium perchlorate0New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Na 1.5 Ag 1.5 MO 3 F 3 (M = Mo, W): An Ordered Oxyfluoride Derivative of the LiNbO 3 Structure36A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222Exploration on anion ordering, optical properties and electronic structure in K3WO3F3 elpasolite140UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Orientational order of [VOF5]2− and [NbOF5]2− polar units in chains40Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures139Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks17Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)7Synthesis, crystal structure and properties of a new strontium cadmium diborate5Ba2(BO3)1–x(CO3)xCl1+x: A Mixed Borate and Carbonate Chloride Crystallized from High-Temperature Solution37Pb4VBO8: Synthesis, Crystal Structure, and Properties5Octahedral Rotation‐Induced Ferroelectricity in Cation Ordered Perovskites345Synthesis, Structural, Magnetic, and Electronic Properties of Cubic CsMnMoO3F3 Oxyfluoride54Synthesis, crystal structure and properties of a new lead calcium diborate7Integration of first-principles methods and crystallographic database searches for new ferroelectrics: Strategies and explorations53Synthesis, growth, crystal structure and optical properties of BaBiBO49The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)8Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Polymorphism of KNaNbOF5 crystals10Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks26Integration of first-principles methods and crystallographic database searches for new ferroelectrics: Strategies and explorations0Dinuclear oxofluorometallates as a new structural type of d 0 transition metal oxofluoride compound7Pb2B5O9Cl: a chloride borate with second harmonic generation effect40Chemistry of Polar Transition-Metal Oxides1Diversity in supramolecular self-assembly through hydrogen-bonding interactions of non-coordinated aliphatic –OH group in a series of heterodinuclear CuIIM (M = NaI, ZnII, HgII, SmIII, BiIII, PbII and CdII)48The dimeric [V2O2F8]4− anion: Structural characterization of a magnetic basic-building-unit18Investigation into phase diagrams of the fluorine-oxygen system: Ferroelastic-antiferroelectric (NH4)2WO2F4-(NH4)2MoO2F46New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247Structural, Spectroscopic, and Electronic Properties of Cubic G0-Rb2KTiOF5 Oxyfluoride43Ba2YFeO5.5: A Ferromagnetic Pyroelectric Phase Prepared by Topochemical Oxidation.17Bonding and Structure of Oxofluoroniobate-Based Glasses7Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br20AgNa(VO2F2)2: A Trioxovanadium Fluoride with Unconventional Electrochemical Properties22Principles and Applications of Anion Order in Solid Oxynitrides91Structures of α-K3MoO3F3 and α-Rb3MoO3F3: Ferroelectricity from Anion Ordering and Noncooperative Octahedral Tilting31Crystal and local structure refinement in Ca 2 Al 3 O 6 F explored by X-ray diffraction and Raman spectroscopy45Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61Competing Cation–Anion Interactions and Noncentrosymmetry in Metal Oxide-Fluorides: A First-Principles Theoretical Study8Influence of the Molecular Groups Ordering on Structural Phase Transitions in (NH4)2WO2F4 Crystal10From Solution to the Solid State: Control of Niobium Oxide–Fluoride [NbO x F y ] n − Species26Polar Alignment of Λ-Shaped Basic Building Units within Transition Metal Oxide Fluoride Materials15Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge50Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–20Structural, spectroscopic, and thermophysical investigations of the oxyfluorides CsZnMoO3F3 and CsMnMoO3F3 with the pyrochlore structure3Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50How Lewis Acidity of the Cationic Framework Affects KNaNbOF5 Polymorphism19Anion Order-to-Disorder Transition in Layered Iron Oxyfluoride Sr2FeO3F Single Crystals28Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability46Substrate-induced anion rearrangement in epitaxial thin films of LaSrCoO 4−x H x26Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Designing the syntheses and photophysical simulations of noncentrosymmetric compounds17Anomalous second-harmonic generation response in SrBPO 5 and BaBPO 542Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units55Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752K5Mo4O14F: A Novel Fluorinated Polyoxomolybdate and Its Structural Stability7Syntheses and Structures of Homodinuclear (Na–Na) and Heterodinuclear (Cu–Na, Cu–K) Metal Complexes2Hydrothermal crystal growth, piezoelectricity, and triboluminescence of KNaNbOF512Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O1016Structural Modulation of Anionic Group Architectures by Cations to Optimize SHG Effects: A Facile Route to New NLO Materials in the ATCO3F (A = K, Rb; T = Zn, Cd) Series114Observation of Anion Order in Pb2Ti4O9F211Piezoelectric, Mechanical and Acoustic Properties of KNaNbOF5 from First-Principles Calculations6A series of new silver selenites with d 0 -TM cations19Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)11On the identification of oxygen and fluorine atoms in disordered inorganic oxyfluoride compounds8Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Directed Lifting of Inversion Symmetry in Ruddlesden–Popper Oxide–Fluorides: Toward Ferroelectric and Multiferroic Behavior57Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Assessing exchange-correlation functional performance for structure and property predictions of oxyfluoride compounds from first principles32Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials268Noncentrosymmetric Cubic Cyanurate K6Cd3(C3N3O3)4 Containing Isolated Planar π-Conjugated (C3N3O3)3– Groups59Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13Luminescent and optical properties of complex oxyfluoride crystals0RbSe 3 B 2 O 9 (OH) and CsSe 3 B 2 O 9 (OH): one dimensional boroselenite-based anionic frameworks with second harmonic generation properties15Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System91LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20A luminescence-optical spectroscopy study of Rb2KTiOF5 single crystals1Structural Diversity from Anion Order in Heteroanionic Materials53Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates BiMTeO6 (M = Al, Ga)21Making an order: the concerted alignment of [MOF5]2− (M = Nb and Ta) dipolar anions in one-dimensional coordination chains sustained by tris(3,4,5-trimethyl-1H-pyrazole)copper(II)2The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge17Host and defect-related luminescence in Rb2KTiOF5 oxyfluoride crystals irradiated by fast electrons0Y2(CO3)3·H2O and (NH4)2Ca2Y4(CO3)9·H2O: Partial Aliovalent Cation Substitution Enabling Evolution from Centrosymmetry to Noncentrosymmetry for Nonlinear Optical Response37M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides14Structural insights into three phosphates with distinct polyanionic configurations20Synthesis, crystal structures, second harmonic generation response and temperature phase transitions of two noncentrosymmetric Cu(II)-hybrid halides compounds: [(R)-C7H16N2][CuX4] (X = Cl or Br)24Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35Heteroanionic Materials by Design: Progress Toward Targeted Properties236Predicting the Structure Stability of Layered Heteroanionic Materials Exhibiting Anion Order16LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO398LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO337A solid-state chemist’s eye for the development of materials science in China5Computational Prediction of Ferro‐ and Piezoelectricity in Lead‐Free Oxyhydrides Ln 2 H 4 O (Ln = Y, La)4Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Synthesis, crystal structure and properties of a new noncentrosymmetric tetraoxidomolybdate(VI)3Ba(B 2 OF 3 (OH) 2 ) 2 with well-ordered OH/F anions and a unique B 2 OF 3 (OH) 2 dimer29Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides1Microscopic Insights into the Reconstructive Phase Transition of KNaNbOF5 with 19F NMR Spectroscopy8Synthesis, Structure, and Characterization of d0 Transition-Metal Iodate: BaTi(IO3)6·0.5H2O12Vanadoborates: cluster-based architectures, preparation and properties36From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]14

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  1. Noncentrosymmetry in Mixed Metal Oxide-Fluorides, Can We Control It?

    MRS Proceedings · 2008-01-01

    Rachelle Ann F. Pinlac, Michael R. Marvel, Julien Lesage, Kenneth Reinhard Poeppelmeier

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  2. ChemInform Abstract: Cation—Anion Interactions and Polar Structures in the Solid State.

    ChemInform · 2008-01-28

    Michael R. Marvel, Julien Lesage, Jaewook Baek, P. Shiv Halasyamani, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  3. Two bimetallic tetranuclear three-blade propeller shaped complexes with helical water chains: Crystal structures, second-order nonlinear optical (NLO) properties and thermal decomposition mechanisms

    Inorganic Chemistry Communications · 2008-04-08

    Wei‐Hua Yu, Xiaozu Wang, Yunxia Sui, Xiao‐Ming Ren, Qingjin Meng

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  4. Orientational disorder and phase transitions in crystals of (NH4)2NbOF5

    Acta Crystallographica Section B Structural Science · 2008-09-05

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  5. Synthetic Approaches for Noncentrosymmetric Molybdates

    Inorganic Chemistry · 2008-09-29

    Desmond J. Hubbard, Alexander R. Johnston, Hernan Sanchez Casalongue, Amy Narducci Sarjeant, Alexander J. Norquist

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  6. Disorder in crystals of dioxofluorotungstates, (NH4)2WO2F4 and Rb2WO2F4

    Acta Crystallographica Section B Structural Science · 2008-11-13

    Anatoly A. Udovenko, N. M. Laptash

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  7. Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions

    Zeitschrift für anorganische und allgemeine Chemie · 2009-04-08

    Michael R. Marvel, Rachelle Ann F. Pinlac, Julien Lesage, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  8. Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)

    Journal of the American Chemical Society · 2009-04-22

    Hong‐Young Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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  9. Growth, Structure, and Optical Properties of a Congruent Melting Oxyborate, Bi2ZnOB2O6

    Chemistry of Materials · 2009-05-21

    Feng Li, Xueling Hou, Shilie Pan, Xian Wang

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  10. Cocrystallized Dinuclear−Mononuclear CuII3NaI and Double-Decker−Triple-Decker CuII5KI3 Complexes Derived from N,N′-Ethylenebis(3-ethoxysalicylaldimine)

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  11. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

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    Sheng‐Ping Guo, Guo‐Cong Guo, Ming‐Sheng Wang, Jian‐Ping Zou, Gang Xu, Guojian Wang, Xifa Long, Jin‐Shun Huang

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  12. New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra

    Inorganic Chemistry · 2009-08-05

    Myung‐Ho Choi, Sang‐Hwan Kim, Hong‐Young Chang, P. Shiv Halasyamani, Kang Min Ok

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  13. Recent Developments in the Methods and Applications of the Bond Valence Model

    Chemical Reviews · 2009-09-03

    Ian David Brown

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  14. Syntheses and crystal structures of CuIIBiIII, CuIIBaIICuII, [CuIIPbII]2 and cocrystallized (U VI O 2 ) 2 .4Cu II complexes: structural diversity of the coordination compounds derived from N,N′-ethylenebis(3-ethoxysalicylaldiimine)

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    Susanta Hazra, Sujit Sasmal, Malabika Nayak, Hazel A. Sparkes, Judith A. K. Howard, Sasankasekhar Mohanta

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  15. Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships

    Chemistry of Materials · 2009-10-12

    Sang‐Hwan Kim, Jeongho Yeon, P. Shiv Halasyamani

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  16. Noncentrosymmetry in New Templated Gallium Fluorophosphates

    Inorganic Chemistry · 2009-10-28

    Sarah J. Choyke, Samuel M. Blau, A.A. Larner, Amy Narducci Sarjeant, Jeongho Yeon, P. Shiv Halasyamani, Alexander J. Norquist

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  17. A unique example of a three component cocrystal of metal complexes

    CrystEngComm · 2009-12-22

    Malabika Nayak, Arpita Jana, Μ. Fleck, Susanta Hazra, Sasankasekhar Mohanta

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  18. Syntheses, Crystal Structures and Mass Spectrometry of Mononuclear NiII Inclusion Product and Self‐Assembled [2 × 1+1 × 2] NiII3MII (M = Cu, Ni, Co, Fe or Mn) Cocrystals Derived from N,N′‐Ethylenebis(3‐ethoxysalicylaldimine)

    European Journal of Inorganic Chemistry · 2009-12-22

    Sohini Sarkar, Malabika Nayak, Μ. Fleck, Supriya Dutta, Ülrich Flörke, R. Koner, Sasankasekhar Mohanta

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  19. Unprecedented coordination modes for PDC (pyridine-2,5-dicarboxylate) in polymorphic 3D heterobimetallic compounds α- and β-[MNa2(PDC)2(H2O)4], with M = Ni, Co

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  20. Cation Coordination Control of Anionic Group Alignment to Maximize SHG Effects in the BaMBO3F (M = Zn, Mg) Series

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  21. Microporosity, Optical Bandgap Sizes, and Photocatalytic Activity of M(I)-Nb(V) (M = Cu, Ag) Oxyfluoride Hybrids

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  22. Thermal expansion, phase diagrams and barocaloric effects in (NH4)2NbOF5

    Journal of Physics Condensed Matter · 2010-04-15

    М. В. Горев, Evgeniy V. Bogdanov, Igor N. Flerov, Nataly Laptash

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  23. Synthesis and characterization of new ammonium-containing niobium fluoro complexes of composition NH4NaNbF7 and NH4MNbOF5 (M = Li and Na)

    Russian Journal of Inorganic Chemistry · 2010-05-01

    Т. Ф. Антохина, Natalia N. Savchenko, Л. Н. Игнатьева, T. A. Kaidalova

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  24. Low-temperature synthesis and structural properties of ferroelectric K3WO3F3 elpasolite

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    Victor V. Atuchin∥⊥, Tatiana A. Gavrilova, Valery G. Kesler, Мaxim S. Моlokeev, K. S. Aleksandrov

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  25. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

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  26. Alkali metal cation complexation and solvent interactions by robust chromium(III) fluoride complexes

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  27. A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

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  28. Cd1−xBix(Cd1+xIn1−x)VO6 (0 ≤ x ≤ 0.14): A New Polar Oxide with Second-Harmonic Generation

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    Tao Yang, Junliang Sun, Jeongho Yeon, P. Shiv Halasyamani, Shiliang Huang, J. Hemberger, M. Greenblatt

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  29. Nearly Monodisperse Ferroelectric BaTiO3 Hollow Nanoparticles: Size-Related Solid Evacuation in Ostwald-Ripening-Induced Hollowing Process

    Crystal Growth & Design · 2010-07-29

    Xuelin Tian, Juan Li, Kai Chen, Jian Wei Han, Shilie Pan, Yongjiang Wang, Xiaoyun Fan, Feng Li, Zhongxiang Zhou

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  30. Syntheses, crystal structures and magnetic properties of trinuclear and [3 × 1 + 1 × 2] pentanuclear complexes derived from a compartmental ligand: Role of solvent on nuclearity and number of components

    Inorganica Chimica Acta · 2010-09-01

    Arpita Jana, R. Koner, Malabika Nayak, Pascale Lemoine, Supriya Dutta, Meenakshi Ghosh, Sasankasekhar Mohanta

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  31. Syntheses and crystal structures of dinuclear, trinuclear [2 × 1 + 1 × 1] and tetranuclear [2 × 1 + 1 × 2] copper( ii )–d 10 complexes (d 10 ⇒ Zn II , Cd II , Hg II and Ag I ) derived from N,N′-ethylenebis(3-ethoxysalicylaldimine)

    CrystEngComm · 2010-09-06

    Malabika Nayak, Sohini Sarkar, Susanta Hazra, Hazel A. Sparkes, Judith A. K. Howard, Sasankasekhar Mohanta

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  32. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

    Journal of Materials Chemistry · 2011-01-01

    Yun Mo Yang, Shilie Pan, Xueling Hou, Chuanyi Wang, Kenneth Reinhard Poeppelmeier, Zhaohui Chen, Hongping Wu, Zhongxiang Zhou

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  33. New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)

    Crystals · 2011-03-18

    Rachelle Ann F. Pinlac, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  34. Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)2

    Journal of Alloys and Compounds · 2011-04-15

    Min Zhang, Shilie Pan, Jian Wei Han, Yun Mo Yang, Liang Cui, Zhongxiang Zhou

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  35. [R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers

    Journal of Solid State Chemistry · 2011-04-20

    Ethan C. Glor, Samuel M. Blau, Jeongho Yeon, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  36. Intramolecular mobility and phase transitions in ammonium oxofluoroniobates (NH4)2NbOF5 and (NH4)3NbOF6, a NMR and DFT study

    Journal of Fluorine Chemistry · 2011-04-22

    V. Ya. Kavun, Svyatoslav Petrovich Gabuda, S. G. Kozlova, И. А. Ткаченко, N. M. Laptash

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  37. K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

    Journal of the American Chemical Society · 2011-05-02

    Hongping Wu, Shilie Pan, Kenneth Reinhard Poeppelmeier, Hongyi Li, Dianzeng Jia, Zhaohui Chen, Xiaoyun Fan, Yun Mo Yang, James M. Rondinelli, Haosu Luo

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  38. Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)

    Inorganic Chemistry · 2011-05-10

    Sau Doan Nguyen, Sang‐Hwan Kim, P. Shiv Halasyamani

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  39. Stabilization of Noncondensed (AsIIIS3)3– Anions by Coordinating to [MnII(phen)]2+ Complex Cations: a Mixed-Valent Thioarsenate (III, V) {[Mn(phen)]3(AsVS4)(AsIIIS3)}n·nH2O Showing the Coexistence of Antiferromagnetic Order, Photoluminescence, and Nonlinear Optical Properties

    Inorganic Chemistry · 2011-05-20

    Guang‐Ning Liu, Xiao‐Ming Jiang, Mei‐Feng Wu, Guan‐E Wang, Guo‐Cong Guo, Jin‐Shun Huang

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  40. Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O9

    Crystal Growth & Design · 2011-06-13

    Weiguo Zhang, P. Shiv Halasyamani, Zeliang Gao, Shanpeng Wang, Jian Wang, Xutang Tao

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  41. BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

    Journal of the American Chemical Society · 2011-07-21

    Sau Doan Nguyen, Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  42. Dipotassium sodium niobium dioxide tetrafluoride, K2NaNbO2F4, crystal structure and characterization

    Journal of Physics and Chemistry of Solids · 2011-10-24

    Junjie Li, Shilie Pan, Xuelin Tian, Fangfang Zhang, Wenwu Zhao

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  43. Synthesis and crystal structure of a new tetradecker complex: Tetra(μ4-N,N′-Ethylen-bis(3-Methoxysalicylideneamine)-bis(μ2-perchlorato-O,O′)-tetranickel(II)-tripotassium perchlorate

    Russian Journal of Coordination Chemistry · 2011-12-01

    D. Zhang, Zhen Zhao

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  44. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  45. Na 1.5 Ag 1.5 MO 3 F 3 (M = Mo, W): An Ordered Oxyfluoride Derivative of the LiNbO 3 Structure

    Journal of the American Chemical Society · 2011-12-20

    Allyson M. Fry‐Petit, Harry A. Seibel, Indunil N. Lokuhewa, Patrick M. Woodward

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  46. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12

    Dalton Transactions · 2012-01-01

    Songjie Chen, Shilie Pan, Wenwu Zhao, Hongwei Yu, Hongping Wu, Zhihua Yang, Yun Mo Yang

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  47. Exploration on anion ordering, optical properties and electronic structure in K3WO3F3 elpasolite

    Journal of Solid State Chemistry · 2012-01-12

    Victor V. Atuchin∥⊥, L. I. Isaenko, Valery G. Kesler, Zheshuai Lin, Мaxim S. Моlokeev, Alexander Yèlisseyev, Sergey Alexandrovich Zhurkov

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  48. UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units

    Inorganic Chemistry · 2012-01-19

    Li Wang, Shilie Pan, Li‐Xian Chang, Jianyang Hu, Hongwei Yu

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  49. Orientational order of [VOF5]2− and [NbOF5]2− polar units in chains

    Journal of Solid State Chemistry · 2012-01-24

    Romain Gautier, Martin D. Donakowski, Kenneth Reinhard Poeppelmeier

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  50. Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)

    Inorganic Chemistry · 2012-02-01

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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