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RESEARCH PAPER · Chemistry of Materials · 2006

Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric Properties

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Na2Te3Mo3O16: A New Molybdenum Tellurite with Second-Harmonic Generating and Pyroelectric PropertiesOriginalNa2Te3Mo3O16: A New Molybdenum Tellurite with Second‐Harmonic Generating and Pyroelectric Properties.0New compounds and structures in the solid state2Polyoxomolybdenum(V/VI)−Sulfite Compounds: Synthesis, Structural, and Physical Studies26Biosynthesis and biological activity of enniatins49Deuteration Effect of Ferroelectricity and Permittivity on Homochiral Zinc Coordination Compound47Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5115(NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties88La4(Si5.2Ge2.8O18)(TeO3)4 and La2(Si6O13)(TeO3)2: Intergrowth of the lanthanum(III) tellurite layer with the XO4 (X=Si/Ge) tetrahedral layer20Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9125Explorations of New Types of Second‐Order Nonlinear Optical Materials in Cd(Zn)‐VV‐TeIV‐O Systems109Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr3(SeO3)(Se2O5)Cl2 and Sr4(Te3O8)Cl432SbF3: A new second-order nonlinear optical material62A rare multi-coordinate tellurite, NH4ATe4O9·2H2O (ARb or Cs): The occurrence of TeO3, TeO4, and TeO5 Polyhedra in the same material66ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations54Isotope Effect on SHG Response and Ferroelectric Properties of a Homochiral Zinc Coordination Compound Containing Tetrazole Ligand98Polar Hexagonal Tungsten Bronze-Type Oxides: KNbW2O9, RbNbW2O9, and KTaW2O973Structures and Properties of Functional Metal Selenites and Tellurites164Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties159Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties26Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb)265Elastic, dielectric, and piezoelectric properties of BaTeMo2O9 single crystal62Organic–inorganic hybrid based on the molybdenum tellurite5Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems46Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems62New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12125Two Gallium Antimony Sulfides Built on a Novel Heterometallic Cluster48Structure and Thermal Properties of the Nonlinear Optical Crystal BaTeMo2O965Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)306BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response331Prediction of acentric crystal structure of complex crystals by neural net analysis0A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Quaternary Tin(IV) Antimony(III) Sulfide Decorated with Lanthanum(III) Ethylenediamine Complexes: [La(en)4SbSnS5]2·0.5H2O37New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra63Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Lone electron-pair enhancement of SHG responses in eulytite-type compounds: A II 3 M III (PO 4 ) 3 (A = Pb, M = Bi; A = Ba, M = Bi, La)34Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems23New compounds and structures in the solid state1Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143A Strong Second-Harmonic Generation Material Cd4BiO(BO3)3 Originating from 3-Chromophore Asymmetric Structures295Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study241Synthesis and Characterization of New Open-Framework Vanadium Tellurite Featuring an Unprecedented (3,7)-Connected Network: K3[(VVO4)(VIVO)4(TeO3)4]·4H2O3First-principles study of electronic structures and nonlinear optical properties of AMoO3(IO3) (A = Li, Rb and Cs) crystals13Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43First‐Principles Studies on Novel Polar Oxide ZnSnO3; Pressure‐Induced Phase Transition and Electric Properties56Synthesis, micromorphology and structural properties of rubidium neodymium molybdate, RbNd(MoO4)20A Series of New Phases Containing Three Different Asymmetric Building Units55A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Top-Seeded Solution Crystal Growth and Functional Properties of a Polar Material—Na2TeW2O956Cd1−xBix(Cd1+xIn1−x)VO6 (0 ≤ x ≤ 0.14): A New Polar Oxide with Second-Harmonic Generation22(Ag2TeS3)2·A2S6 (A = Rb, Cs): Layers of Silver Thiotellurite Intergrown with Alkali-Metal Polysulfides28Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O998Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br91New Second-Order NLO Materials Based on Polymeric Borate Clusters and GeO4 Tetrahedra: A Combined Experimental and Theoretical Study69Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites34Syntheses, Crystal Structures, and Optical Properties of Indium Arsenic(III) Oxide Halides: In2(As2O5)Cl2 and In4(As2O5)(As3O7)Br314Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80[Ni(en)3][InSbS4]: A One‐Dimensional Polymeric Indium Thioantimonate with a Polar Structure25Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Centrosymmetric [N(CH3)4]2TiF6 vs. noncentrosymmetric polar [C(NH2)3]2TiF6: A hydrogen-bonding effect on the out-of-center distortion of TiF6 octahedra31New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry14Anisotropic thermal properties of the polar crystal Cs2TeMo3O1224A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O1641Exploration of New Second-Order Nonlinear Optical Compounds Containing Main Group Elements4MgTeMoO6: A neutral layered material showing strong second-harmonic generation110PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second order nonlinear properties of monoclinic single crystal BaTeMo2O936Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Structural Designs and Property Characterizations for Second-Harmonic Generation Materials1Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41Syntheses, crystal structures and SHG properties of a series of polar alkali-metal molybdenum(vi) selenites based on strandberg-type [Mo5O15(SeO3)2]4− polyanion28Top‐seeded growth, optical properties and theoretical studies of noncentrosymmetric Te2V2O914Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Investigation of the dielectric, elastic, and piezoelectric properties of Cs2TeMo3O12 crystals22Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks30Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units81CdB10O14(OH)4·H2O with an unprecedented decaborate fundamental building block1Synthesis, Band and Crystal Structures, and Optical Properties of the Ternary Compound Mg2Te3O814Sulfite Anions as Structure‐Directing Templates for the Engineering of Modular Polyoxometalates18A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Chemistry of Polar Transition-Metal Oxides1Nonlinear Optical Properties of Coordination and Organometallic Complexes28Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O836Synthesis, crystal growth, and characterization of the orthorhombic BaTeW2O9: a new polymorph of BaTeW2O925Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F42ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239Top-seeded solution growth and characterization of a novel nonlinear optical crystal MnTeMoO637Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247Crystal structure, growth and characterization of LiPbB9O15: A new congruent melting nonlinear optical crystal26Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94A new strontium antimonateIII Sr5Sb22O38: Synthesis, crystal structure and characterizations9Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+14Chiral and Noncentrosymmetric Metal–Organic Frameworks Featuring a 2D → 3D Parallel/Parallel Inclined Subpolycatenation27Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment22Effects of structure distortion on optical phonon properties of crystalline beta-BaTeMo2O9—A novel nonlinear optical material: Infrared and Raman spectra as well as first-principles calculations3Synthesis and characterization of Cd 4 YbO(BO 3 ) 3 – a congruent melting cadmium–ytterbium oxyborate with large nonlinear optical properties11Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–20Investigation of the second-order nonlinear optical properties of Cs2TeMo3O12 single crystal31Series of Lead Oxide Hydroxide Nitrates Obtained by Adjusting the pH Values of the Reaction Systems32Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Synthesis and Characterization of the New Strontium Borogermanate Sr3–x/2B2–xGe4+xO14 (x = 0.32)16Growth and characterization of nonlinear optical telluromolybdate CoTeMoO 6 single crystals17New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O21Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Lanthanum Lead Oxide Hydroxide Nitrates with a Nonlinear Optical Effect30Designing the syntheses and photophysical simulations of noncentrosymmetric compounds17An outstanding second-harmonic generation material BiB 2 O 4 F: exploiting the electron-withdrawing ability of fluorine92ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction61Assembly of noncentrosymmetric coordination polymers by the integration of acentric Ba( ii )/Sr( ii ) and Li( i ) coordination polyhedra8Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82Microcrystalline β-RbNd(MoO 4 ) 2 : spin polarizing DFT+U7Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30Sr 2 (OH) 3 NO 3 : the first nitrate as a deep UV nonlinear optical material with large SHG responses166Theoretical perspective of the lone pair activity influence on band gap and SHG response of lead borates24A Series of Noncentrosymmetric Antimony Sulfides Ln8Sb2S15 (Ln = La, Pr, Nd) – Syntheses, Crystal and Electronic Structures, and NLO Properties26Recent advances on second-order NLO materials based on metal iodates328Theoretical exploration to the cation effect on the second-order nonlinear optical properties of Strandberg-type polyoxometalates3Synthesis, Crystal Structure, and Properties of the Sodium Molybdate Fluoride Na3MoO4F5Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)24Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)232Effects of Te(IV) Oxo-Anion Incorporation into Thorium Molybdates and Tungstates14Ba2Cu2Te2P2O13: A new telluro-phosphate with S=1/2 Heisenberg chain6Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14169Pb4(OH)4(BrO3)3(NO3): An Example of SHG Crystal in Metal Bromates Containing π-Conjugated Planar Triangle59Synthesis and characterization of CsSrCO 3 F – a beryllium-free new deep-ultraviolet nonlinear optical material34A series of new silver selenites with d 0 -TM cations19Metal–organic frameworks as competitive materials for non-linear optics312Structural variety in zinc telluro-phosphates: syntheses, crystal structures and characterizations of Sr 2 Zn 3 Te 2 P 2 O 14 , Pb 2 Zn 3 Te 2 P 2 O 14 and Ba 2 Zn 2 TeP 2 O 1119Second order nonlinear optical properties of Cs_2TeW_3O_12 single crystal21Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain19New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33Rb2Na(NO3)3: A Congruently Melting UV-NLO Crystal with a Very Strong Second-Harmonic Generation Response71A review of the structural architecture of tellurium oxycompounds170BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129

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  1. Na2Te3Mo3O16: A New Molybdenum Tellurite with Second‐Harmonic Generating and Pyroelectric Properties.

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  2. New compounds and structures in the solid state

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  3. Polyoxomolybdenum(V/VI)−Sulfite Compounds: Synthesis, Structural, and Physical Studies

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    Nikolaos I. Kapakoglou, Betzios I. Panagiotis, Spiros E. Kazianis, Constantine E. Kosmidis, Chryssoula Drouza, Manolis J. Manos, Michael P. Sigalas, Anastasios D. Keramidas, Themistoklis A. Kabanos

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  4. Biosynthesis and biological activity of enniatins

    Die Pharmazie · 2007-08-01

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  5. Deuteration Effect of Ferroelectricity and Permittivity on Homochiral Zinc Coordination Compound

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  6. Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5

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  7. (NH4)2Te2WO8: A New Polar Oxide with Second-Harmonic Generating, Ferroelectric, and Pyroelectric Properties

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  8. La4(Si5.2Ge2.8O18)(TeO3)4 and La2(Si6O13)(TeO3)2: Intergrowth of the lanthanum(III) tellurite layer with the XO4 (X=Si/Ge) tetrahedral layer

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  9. Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9

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  10. Explorations of New Types of Second‐Order Nonlinear Optical Materials in Cd(Zn)‐VV‐TeIV‐O Systems

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  11. Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr3(SeO3)(Se2O5)Cl2 and Sr4(Te3O8)Cl4

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  12. SbF3: A new second-order nonlinear optical material

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  13. A rare multi-coordinate tellurite, NH4ATe4O9·2H2O (ARb or Cs): The occurrence of TeO3, TeO4, and TeO5 Polyhedra in the same material

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  14. ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations

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  15. Isotope Effect on SHG Response and Ferroelectric Properties of a Homochiral Zinc Coordination Compound Containing Tetrazole Ligand

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  16. Polar Hexagonal Tungsten Bronze-Type Oxides: KNbW2O9, RbNbW2O9, and KTaW2O9

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  17. Structures and Properties of Functional Metal Selenites and Tellurites

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  18. Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties

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  19. Three‐Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion‐Exchange Properties

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  20. Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb)

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  21. Elastic, dielectric, and piezoelectric properties of BaTeMo2O9 single crystal

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  22. Organic–inorganic hybrid based on the molybdenum tellurite

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  23. Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems

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  24. Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems

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  25. New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12

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  26. Two Gallium Antimony Sulfides Built on a Novel Heterometallic Cluster

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  27. Structure and Thermal Properties of the Nonlinear Optical Crystal BaTeMo2O9

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  28. Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)

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  29. BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response

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  30. Prediction of acentric crystal structure of complex crystals by neural net analysis

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  31. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

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  32. Quaternary Tin(IV) Antimony(III) Sulfide Decorated with Lanthanum(III) Ethylenediamine Complexes: [La(en)4SbSnS5]2·0.5H2O

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  33. New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra

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  34. Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites

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  35. Lone electron-pair enhancement of SHG responses in eulytite-type compounds: A II 3 M III (PO 4 ) 3 (A = Pb, M = Bi; A = Ba, M = Bi, La)

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  36. Explorations of new quaternary phases in the LnIII–VV(d0)–SeIV–O (Ln = Nd, Eu, Gd, Tb) systems

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  37. New compounds and structures in the solid state

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  38. Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates

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  45. First‐Principles Studies on Novel Polar Oxide ZnSnO3; Pressure‐Induced Phase Transition and Electric Properties

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    International Conference and Seminar on Micro/Nanotechnologies and Electron Devices · 2010-06-01

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  47. A Series of New Phases Containing Three Different Asymmetric Building Units

    Inorganic Chemistry · 2010-06-07

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  48. A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

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  49. Top-Seeded Solution Crystal Growth and Functional Properties of a Polar Material—Na2TeW2O9

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  50. Cd1−xBix(Cd1+xIn1−x)VO6 (0 ≤ x ≤ 0.14): A New Polar Oxide with Second-Harmonic Generation

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