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RESEARCH PAPER · Zeitschrift für anorganische und allgemeine Chemie · 2009

Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions

Michael R. Marvel, Rachelle Ann F. Pinlac, Julien Lesage, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride AnionsOriginalSyntheses and Physicochemical Properties of Low‐Melting Salts Based on VOF4– and MoOF5–, and the Molecular Geometries of the Dimeric (VOF4–)2 and Mo2O4F62– Anions24Low-temperature synthesis and structural properties of ferroelectric K3WO3F3 elpasolite12Alkali metal cation complexation and solvent interactions by robust chromium(III) fluoride complexes27Crystal Growth of Ag3MOxF6−x (M = V, x = 2; M = Mo, x = 3)30Multiferroic magnetoelectric fluorides: why are there so many magnetic ferroelectrics?129New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)43Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response507New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Exploration on anion ordering, optical properties and electronic structure in K3WO3F3 elpasolite140Orientational order of [VOF5]2− and [NbOF5]2− polar units in chains40The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures139Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks17The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)8Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Polymorphism of KNaNbOF5 crystals10Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks26Dinuclear oxofluorometallates as a new structural type of d 0 transition metal oxofluoride compound7Fluorides and Oxide-Fluorides of d-Transition Elements2New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Structural, Spectroscopic, and Electronic Properties of Cubic G0-Rb2KTiOF5 Oxyfluoride43Ba2YFeO5.5: A Ferromagnetic Pyroelectric Phase Prepared by Topochemical Oxidation.17Bonding and Structure of Oxofluoroniobate-Based Glasses7AgNa(VO2F2)2: A Trioxovanadium Fluoride with Unconventional Electrochemical Properties22Synthesis and Characterization of a Novel Sodium Transition Metal Oxyfluoride: NaMnMoO3F3·H2O5Crystal and local structure refinement in Ca 2 Al 3 O 6 F explored by X-ray diffraction and Raman spectroscopy45Synthesis and Magnetic Properties of β‐KVOF317Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-Fluorides173Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability46On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units55The role of inorganic acidity on templated vanadate composition and dimensionality4Observation of Anion Order in Pb2Ti4O9F211Anion order in perovskites: a group-theoretical analysis38M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides14Synthesis, crystal structures, second harmonic generation response and temperature phase transitions of two noncentrosymmetric Cu(II)-hybrid halides compounds: [(R)-C7H16N2][CuX4] (X = Cl or Br)24Templated vanadium tellurites: Identifying the effects of low density attractions on inorganic layer topology4Heteroanionic Materials by Design: Progress Toward Targeted Properties236Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)218Synthesis of NaMoO3F and Na5W3O9F5 with Morphological Controllability in Non-Aqueous Solvents15Order and Disorder: Toward the Thermodynamically Stable α-BaMoO2F4 from the Metastable Polymorph31A Novel Red-Emitting Na2NbOF5:Mn4+ Phosphor with Ultrahigh Color Purity for Warm White Lighting and Wide-Gamut Backlight Displays37Structural evolution of transition metal orthoborates (Zn3B2O6−Co3B2O6) with the Kotoite mineral structure: Synthesis, structure and properties13Low-Temperature Microwave-Assisted Hydrothermal Synthesis of Pb2Ti2O5.4F1.2 Photocatalyst for Improved H2 Evolution under Visible Light16Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size84

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  1. Syntheses and Physicochemical Properties of Low‐Melting Salts Based on VOF4– and MoOF5–, and the Molecular Geometries of the Dimeric (VOF4–)2 and Mo2O4F62– Anions

    European Journal of Inorganic Chemistry · 2010-01-19

    Takatsugu Kanatani, Kazuhiko Matsumoto, Rika Hagiwara

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  2. Low-temperature synthesis and structural properties of ferroelectric K3WO3F3 elpasolite

    Chemical Physics Letters · 2010-05-13

    Victor V. Atuchin∥⊥, Tatiana A. Gavrilova, Valery G. Kesler, Мaxim S. Моlokeev, K. S. Aleksandrov

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  3. Alkali metal cation complexation and solvent interactions by robust chromium(III) fluoride complexes

    Journal of Fluorine Chemistry · 2010-06-17

    Torben Birk, Magnus J. Magnussen, Stergios Piligkos, Høgni Weihe, A. Holten, Jesper Bendix

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  4. Crystal Growth of Ag3MOxF6−x (M = V, x = 2; M = Mo, x = 3)

    Crystal Growth & Design · 2010-09-30

    Julia M. Chamberlain, Thomas A. Albrecht, Julien Lesage, Frédéric Sauvage, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  5. Multiferroic magnetoelectric fluorides: why are there so many magnetic ferroelectrics?

    Journal of Physics Condensed Matter · 2011-03-01

    James Floyd Scott, R. Blinc

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  6. New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)

    Crystals · 2011-03-18

    Rachelle Ann F. Pinlac, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  7. Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)

    Inorganic Chemistry · 2011-05-10

    Sau Doan Nguyen, Sang‐Hwan Kim, P. Shiv Halasyamani

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  8. Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O9

    Crystal Growth & Design · 2011-06-13

    Weiguo Zhang, P. Shiv Halasyamani, Zeliang Gao, Shanpeng Wang, Jian Wang, Xutang Tao

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  9. BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

    Journal of the American Chemical Society · 2011-07-21

    Sau Doan Nguyen, Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  10. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  11. Exploration on anion ordering, optical properties and electronic structure in K3WO3F3 elpasolite

    Journal of Solid State Chemistry · 2012-01-12

    Victor V. Atuchin∥⊥, L. I. Isaenko, Valery G. Kesler, Zheshuai Lin, Мaxim S. Моlokeev, Alexander Yèlisseyev, Sergey Alexandrovich Zhurkov

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  12. Orientational order of [VOF5]2− and [NbOF5]2− polar units in chains

    Journal of Solid State Chemistry · 2012-01-24

    Romain Gautier, Martin D. Donakowski, Kenneth Reinhard Poeppelmeier

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  13. The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures

    Journal of the American Chemical Society · 2012-02-15

    Martin D. Donakowski, Romain Gautier, Jeongho Yeon, Donald T. Moore, Juan C. Nino, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  14. Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks

    Journal of Solid State Chemistry · 2012-02-21

    Matthew D. Smith, Samuel M. Blau, Kelvin B. Chang, T. Thao Tran, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  15. The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)

    Zeitschrift für anorganische und allgemeine Chemie · 2012-06-27

    Martin D. Donakowski, Anastasiya I. Vinokur, Kenneth Reinhard Poeppelmeier

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  16. Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)

    Inorganic Chemistry · 2012-08-23

    Sau Doan Nguyen, P. Shiv Halasyamani

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  17. Polymorphism of KNaNbOF5 crystals

    Journal of Structural Chemistry · 2012-09-01

    Alexander D. Vasiliev, N. M. Laptash

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  18. Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks

    Inorganic Chemistry · 2012-09-24

    Jacob H. Olshansky, T. Thao Tran, Kristen J. Hernandez, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  19. Dinuclear oxofluorometallates as a new structural type of d 0 transition metal oxofluoride compound

    Acta Crystallographica Section B Structural Science · 2012-11-16

    Anatoly A. Udovenko, N. M. Laptash

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  20. Fluorides and Oxide-Fluorides of d-Transition Elements

    Elsevier eBooks · 2013-01-01

    M. Leblanc, A. Tressaud

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  21. New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F3

    Inorganic Chemistry · 2013-02-08

    T. Thao Tran, P. Shiv Halasyamani

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  22. Structural, Spectroscopic, and Electronic Properties of Cubic G0-Rb2KTiOF5 Oxyfluoride

    The Journal of Physical Chemistry C · 2013-03-18

    Victor V. Atuchin∥⊥, L. I. Isaenko, Valery G. Kesler, Lei Kang, Zheshuai Lin, Мaxim S. Моlokeev, Alexander Yèlisseyev, Sergey Alexandrovich Zhurkov

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  23. Ba2YFeO5.5: A Ferromagnetic Pyroelectric Phase Prepared by Topochemical Oxidation.

    Chemistry of Materials · 2013-04-09

    Kun Luo, Roger D. Johnson, T. Thao Tran, P. Shiv Halasyamani, Paolo G. Radaelli, Michael A. Hayward

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  24. Bonding and Structure of Oxofluoroniobate-Based Glasses

    Inorganic Chemistry · 2013-04-30

    N. M. Laptash, Масленникова Ирина Григорьевна, A. B. Slobodyuk, V. Ya. Kavun, В. К. Гончарук

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  25. AgNa(VO2F2)2: A Trioxovanadium Fluoride with Unconventional Electrochemical Properties

    Journal of the American Chemical Society · 2013-06-24

    Martin D. Donakowski, Arno L. Görne, John T. Vaughey, Kenneth Reinhard Poeppelmeier

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  26. Synthesis and Characterization of a Novel Sodium Transition Metal Oxyfluoride: NaMnMoO3F3·H2O

    Inorganic Chemistry · 2013-08-09

    Jessica Nava-Avendaño, Carlos Frontera, José A. Ayllón, Judith Oró‐Solé, Premkumar Senguttuvan, M. Rosa Palacín

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  27. Crystal and local structure refinement in Ca 2 Al 3 O 6 F explored by X-ray diffraction and Raman spectroscopy

    Physical Chemistry Chemical Physics · 2013-11-05

    Zhiguo Xia, Мaxim S. Моlokeev, Aleksandr S. Oreshonkov, Victor V. Atuchin∥⊥, Ru‐Shi Liu, Cheng Dong

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  28. Synthesis and Magnetic Properties of β‐KVOF3

    Zeitschrift für anorganische und allgemeine Chemie · 2014-01-23

    Martin D. Donakowski, Hongcheng Lu, Romain Gautier, Rana Saha, Athinarayanan Sundaresan, Kenneth Reinhard Poeppelmeier

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  29. Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-Fluorides

    Chemical Reviews · 2014-08-19

    M. Leblanc, V. Maisonneuve, A. Tressaud

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  30. Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability

    Inorganic Chemistry · 2014-08-19

    Martin D. Donakowski, Romain Gautier, Hongcheng Lu, T. Thao Tran, Jacqueline Cantwell, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  31. On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units

    Inorganic Chemistry · 2015-01-22

    Romain Gautier, Régis Gautier, Kelvin B. Chang, Kenneth Reinhard Poeppelmeier

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  32. The role of inorganic acidity on templated vanadate composition and dimensionality

    Journal of Solid State Chemistry · 2015-08-06

    Anahita Nourmahnad, Malia B. Wenny, Mat­thias Zeller, Joshua Schrier, Alexander J. Norquist

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  33. Observation of Anion Order in Pb2Ti4O9F2

    Inorganic Chemistry · 2015-10-20

    Kengo Oka, Katsuyoshi Oh‐ishi

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  34. Anion order in perovskites: a group-theoretical analysis

    Acta Crystallographica Section A Foundations and Advances · 2016-01-28

    Mikhail V. Talanov, В. Б. Широков, В. М. Таланов

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  35. M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides

    CrystEngComm · 2019-01-01

    Fengguang You, Pifu Gong, Fei Liang, Xingxing Jiang, Heng Tu, Ying Zhao, Zhanggui Hu, Zheshuai Lin

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  36. Synthesis, crystal structures, second harmonic generation response and temperature phase transitions of two noncentrosymmetric Cu(II)-hybrid halides compounds: [(R)-C7H16N2][CuX4] (X = Cl or Br)

    Journal of Molecular Structure · 2019-01-10

    Fadhel Hajlaoui, Ines Ben Hadj Sadok, H. Alamri Aeshah, Nathalie Audebrand, Thierry Roisnel, Nabil Zouari

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  37. Templated vanadium tellurites: Identifying the effects of low density attractions on inorganic layer topology

    Journal of Solid State Chemistry · 2019-02-27

    Xiwen Jia, Jessica L. Dixon, Mat­thias Zeller, Joshua Schrier, Alexander J. Norquist

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  38. Heteroanionic Materials by Design: Progress Toward Targeted Properties

    Advanced Materials · 2019-03-12

    Jaye K. Harada, Nenian Charles, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  39. Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides

    Science China Materials · 2019-10-24

    Junben Huang, Siru Guo, Zhizhong Zhang, Zhihua Yang, Shilie Pan

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  40. Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)2

    Inorganic Chemistry · 2020-02-13

    Tingting Shi, Fangfang Zhang, Yahui Li, Le Gao, Zhihua Yang, Shilie Pan

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  41. Synthesis of NaMoO3F and Na5W3O9F5 with Morphological Controllability in Non-Aqueous Solvents

    Inorganic Chemistry · 2020-07-21

    Yusuke Asakura, Tomoyo Akahira, Makoto Kobayashi, Minoru Osada, Shu Yin

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  42. Order and Disorder: Toward the Thermodynamically Stable α-BaMoO2F4 from the Metastable Polymorph

    Chemistry of Materials · 2021-02-25

    Hongil Jo, Min Hyung Lee, Kang Min Ok

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  43. A Novel Red-Emitting Na2NbOF5:Mn4+ Phosphor with Ultrahigh Color Purity for Warm White Lighting and Wide-Gamut Backlight Displays

    Materials · 2021-09-15

    Jingshan Hou, Wenxiang Yin, Langping Dong, Yang Li, Yufeng Liu, Zhifu Liu, Guoying Zhao, Ganghua Zhang, Yongzheng Fang

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  44. Structural evolution of transition metal orthoborates (Zn3B2O6−Co3B2O6) with the Kotoite mineral structure: Synthesis, structure and properties

    Zeitschrift für anorganische und allgemeine Chemie · 2022-04-04

    Gurusamy Sivakumar, Srinivasan Natarajan

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  45. Low-Temperature Microwave-Assisted Hydrothermal Synthesis of Pb2Ti2O5.4F1.2 Photocatalyst for Improved H2 Evolution under Visible Light

    ACS Materials Letters · 2023-08-02

    Kenta Aihara, Ryusuke Mizuochi, Megumi Okazaki, Shunta Nishioka, Shuhei Yasuda, Toshiyuki Yokoi, Fumitaka Ishiwari, Akinori Saeki, Miki Inada, Kazuhiko Maeda

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  46. Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size

    Journal of the American Chemical Society · 2023-10-26

    Jia-Hang Wu, Chun‐Li Hu, Ting-Kun Jiang, Jiang‐Gao Mao, Fang Kong

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