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RESEARCH PAPER · Inorganic Chemistry · 2007

Binuclear Fluoro-Bridged Zinc and Cadmium Complexes of a Schiff Base Expanded Porphyrin: Fluoride Abstraction from the Tetrafluoroborate Anion

Elisa Tomat, Luciano Cuesta, Vincent M. Lynch, Jonathan L. Sessler

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Binuclear Fluoro-Bridged Zinc and Cadmium Complexes of a Schiff Base Expanded Porphyrin: Fluoride Abstraction from the Tetrafluoroborate AnionOriginalBinuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin23New Chromogenic and Fluorescent Probes for Anion Detection: Formation of a [2 + 2] Supramolecular Complex on Addition of Fluoride with Positive Homotropic Cooperativity50SCHIFF BASE MACROCYCLES: RELIABLE TEMPLATES FOR MULTINUCLEAR METALLOCAVITANDS35Dichlorido{2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II) monohydrate4{(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II)4Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate)1Dibromido[N-propyl-N′-(2-pyridylmethylidene)ethane-1,2-diamine]zinc(II)4Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II)1Social and Antisocial [3 + 3] Schiff Base Macrocycles with Isomeric Backbones26Dichlorido{2-[3-(dimethylammonio)propyliminomethyl]phenolato}zinc(II) hemihydrate5Anion receptor chemistry: highlights from 2007859A macrocyclic approach to transition metal and uranyl Pacman complexes103Chemical etching with tetrafluoroborate: a facile method for resizing of CdTe nanocrystals under mild conditions19SiF6 2 − anionic hydrogen-bonds in [Co(im)6] · (SiF6) · (im)2 and cis-[Cd2(bipy)2(H2O)4(μ-F)2] · SiF6 complexes4{4-Bromo-2-[2-(piperidin-1-ium-1yl)ethyliminomethyl]phenolato}diiodidozinc(II)1Diiodido[N′-(2-methoxybenzylidene)-N,N-dimethylethane-1,2-diamine]zinc(II)0{4-Bromo-2-[3-(diethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) methanol solvate4Diiodido{4-nitro-2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II)2Monofluoride Bridged, Binuclear Metallacycles of First Row Transition Metals Supported by Third Generation Bis(1-pyrazolyl)methane Ligands: Unusual Magnetic Properties44Spectroscopic and functional models for Hmd hydrogenase0Charge-Assisted Encapsulation of Two Chlorides by a Hexaprotonated Azamacrocycle24Anion Recognition and Sensing by a New Macrocyclic Dinuclear Copper(II) Complex: A Selective Receptor for Iodide60Synthesis and complexes of an N 4 Schiff-base macrocycle derived from 2,2′-iminobisbenzaldehyde29Expanded Porphyrins: Intriguing Structures, Electronic Properties, and Reactivities695Expandierte Porphyrine: überraschende Strukturen, elektronische Eigenschaften und Reaktivitäten231Encapsulation of a Magnesium Hydroxide Cubane by a Bowl-Shaped Polypyrrolic Schiff Base Macrocycle64Toward Functional Carboxylate-Bridged Diiron Protein Mimics: Achieving Structural Stability and Conformational Flexibility Using a Macrocylic Ligand Framework41Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer24Solvent control: dinuclear versus tetranuclear complexes of a bis-tetradentate pyrimidine-based ligand23The multifunctional roles of the ionic liquid [Bmim][BF4] in the creation of cadmium metal–organic frameworks37Acyclic and cyclic compartmental ligands: Recent results and perspectives186Basic apoptotic and necrotic cell death in human liver carcinoma (HepG 2 ) cells induced by synthetic azamacrocycle9Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template5Dinuclear Complexes Containing Linear M–F–M [M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)] Bridges: Trends in Structures, Antiferromagnetic Superexchange Interactions, and Spectroscopic Properties84Self-assembly of transition metal ion complexes of a hybrid pyrazine–terpyridine ligand17Di‐ and Tetranuclear Complexes of Bis‐Tetradentate Pyrimidine‐Based Ligands with All‐Methylene‐ Versus Mixed Methylene/Ethylene‐Linked Arms12Spectroscopic and mechanistic studies of dinuclear metallohydrolases and their biomimetic complexes78Synthesis, Structure, and Reactivity of a Terminal Organozinc Fluoride Compound: Hydrogen Bonding, Halogen Bonding, and Donor–Acceptor Interactions40Crystal Structure of a Dinuclear Co Complex with Doubly Bridged Fluoride and Peroxo Ligands: μ-fluoro μ-peroxo bis{tris(2-pyridylmethyl)amine} dicobalt(III) tris(tetrafluoroborate), [Co2(μ-F)(μ-O2)(tpa)2](BF4)32Mechanistic Studies of Cd(II) Complexes as Phosphoesterase and Metallo-β-lactamase Models0Second-sphere coordination in anion binding: Synthesis, characterization and X-ray structures of bis(diethylenetriamine)cobalt(III) complexes containing benzoates19Resistive Memory for Harsh Electronics: Immunity to Surface Effect and High Corrosion Resistance via Surface Modification39Preparation of extremely smooth and boron-fluorine co-doped TiO2 nanotube arrays with enhanced photoelectrochemical and photocatalytic performance51Beyond the Balz–Schiemann Reaction: The Utility of Tetrafluoroborates and Boron Trifluoride as Nucleophilic Fluoride Sources210Formation and characterization of a reactive chromium( v )–oxo complex: mechanistic insight into hydrogen-atom transfer reactions51Towards dipyrrins: oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes29Macrocyclic Platforms for the Construction of Tetranuclear Oxo and Hydroxo Zinc Clusters22A facile synthetic route to benzimidazolium salts bearing bulky aromatic N-substituents17Br 2 F 7 − and Br 3 F 10 − : peculiar anions showing μ 2 - and μ 3 -bridging F-atoms27Substituent effects of N4 Schiff base ligands on the formation of fluoride-bridged dicobalt( ii ) complexes via B–F abstraction: structures and magnetism28A Boron‐Fluorinated Tris(pyrazolyl)borate Ligand (FTp*) and Its Mono‐ and Dinuclear Copper Complexes [Cu(FTp*)2] and [Cu2(FTp*)2]: Synthesis, Structures, and DFT Calculations12Diiron(III)–μ‐Fluoro Bisporphyrins: Effect of Bridging Ligand on the Metal Spin State40Spontaneous Si–C bond cleavage in (Triphos Si )-nickel complexes20Dinuclear Metallacycles with Single M–X–M Bridges (X = Cl–, Br–; M = Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)): Strong Antiferromagnetic Superexchange Interactions25Synthesis and Characterization of a Binuclear Copper(II) Naphthoisoamethyrin Complex Displaying Weak Antiferromagnetic Coupling15Aromaticity control via modifications of a macrocyclic frame: 5,6-dimethoxyphenanthriporphyrin and 5,6-dioxophenanthriporphyrin28Novel 1D coordination polymers built from acyclic cryptate containing bis(1 H -1,2,4-triazole) ligands and featuring coordinated counteranions7Substituents drive ligand rearrangements, giving dinuclear rather than mononuclear complexes, and tune Co II/III redox potential2A tetranuclear fluorido-bridged iron compound: Fluoride abstraction from the tetrafluoridoborate anion7Organocopper(III) Phenanthriporphyrin—Exocyclic Transformations29Porphyrinoid f-Element Complexes30Selected polyazole based coordination polymers displaying functional properties8New benzothiazole based copper(II) hydrazone Schiff base complexes for selective and environmentally friendly oxidation of benzylic alcohols: The importance of the bimetallic species tuned by the choice of the counterion28Experimental and Theoretical Investigation of an SN2-type Pathway for Borate–Fluorine Bond Cleavage by Electron-Rich Late-Transition Metal Complexes8Design of a bifunctional alkoxy-NHC ligand for assembling tantalum-rhodium heterobimetallic molecular and silica-supported complexes0Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu2(dipyriamethyrin)(μ2-1,1-acetato)2]5Recent developments in metal dipyrrin complexes: Design, synthesis, and applications78A family of rhodium( i ) NHC chelates featuring O-containing tethers for catalytic tandem alkene isomerization–hydrosilylation22Self-assembly of a trigonal bipyramidal architecture with stabilisation of iron in three spin states4Fluoro-bridged dimanganese(III) porphyrin dimer: Effect of intermacrocyclic interactions in modulating metal spin state3Phenanthrene‐Embedded Carbaporphyrinoids and Related Systems: From Ligands to Cages and Molecular Switches24Organozinc Fluoride and Trifluoromethyl Compounds Supported by the Bis(2-pyridylthio)methyl Ligand6Binuclear complexes with single M-F-M bridge (M: Fe, Mn, and Cu): A critical analysis of the impact of fluoride for isoelectronic hydroxide substitution7Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF42Dabcyl as a Naked Eye Colorimetric Chemosensor for Palladium Detection in Aqueous Medium5Coordination of ε-Caprolactone to a Cationic Niobium(V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination–Insertion11C–F Bond Activation and C–H Bond Zincation of Fluoroarenes with Bis-Guanidinate Zinc Hydrides0

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  1. Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

    Chemical Communications · 2008-01-01

    Luciano Cuesta, Elisa Tomat, Vincent M. Lynch, Jonathan L. Sessler

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  2. New Chromogenic and Fluorescent Probes for Anion Detection: Formation of a [2 + 2] Supramolecular Complex on Addition of Fluoride with Positive Homotropic Cooperativity

    The Journal of Organic Chemistry · 2008-01-10

    Chan-Yu Chen, Tzu‐Pin Lin, Chine-Kun Chen, Su‐Ching Lin, Mei‐Chun Tseng, Yuh‐Sheng Wen, Shih‐Sheng Sun

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  3. SCHIFF BASE MACROCYCLES: RELIABLE TEMPLATES FOR MULTINUCLEAR METALLOCAVITANDS

    Comments on Inorganic Chemistry · 2008-04-26

    Peter D. Frischmann, Mark J. MacLachlan

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  4. Dichlorido{2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II) monohydrate

    Acta Crystallographica Section E Structure Reports Online · 2008-05-16

    Dongfang Zhang, Mei-Huan Zhou, Yuan Chang-ji

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  5. {(E)-2-[3-(Dimethylammonio)propyliminomethyl]phenolato}diiodidozinc(II)

    Acta Crystallographica Section E Structure Reports Online · 2008-07-30

    Xue-Wen Zhu, Xu-Zhao Yang

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  6. Bis{(E)-2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}nickel(II) bis(perchlorate)

    Acta Crystallographica Section E Structure Reports Online · 2008-07-30

    Xue-Wen Zhu, Xu-Zhao Yang

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  7. Dibromido[N-propyl-N′-(2-pyridylmethylidene)ethane-1,2-diamine]zinc(II)

    Acta Crystallographica Section E Structure Reports Online · 2008-07-30

    Xue-Wen Zhu, Xu-Zhao Yang

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  8. Dibromido{(E)-2-ethoxy-6-[3-(methylammonio)propyliminomethyl]phenolato}zinc(II)

    Acta Crystallographica Section E Structure Reports Online · 2008-07-30

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  9. Social and Antisocial [3 + 3] Schiff Base Macrocycles with Isomeric Backbones

    The Journal of Organic Chemistry · 2008-09-12

    Britta N. Boden, Joseph K.‐H. Hui, Mark J. MacLachlan

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  10. Dichlorido{2-[3-(dimethylammonio)propyliminomethyl]phenolato}zinc(II) hemihydrate

    Acta Crystallographica Section E Structure Reports Online · 2008-10-24

    Xue-Wen Zhu

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  11. Anion receptor chemistry: highlights from 2007

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  12. A macrocyclic approach to transition metal and uranyl Pacman complexes

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  13. Chemical etching with tetrafluoroborate: a facile method for resizing of CdTe nanocrystals under mild conditions

    Chemical Communications · 2009-01-01

    Jianbo Liu, Xiaohai Yang, Kemin Wang, Dong Wang, Pengfei Zhang

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  14. SiF6 2 − anionic hydrogen-bonds in [Co(im)6] · (SiF6) · (im)2 and cis-[Cd2(bipy)2(H2O)4(μ-F)2] · SiF6 complexes

    Journal of Coordination Chemistry · 2009-05-18

    Jing Wang, Fang‐Fang Jian, Xian Wang

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  15. {4-Bromo-2-[2-(piperidin-1-ium-1yl)ethyliminomethyl]phenolato}diiodidozinc(II)

    Acta Crystallographica Section E Structure Reports Online · 2009-09-18

    Xue-Wen Zhu, Zhi‐Gang Yin, Gang-Sen Li, Xu-Zhao Yang, Chun‐Xia Zhang

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  16. Diiodido[N′-(2-methoxybenzylidene)-N,N-dimethylethane-1,2-diamine]zinc(II)

    Acta Crystallographica Section E Structure Reports Online · 2009-09-18

    Xue-Wen Zhu, Zhi‐Gang Yin, Chun‐Xia Zhang, Xu-Zhao Yang, Gang-Sen Li

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  17. {4-Bromo-2-[3-(diethylammonio)propyliminomethyl]phenolato}diiodidozinc(II) methanol solvate

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  18. Diiodido{4-nitro-2-[2-(piperidin-1-yl)ethyliminomethyl]phenolato}zinc(II)

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    Xue-Wen Zhu, Xu-Zhao Yang, Chun‐Xia Zhang, Gang-Sen Li, Zhi‐Gang Yin

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  19. Monofluoride Bridged, Binuclear Metallacycles of First Row Transition Metals Supported by Third Generation Bis(1-pyrazolyl)methane Ligands: Unusual Magnetic Properties

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    Daniel L. Reger, Elizabeth A. Foley, Russell P. Watson, Perry J. Pellechia, Mark D. Smith, Fernande Grandjean, Gary J. Long

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  20. Spectroscopic and functional models for Hmd hydrogenase

    Illinois Digital Environment for Access to Learning and Scholarship (University of Illinois at Urbana-Champaign) · 2010-01-01

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  21. Charge-Assisted Encapsulation of Two Chlorides by a Hexaprotonated Azamacrocycle

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  22. Anion Recognition and Sensing by a New Macrocyclic Dinuclear Copper(II) Complex: A Selective Receptor for Iodide

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  23. Synthesis and complexes of an N 4 Schiff-base macrocycle derived from 2,2′-iminobisbenzaldehyde

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  24. Expanded Porphyrins: Intriguing Structures, Electronic Properties, and Reactivities

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  25. Expandierte Porphyrine: überraschende Strukturen, elektronische Eigenschaften und Reaktivitäten

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  26. Encapsulation of a Magnesium Hydroxide Cubane by a Bowl-Shaped Polypyrrolic Schiff Base Macrocycle

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  27. Toward Functional Carboxylate-Bridged Diiron Protein Mimics: Achieving Structural Stability and Conformational Flexibility Using a Macrocylic Ligand Framework

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  28. Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer

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  29. Solvent control: dinuclear versus tetranuclear complexes of a bis-tetradentate pyrimidine-based ligand

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  30. The multifunctional roles of the ionic liquid [Bmim][BF4] in the creation of cadmium metal–organic frameworks

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  31. Acyclic and cyclic compartmental ligands: Recent results and perspectives

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  32. Basic apoptotic and necrotic cell death in human liver carcinoma (HepG 2 ) cells induced by synthetic azamacrocycle

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  33. Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template

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  34. Dinuclear Complexes Containing Linear M–F–M [M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)] Bridges: Trends in Structures, Antiferromagnetic Superexchange Interactions, and Spectroscopic Properties

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  35. Self-assembly of transition metal ion complexes of a hybrid pyrazine–terpyridine ligand

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  36. Di‐ and Tetranuclear Complexes of Bis‐Tetradentate Pyrimidine‐Based Ligands with All‐Methylene‐ Versus Mixed Methylene/Ethylene‐Linked Arms

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  37. Spectroscopic and mechanistic studies of dinuclear metallohydrolases and their biomimetic complexes

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  38. Synthesis, Structure, and Reactivity of a Terminal Organozinc Fluoride Compound: Hydrogen Bonding, Halogen Bonding, and Donor–Acceptor Interactions

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  39. Crystal Structure of a Dinuclear Co Complex with Doubly Bridged Fluoride and Peroxo Ligands: μ-fluoro μ-peroxo bis{tris(2-pyridylmethyl)amine} dicobalt(III) tris(tetrafluoroborate), [Co2(μ-F)(μ-O2)(tpa)2](BF4)3

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  40. Mechanistic Studies of Cd(II) Complexes as Phosphoesterase and Metallo-β-lactamase Models

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  41. Second-sphere coordination in anion binding: Synthesis, characterization and X-ray structures of bis(diethylenetriamine)cobalt(III) complexes containing benzoates

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  42. Resistive Memory for Harsh Electronics: Immunity to Surface Effect and High Corrosion Resistance via Surface Modification

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    Teng-Han Huang, Po‐Kang Yang, Der‐Hsien Lien, Chen‐Fang Kang, Meng‐Lin Tsai, Yu‐Lun Chueh, Jr‐Hau He

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  43. Preparation of extremely smooth and boron-fluorine co-doped TiO2 nanotube arrays with enhanced photoelectrochemical and photocatalytic performance

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  44. Beyond the Balz–Schiemann Reaction: The Utility of Tetrafluoroborates and Boron Trifluoride as Nucleophilic Fluoride Sources

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  45. Formation and characterization of a reactive chromium( v )–oxo complex: mechanistic insight into hydrogen-atom transfer reactions

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  46. Towards dipyrrins: oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

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  47. Macrocyclic Platforms for the Construction of Tetranuclear Oxo and Hydroxo Zinc Clusters

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  48. A facile synthetic route to benzimidazolium salts bearing bulky aromatic N-substituents

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  49. Br 2 F 7 − and Br 3 F 10 − : peculiar anions showing μ 2 - and μ 3 -bridging F-atoms

    Chemical Communications · 2016-01-01

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  50. Substituent effects of N4 Schiff base ligands on the formation of fluoride-bridged dicobalt( ii ) complexes via B–F abstraction: structures and magnetism

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