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RESEARCH PAPER · Chem · 2021

Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants

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Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactantsOriginalPolyolefin recycling by C–C bond alumination5Breaking C–C Bonds via Electrochemically Mediated Hydrogen Atom Transfer Reactions1Active Sites in a Heterogeneous Organometallic Catalyst for the Polymerization of Ethylene37Scalable Synthesis of Pt/SrTiO3 Hydrogenolysis Catalysts in Pursuit of Manufacturing-Relevant Waste Plastic Solutions44Electrochemical Activation of C−C Bonds through Mediated Hydrogen Atom Transfer Reactions63Determining the Three-Dimensional Structures of Silica-Supported Metal Complexes from the Ground Up22Expanding plastics recycling technologies: chemical aspects, technology status and challenges610The coordination chemistry of oxide and nanocarbon materials10From trash to treasure: Chemical recycling and upcycling of commodity plastic waste to fuels, high-valued chemicals and advanced materials269Environment-friendly deoxygenation of non-edible Ceiba oil to liquid hydrocarbon biofuel: process parameters and optimization study6Size-Controlled Nanoparticles Embedded in a Mesoporous Architecture Leading to Efficient and Selective Hydrogenolysis of Polyolefins168Catalytic carbon and hydrogen cycles in plastics chemistry78A High‐Throughput Approach to Repurposing Olefin Polymerization Catalysts for Polymer Upcycling32A High‐Throughput Approach to Repurposing Olefin Polymerization Catalysts for Polymer Upcycling0Reactions of Triisobutylaluminum with Unbridged or Bridged Group IV Metallocene Dichlorides13Isolation of an Elusive Phosphametallacyclobutadiene and Its Role in Reversible Carbon−Carbon Bond Cleavage3Isolation of an Elusive Phosphametallacyclobutadiene and Its Role in Reversible Carbon−Carbon Bond Cleavage9Interlocking degradation of vinyl polymers via main‐chain CC bonds scission by introducing pendant‐responsive comonomers37Plastic Waste Valorization by Leveraging Multidisciplinary Catalytic Technologies169Polyolefin Innovations toward Circularity and Sustainable Alternatives96INTERFACES. A program for determining the 3D structures of surfaces sites using NMR data18A unified view on catalytic conversion of biomass and waste plastics584Structure-activity relationship in hydrogenolysis of polyolefins over Ru/support catalysts139Upcycling plastic waste into high value-added chemicals under mild conditions1Enhanced Production of Liquid Alkanes from Waste Polyethylene via the Electronic Effect‐Favored Csecondary−Csecondary Bond Cleavage42Biosurfactants' production with substrates from the sugar industry – environmental, cost, market, and social aspects16Double-resonance 17 O NMR experiments reveal unique configurational information for surface organometallic complexes12Effects of surface acidity on the structure of organometallics supported on oxide surfaces21Mechanistic insights into the conversion of polyalcohols over Brønsted acid sites4Aging dependent plastic bag derived-microplastics as a vector of metals in lake water8Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane22Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysis176Cationic Tantalum Hydrides Catalyze Hydrogenolysis and Alkane Metathesis Reactions of Paraffins and Polyethylene38A Facile, One-pot, and Green Method for Synthesis of 2-Aryl-3-(Phenylamino)Dihydroquinazolin-4(1 H )-One Derivatives Using Sodium Lauryl Sulfate (SLS) in Aqueous Media at the Room Temperature6Recent Advances in Catalytic Chemical Recycling of Polyolefins104Sustainable catalytic strategies for the transformation of plastic wastes into valued products53Mass transfer in catalytic depolymerization: External effectiveness factors and serendipitous processivity in stagnant and stirred melts31Mechanistic Insights into Processive Polyethylene Hydrogenolysis throughIn SituNMR25Sustainable developments in polyolefin chemistry: Progress, challenges, and outlook204Upcycling of polyethylenes by catalysis0Polypropylene Degradation Catalyzed by Tantalum Hydrides Supported on Sulfated Alumina23Chemical upcycling of polyethylene, polypropylene, and mixtures to high-value surfactants349Hydroformylation of pyrolysis oils to aldehydes and alcohols from polyolefin waste195A Supported Ziegler-Type Organohafnium Site Metabolizes Polypropylene8Copolymerization of ethylene and isoprene via silicon bridge metallocene [rac-Me2Si(2-Me-4-Ph-Ind)2ZrCl2] catalyst: A new way to control the composition and microstructure of copolymers17Probing the Nature of Surface Hydrides by Deuterium Quadrupolar Parameters: A Case Study on Silica‐Supported Zirconium Hydrides1Investigation of the effect of alumina porous media on the polyethylene waste pyrolysis with continuous feed18Modern mechanistic approaches for the depolymerization of commodity plastics via organometallic catalysis0Catalytic conversion of mixed polyolefins under mild atmospheric pressure48Emerging green approaches for valorization of plastics with saturated carbon backbones42Circular olefin copolymers made de novo from ethylene and α-olefins83Supported Platinum Nanoparticles Catalyzed Carbon–Carbon Bond Cleavage of Polyolefins: Role of the Oxide Support Acidity27The Overlooked Potential of Sulfated Zirconia: Reexamining Solid Superacidity Toward the Controlled Depolymerization of Polyolefins11Progress and Challenges in Polystyrene Recycling and Upcycling87Cu MOF-biocarbon functional catalysts as adsorbent for oxygen-linked carbon capture via thermo-catalytic pyrolysis: A low-carbon fuel synthesis strategy8Catalytic Upcycling of Polyolefins316Selective Upcycling of Polyolefins into High-Value Nitrogenated Chemicals80One-pot catalytic conversion of polyethylene wastes to gasoline through a dual-catalyst system41Chain-length-controllable upcycling of polyolefins to sulfate detergents41Sustainable base-mediated chemical upcycling of poly (propylene carbonate) to β-hydroxy sulfides and oxides1Anionic Surfactants from Reactive Separation of Hydrocarbons Derived from Polyethylene Upcycling8Upcycling of Waste Plastics into Value-Added Chemicals6Industrially Adaptable Way for Upcycling of Mixed i PP and PE via In Situ Compatibilization5Valorization of food processing waste byproducts for essential oil production and their application in food system202 H Quadrupolar Coupling Constant: A Spectroscopic Ruler for Transition Metal–Hydride Bond Distances in Molecular and Surface Sites1A Broad-Spectrum Catalyst for Aliphatic Polymer Breakdown4Surface Protected Organozirconium Catalyzes C─H Alumination of Saturated Hydrocarbons0Surface Protected Organozirconium Catalyzes C─H Alumination of Saturated Hydrocarbons0Review of EOR-based techniques for enhancing sweep efficiency in carbon geo-storage15Circular economy strategies for converting waste plastics into surfactants6Functionalizations of C─H and C═C Bonds in Polyolefins Catalyzed by Transition‐Metal Complexes14Kinetics of Carboxylic Acids Formation During Polypropylene Thermooxidation in Water Saturated with Pressurized Oxygen4Fractionated degradation and valorization of polypropylene waste into sulfonate surfactants2Breaking C–C (sp 3 –sp 3 ) σ bonds in 1,4-diazabicyclo[2.2.2]octane (DABCO) by oxidation with antimony pentachloride0Carbon–carbon bond cleavage for lignin and plastics deconstruction0Recent Advances in Earth-Abundant Metal-Catalyzed Oxidative Degradation of Polyolefins0Suppressing Hydrogen Transfer and Aromatization Reactions Enables Efficient Photothermal Recycling of Polyethylene into Platform Olefins5Recycling of polyolefins using recycled PVC under sunlight7Cleavage Alkylation Coupling with Versatile Amide-Based Eutectic Catalytic Systems0Group 4 Metallocenes Supported on Sulfated Zirconium Oxide Catalyze Benzene C–H Borylation0Recent advances in the directed degradation of polyolefins into oligomers0

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  4. Scalable Synthesis of Pt/SrTiO3 Hydrogenolysis Catalysts in Pursuit of Manufacturing-Relevant Waste Plastic Solutions

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  10. Environment-friendly deoxygenation of non-edible Ceiba oil to liquid hydrocarbon biofuel: process parameters and optimization study

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  11. Size-Controlled Nanoparticles Embedded in a Mesoporous Architecture Leading to Efficient and Selective Hydrogenolysis of Polyolefins

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  14. A High‐Throughput Approach to Repurposing Olefin Polymerization Catalysts for Polymer Upcycling

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  15. Reactions of Triisobutylaluminum with Unbridged or Bridged Group IV Metallocene Dichlorides

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  16. Isolation of an Elusive Phosphametallacyclobutadiene and Its Role in Reversible Carbon−Carbon Bond Cleavage

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  18. Interlocking degradation of vinyl polymers via main‐chain CC bonds scission by introducing pendant‐responsive comonomers

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  19. Plastic Waste Valorization by Leveraging Multidisciplinary Catalytic Technologies

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  20. Polyolefin Innovations toward Circularity and Sustainable Alternatives

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  21. INTERFACES. A program for determining the 3D structures of surfaces sites using NMR data

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  22. A unified view on catalytic conversion of biomass and waste plastics

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  23. Structure-activity relationship in hydrogenolysis of polyolefins over Ru/support catalysts

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  48. Modern mechanistic approaches for the depolymerization of commodity plastics via organometallic catalysis

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  49. Catalytic conversion of mixed polyolefins under mild atmospheric pressure

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