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RESEARCH PAPER · Chemistry of Materials · 2020

Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution

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Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial SubstitutionOriginalSelenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization20Synthesis, crystal structures and optical properties of open-framework gallium phosphates: NaGa3F4(PO4)2(H2O)2 and AGa2P2O7(OH)3(H2O) (A = K, Rb)1AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses63Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation34Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36A melamine-based organic–inorganic hybrid material revealing excellent optical performance and moderate thermal stability75Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization28Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence18In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O5Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution26UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate196UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate28CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation47Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses5Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo 2 O 8 F149From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence53Complex coordinated functional groups: A great genes for nonlinear optical materials64Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds36Wide bandgaps and strong SHG responses of hetero-oxyfluorides by dual-fluorination-directed bandgap engineering28Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1SrZnGeS 4 : A Dual‐Waveband Nonlinear Optical Material with a Transparency Spanning UV/Vis and Far‐IR Spectral Regions88SrZnGeS4: A Dual‐Waveband Nonlinear Optical Material with a Transparency Spanning UV/Vis and Far‐IR Spectral Regions12From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency21Small Changes, Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B‐Site26The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 485The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)47Polytypism of Ln(SeO 3 )(HSeO 3 )·2H 2 O compounds: synthesis and crystal structure of the first monoclinic modification of Nd(SeO 3 )(HSeO 3 )·2H 2 O, DFT calculations and order/disorder description6Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions15A survey of stereoactive oxysalts for linear and nonlinear optical applications40Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds22Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)31Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions25A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation41Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction26Raman Spectroscopy, Physical Parameters and γ-Ray Shielding Competence of Newly Lu3+ Ions Doped Borosilicate Glasses15The isotypic series of tetragonal lanthanoid(III) fluoride oxoarsenates(III) Ln 5F3[AsO3]4 (Ln = Eu–Lu)3Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family23Lutetium barium tellurite silicate glass samples doped with Fe2O3: Fabrication, physical, structure, and radiation attenuation capacity4The effect of lutetium oxide (Lu2O3) substitution on the structural, optical, and radiation shielding performance of borate barium zinc sodium glasses1The crystal chemistry and topology of modular structures. I. Selenites of rare-earth elements5Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3The cerium(III) fluoride oxoselenate(IV) CeF[SeO 3 ]0A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Polymerization-enhanced optical anisotropy in selenites: a trimeric [H 2 Se 3 O 7 ] motif delivering large UV birefringence0DFT Insight Into Physical Properties of Halide Ions Replacements in Oxo‐Selenate Halide Compounds for Photovoltaic Application4Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials1The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap2Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0Synthesis, Crystal Structure, and Properties of New Layered Rare-Earth Selenites Ln(HSeO3)(SeO3)·2H2O (Ln = Yb, Dy, Eu)0

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  1. Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization

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  2. Synthesis, crystal structures and optical properties of open-framework gallium phosphates: NaGa3F4(PO4)2(H2O)2 and AGa2P2O7(OH)3(H2O) (A = K, Rb)

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  3. AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses

    Chemistry of Materials · 2020-06-23

    Chao Wu, Xingxing Jiang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  4. Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution

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  5. Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation

    ACS Applied Materials & Interfaces · 2020-10-22

    Lin Lin, Xingxing Jiang, Chao Wu, Longhua Li, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  6. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

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  7. A melamine-based organic–inorganic hybrid material revealing excellent optical performance and moderate thermal stability

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  8. Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization

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  9. Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence

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  10. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

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  11. Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap

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  12. Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

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  13. Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O

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  14. Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution

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  15. UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate

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  16. UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate

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  17. CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation

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  18. Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses

    Crystal Growth & Design · 2021-07-22

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  19. Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo 2 O 8 F

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  20. From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence

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  21. Complex coordinated functional groups: A great genes for nonlinear optical materials

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  22. Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds

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  23. Wide bandgaps and strong SHG responses of hetero-oxyfluorides by dual-fluorination-directed bandgap engineering

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  27. From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency

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  28. Small Changes, Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B‐Site

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  29. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 4

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  30. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)4

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  31. Polytypism of Ln(SeO 3 )(HSeO 3 )·2H 2 O compounds: synthesis and crystal structure of the first monoclinic modification of Nd(SeO 3 )(HSeO 3 )·2H 2 O, DFT calculations and order/disorder description

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  32. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

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  33. A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions

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  34. A survey of stereoactive oxysalts for linear and nonlinear optical applications

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  35. Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds

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  36. Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)

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  37. Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions

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  38. A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

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  42. The isotypic series of tetragonal lanthanoid(III) fluoride oxoarsenates(III) Ln 5F3[AsO3]4 (Ln = Eu–Lu)

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  43. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

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  44. RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps

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  45. Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family

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  46. Lutetium barium tellurite silicate glass samples doped with Fe2O3: Fabrication, physical, structure, and radiation attenuation capacity

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  47. The effect of lutetium oxide (Lu2O3) substitution on the structural, optical, and radiation shielding performance of borate barium zinc sodium glasses

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  48. The crystal chemistry and topology of modular structures. I. Selenites of rare-earth elements

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  49. Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials

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  50. The cerium(III) fluoride oxoselenate(IV) CeF[SeO 3 ]

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