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RESEARCH PAPER · Journal of Structural Chemistry · 2023

Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)

Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, D. А. Banaru, Sergey N. Volkov, Д. В. Дейнеко, Alexey N. Kuznetsov∥, Рамиза Кераровна Расцветаева, Н. В. Чуканов, B. B. Shkurskii, N. A. Yamnova

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Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)OriginalPreparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families17Spectroscopic characterization of extra‐framework hydrated proton complexes with the extremely strong hydrogen bonds in microporous silicate minerals13The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates8Hydroxylbenyacarite, (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10⋅4H2O, a new paulkerrite-group mineral, from the El Criollo mine, Cordoba Province, Argentina2Mutual correlations of complexity indices of the crystal structure for the series of mercury-containing minerals16Stoichiometry and topological features of triple molybdates ABC(MoO4) with the heteropolyhedral open MT-frameworks: Synthesis, crystal structure of Rb5{Hf1.5Co0.5(MoO4)6}, and comparative crystal chemistry8Hafnium Carbide: Prediction of Crystalline Structures and Investigation of Mechanical Properties11Lobanovite from the Koashva Mountain in the Kibiny Massif (Kola Peninsula): crystal-chemical features, IR-spectroscopy and mineral assemblage0Refinement of the crystal structure of christofschäferite-(Ce) and the modular aspect of the chevkinite polysomatic series with the general formula of {A4B(T2O7)2}{C2D2O8}m (m = 1, 2)4Crystal Chemistry of Minerals with Spinel Modules and New Data on the Symmetry, Structure, and Cation Distribution Features in Tashelgite, CaMgFe2+Al9O16(OH)2Structural Features of Hydrated Representatives of the Labuntsovite Group: Refinement of Crystal Structures of Intermediate Members of the Tsepinite-Na–“Tsepinite-Ba”–Tsepinite-K Solid Solution4Synthesis, crystal and electronic structures of two novel tunnel bismuth oxychlorides Bi18O22Cl8.5(BO3)0.5 and Bi18O22Cl8Se2Synthesis and Crystal Structure of a New Non-Centrosymmetrical Layered Barium Iodide-Thiocyanate Tetrahydrate Ba(SCN)I·4H2O03Pb 8 O 7 I 2 ·2CsI: the salt-inclusion strategy enriches the structural chemistry in lead oxyhalides1Structural Family of the CaMg[B2O5] Kurchatovite: Structure Features, Polytypical Complexity, DFT Analysis, and Comparative Crystal Chemistry of Divalent Cation Pyroborates3Insights into the structural chemistry, topology, and complexity of organically templated polychromates(VI) with the linear [Cr O3+1]2– groups: Synthesis and crystal structures of 1-methylpiperazinium polychromates, (C5H14N2)Cr2O7 and (C5H14N2)Cr3O100On a Crystal Chemical Vision on Niobium-Based Superconducting Intermetallics: A Brief Overview2Discovery of a new zinc oxide semiconductor: 21R polytype1Pseudosymmetry and cation ordering in heterophyllosilicates. 1. Refinement of the crystal structure of schüllerite Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)40Pseudosymmetry and cation ordering in heterophyllosilicates. 2. Refinement of the crystal structure of Ca-bearing mineral of the perraultite series0Synthesis and Crystal Structures of (C4H12N2)[Mn(HSeO3)2Cl2] and [(C4N12N2)2Br]2[Mn(HSeO3)2Br2]—New Representatives of the Modular Family of “Layered Hydroselenites”1The crystal chemistry and topology of modular structures. I. Selenites of rare-earth elements5The Crystal Chemistry and Topology of Modular Structures. III. 2D and 3D Zeolites Containing Tetrahedral Layers with the Apophyllite-Type Topology2Complex layered praseodymium tellurite halides: synthesis, crystal chemistry, principles of modular construction, and the character of polytypism0Crystal chemistry and topology of hybrid structures: A new "intermediate" Ga,Ge–representative of dumortierite – ellenbergerite series0Crystal chemistry and topology of simple rare-earth sulfates: synthesis, crystal structures, and spectroscopy of compounds with the general formula Ln2(SO4)3•8H2O1Symmetric molecules under extreme conditions. The minimum Shannon entropy hypothesis in predicting probable structures0Topology–symmetry analysis and design of nonlinear optical borate-halide polytypes0Sr(ReO4)Br⋅2H2O and Ba(ReO4)I⋅2H2O: New Representatives of the Ca(ReO4)Cl⋅2H2O Type Structure0Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure1The crystal chemistry and topology of modular structures. II. Heteropolyhedral substitutions and “blocky isomorphism” in inorganic compounds0A Computational Exploration of Polymorphism and Polytypism in Anhydrous Guanine and Xanthine Biogenic Crystals0

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  1. Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families

    Solid State Sciences · 2023-12-15

    Sergey N. Volkov, Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, Daria A. Banaru, Yulia A. Vaitieva, Maria Georgievna Krzhizhanovskaya, N. A. Yamnova, Vadim E. Kireev, Alevtina N. Gosteva, Nikita Sergeyevich Tsvetov, Yevgeny E. Savchenko, Р. С. Бубнова

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  2. Spectroscopic characterization of extra‐framework hydrated proton complexes with the extremely strong hydrogen bonds in microporous silicate minerals

    Journal of Raman Spectroscopy · 2024-01-22

    Н. В. Чуканов, Рамиза Кераровна Расцветаева, Natalia V. Zubkova, Marina F. Vigasina, Igor V. Pekov, Andrey A. Zolotarev, Julia A. Mikhailova, Sergey M. Aksenov

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  3. The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates

    Journal of Physics and Chemistry of Solids · 2024-02-22

    Sergey M. Aksenov, Nikita V. Chukanov, Viktor P. Tarasov, Daria A. Banaru, Stephanie A. Mackley, A. M. Banaru, Sergey V. Krivovichev, Peter Carman Burns

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  4. Hydroxylbenyacarite, (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10⋅4H2O, a new paulkerrite-group mineral, from the El Criollo mine, Cordoba Province, Argentina

    Mineralogical Magazine · 2024-03-19

    Rupert Hochleitner, Christian Rewitzer, Ian Edward Grey, Anthony R. Kampf, Colin M. MacRae, Robert W. Gable, William Gus Mumme

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  5. Mutual correlations of complexity indices of the crystal structure for the series of mercury-containing minerals

    Zeitschrift für Kristallographie - Crystalline Materials · 2024-03-28

    Daria A. Banaru, Sergey M. Aksenov, A. M. Banaru, Артем Ромаевич Оганов

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  6. Stoichiometry and topological features of triple molybdates ABC(MoO4) with the heteropolyhedral open MT-frameworks: Synthesis, crystal structure of Rb5{Hf1.5Co0.5(MoO4)6}, and comparative crystal chemistry

    Solid State Sciences · 2024-03-29

    Sergey M. Aksenov, Erzhena Т. Pavlova, Nadezhda N. Popova, Цыренова Галина Дашиевна, Bogdan I. Lazoryak

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  7. Hafnium Carbide: Prediction of Crystalline Structures and Investigation of Mechanical Properties

    Crystals · 2024-04-02

    Jelena Zagorac, Johann Christian Schön, Branko Z. Matović, Svetlana Butulija, Dejan Zagorac

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  8. Lobanovite from the Koashva Mountain in the Kibiny Massif (Kola Peninsula): crystal-chemical features, IR-spectroscopy and mineral assemblage

    Zapiski RMO (Proceedings of the Russian Mineralogical Society) · 2024-04-15

    G. S. Ilyin, N. V. Chukanov, D. V. Lisitsin, Dmitry Anatolievich Varlamov, Yu. A. Vaitieva, Sergey N. Britvin, Igor V. Pekov, Sergey M. Aksenov

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  9. Refinement of the crystal structure of christofschäferite-(Ce) and the modular aspect of the chevkinite polysomatic series with the general formula of {A4B(T2O7)2}{C2D2O8}m (m = 1, 2)

    Литосфера · 2024-05-03

    Sergey M. Aksenov, Ekaterina S. Zarubina, Рамиза Кераровна Расцветаева, Nikita V. Chukanov, Maria I. Filina

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  10. Crystal Chemistry of Minerals with Spinel Modules and New Data on the Symmetry, Structure, and Cation Distribution Features in Tashelgite, CaMgFe2+Al9O16(OH)

    Journal of Structural Chemistry · 2024-06-01

    Ekaterina S. Zarubina, Рамиза Кераровна Расцветаева, Vyacheslav S. Rusakov, Anatoliy G. Nikolaev, Farit G. Vagizov, Anatoliy I. Bakhtin, Dmitry Anatolievich Varlamov, Nikita V. Chukanov, Sergey A. Ananyev, Sergey M. Aksenov

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  11. Structural Features of Hydrated Representatives of the Labuntsovite Group: Refinement of Crystal Structures of Intermediate Members of the Tsepinite-Na–“Tsepinite-Ba”–Tsepinite-K Solid Solution

    Journal of Structural Chemistry · 2024-07-01

    Yu. A. Vaitieva, Н. В. Чуканов, Marina F. Vigasina, Dmitry Anatolievich Varlamov, Sergey N. Volkov, Рамиза Кераровна Расцветаева, Sergey M. Aksenov

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  12. Synthesis, crystal and electronic structures of two novel tunnel bismuth oxychlorides Bi18O22Cl8.5(BO3)0.5 and Bi18O22Cl8Se

    Journal of Solid State Chemistry · 2024-07-06

    Dmitri O. Charkin, Sergey N. Volkov, Alexey N. Kuznetsov∥, Alexey V. Povolotskiy, Anastasiya P. Chernyatieva, Julia S. Mironova, Sergey M. Aksenov

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  13. Synthesis and Crystal Structure of a New Non-Centrosymmetrical Layered Barium Iodide-Thiocyanate Tetrahydrate Ba(SCN)I·4H2O

    Journal of Structural Chemistry · 2024-12-01

    V. E. Kireev, Kirill A. Khasanov, Dmitri O. Charkin, Sergey M. Aksenov

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  14. 3Pb 8 O 7 I 2 ·2CsI: the salt-inclusion strategy enriches the structural chemistry in lead oxyhalides

    Dalton Transactions · 2025-01-01

    Mayinuer Maimaiti, Yuchen Yan, Jiang Wu, Tingwen Han, Jing Xie, Min Zhang

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  15. Structural Family of the CaMg[B2O5] Kurchatovite: Structure Features, Polytypical Complexity, DFT Analysis, and Comparative Crystal Chemistry of Divalent Cation Pyroborates

    Journal of Structural Chemistry · 2025-02-01

    Sergey M. Aksenov, D. А. Banaru, A. M. Banaru, Andrey A. Antonov, Natalia A. Kabanova, Alexey N. Kuznetsov∥, Elena L. Belokoneva, N. A. Yamnova, Д. В. Дейнеко, Nadezhda A. Chervonnaya, Nikita V. Chukanov, Vladislav A. Blatov

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  16. Insights into the structural chemistry, topology, and complexity of organically templated polychromates(VI) with the linear [Cr O3+1]2– groups: Synthesis and crystal structures of 1-methylpiperazinium polychromates, (C5H14N2)Cr2O7 and (C5H14N2)Cr3O10

    Solid State Sciences · 2025-02-06

    Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, Dmitri N. Dmitriev, Vadim E. Kireev, G. S. Ilyin, Yulia A. Vaitieva

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  17. On a Crystal Chemical Vision on Niobium-Based Superconducting Intermetallics: A Brief Overview

    Condensed Matter · 2025-02-14

    Taimo Priinits, Artjom Vargunin, Aleksandr Liivand

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  18. Discovery of a new zinc oxide semiconductor: 21R polytype

    Structural Dynamics · 2025-03-01

    Matej Fonović, Jelena Zagorac, Maria Čebela, Dragana J. Jordanov, Dejan Zagorac

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  19. Pseudosymmetry and cation ordering in heterophyllosilicates. 1. Refinement of the crystal structure of schüllerite Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4

    Литосфера · 2025-05-04

    G. S. Ilyin, Nikita V. Chukanov, Рамиза Кераровна Расцветаева, Sergey M. Aksenov

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  20. Pseudosymmetry and cation ordering in heterophyllosilicates. 2. Refinement of the crystal structure of Ca-bearing mineral of the perraultite series

    Литосфера · 2025-05-04

    G. S. Ilyin, Н. В. Чуканов, Igor V. Pekov, N. A. Yamnova, Рамиза Кераровна Расцветаева, Vasily O. Yapaskurt, Sergey M. Aksenov

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  21. Synthesis and Crystal Structures of (C4H12N2)[Mn(HSeO3)2Cl2] and [(C4N12N2)2Br]2[Mn(HSeO3)2Br2]—New Representatives of the Modular Family of “Layered Hydroselenites”

    Crystallography Reports · 2025-06-01

    V. E. Kireev, Dmitri N. Dmitriev, Dmitri O. Charkin, Sergey M. Aksenov

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  22. The crystal chemistry and topology of modular structures. I. Selenites of rare-earth elements

    Structural Chemistry · 2025-09-08

    Sergey M. Aksenov

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  23. The Crystal Chemistry and Topology of Modular Structures. III. 2D and 3D Zeolites Containing Tetrahedral Layers with the Apophyllite-Type Topology

    Molecules · 2025-11-20

    Sergey M. Aksenov, Н. В. Чуканов, Рамиза Кераровна Расцветаева, Dmitry Yu. Pushcharovsky, Dina V. Deyneko, Galina O. Kalashnikova, Ivan Gundarovich Tananaev, Peter Carman Burns

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  24. Complex layered praseodymium tellurite halides: synthesis, crystal chemistry, principles of modular construction, and the character of polytypism

    Russian Chemical Bulletin · 2025-12-01

    Dmitri O. Charkin, S.V. Chegodin, V. E. Kireev, Sergey M. Aksenov

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  25. Crystal chemistry and topology of hybrid structures: A new "intermediate" Ga,Ge–representative of dumortierite – ellenbergerite series

    Solid State Sciences · 2025-12-31

    Yu.A. Vaitieva, Tatiana V. Setkova, Anna V. Spivak, V.E. Kireev, Sergey M. Aksenov

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  26. Crystal chemistry and topology of simple rare-earth sulfates: synthesis, crystal structures, and spectroscopy of compounds with the general formula Ln2(SO4)3•8H2O

    Russian Chemical Bulletin · 2026-01-01

    Yu. A. Vaitieva, D. O. Charkin, E. Yu. Borovikova, Dina V. Deyneko, A. N. Gosteva, S. A. Ivanov, S. N. Volkov, R. K. Rastsvetaeva, V. A. Blatov, S. M. Aksenov

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  27. Symmetric molecules under extreme conditions. The minimum Shannon entropy hypothesis in predicting probable structures

    EPJ Web of Conferences · 2026-01-01

    Igor S. Shepelevich, Denis Sh. Sabirov

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  28. Topology–symmetry analysis and design of nonlinear optical borate-halide polytypes

    Inorganic Chemistry Frontiers · 2026-01-01

    Olga Reutova, Wenqi Jin, Zhihua Yang, Shilie Pan

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  29. Sr(ReO4)Br⋅2H2O and Ba(ReO4)I⋅2H2O: New Representatives of the Ca(ReO4)Cl⋅2H2O Type Structure

    Journal of Chemical Crystallography · 2026-03-25

    Dmitri O. Charkin, Kirill A. Khasanov, Vadim E. Kireev, Vasili Yu Grishaev, Tatiana A. Eremina, Oleg I. Siidra, Sergey M. Aksenov

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  30. Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure

    Journal of Solid State Chemistry · 2026-04-02

    Yu.A. Vaitieva, A. M. Banaru, A.N. Gosteva, M. Yu. Arsent’ev, M.G. Krzhizhanovskaya, S.N. Volkov, Sergey M. Aksenov

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  31. The crystal chemistry and topology of modular structures. II. Heteropolyhedral substitutions and “blocky isomorphism” in inorganic compounds

    Structural Chemistry · 2026-05-07

    S B Aksenov

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  32. A Computational Exploration of Polymorphism and Polytypism in Anhydrous Guanine and Xanthine Biogenic Crystals

    Crystal Growth & Design · 2026-08-14

    Parfaite Senoume Senou, Carlo Adamo, Frédèric Labat

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