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RESEARCH PAPER · Materials Today Physics · 2023

A survey of stereoactive oxysalts for linear and nonlinear optical applications

Pengfei Li, Jiang‐Gao Mao, Fang Kong

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A survey of stereoactive oxysalts for linear and nonlinear optical applicationsOriginalFrom CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency21Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds22Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties14Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application49Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions25Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size83[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation41New iodate fluoride Rb 2 Ce(IO 3 ) 5 F with nonlinear optical properties12Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability2Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification45Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70RbPbPS 4 : a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation23Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction26Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation153UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System16Controlling Nonlinear Optical Switch of Diarylethene by Changing Sizes of Fullerene: A Theoretical Study1The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution28A Highly Optical Anisotropic Hybrid Perovskite for Efficient Manipulation of Light Polarization64[C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence10First copper (II) oxo-selenite-sulfate Cu4O(SeO3)(SO4)2 and the role of a lone electron pair in open framework crystal structure formation2A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units22[C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence13From Ca 3 Be(SeO 3 ) 4 to SrBe(SeO 3 ) 2 : two unprecedented alkaline earth metal beryllium selenites with large band gaps and enhanced birefringence4Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions1The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation3Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching19Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching0(CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units10Rb2HSc(IO3)6 – a new member of the iodate family with a structural unit [M(IO3)6]0A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials3Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0Unveiling the Superior Birefringence Property of a Record‐Birefringent Crystal with Unique Building Block12Unveiling the Superior Birefringence Property of a Record‐Birefringent Crystal with Unique Building Block4Ferroelastic phase transition in lead bismuth borate, PbBiOBO30

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  1. From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency

    Inorganic Chemistry Frontiers · 2023-01-01

    Pengfei Li, Chun‐Li Hu, Bing-Xuan Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  2. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Shenghua Zhou, Mao‐Yin Ran, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  3. Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds

    Advanced Optical Materials · 2023-09-01

    Pengfei Li, Ya-Ping Gong, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  4. Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties

    Inorganic Chemistry · 2023-09-07

    Nan Ma, Yu Hong Huang, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

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  5. Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application

    Small · 2023-10-02

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  6. Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions

    Advanced Science · 2023-10-23

    Yun‐Xiang Ma, Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  7. Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size

    Journal of the American Chemical Society · 2023-10-26

    Jia-Hang Wu, Chun‐Li Hu, Ting-Kun Jiang, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  8. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  9. A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

    Materials Horizons · 2024-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  10. New iodate fluoride Rb 2 Ce(IO 3 ) 5 F with nonlinear optical properties

    Dalton Transactions · 2024-01-01

    O. P. Grigorieva, Т. Б. Шаталова, Alexey N. Kuznetsov∥, Peter S. Berdonosov, Sergey Yu. Stefanovich, Konstantin Alexandrovich Lyssenko, В. А. Долгих

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  11. Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability

    CrystEngComm · 2024-01-01

    O. P. Grigorieva, Larisa Victorovna Shvanskaya, Т. Б. Шаталова, Andrey A. Zolotarev, Peter S. Berdonosov, В. А. Долгих

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  12. Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)

    Inorganic Chemistry Frontiers · 2024-01-01

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  13. Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification

    Chemical Science · 2024-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  14. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  15. RbPbPS 4 : a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation

    Inorganic Chemistry Frontiers · 2024-01-01

    A-Yang Wang, Sheng-Hua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  16. Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction

    Inorganic Chemistry · 2024-02-16

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  17. Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation

    Journal of the American Chemical Society · 2024-03-08

    Pengfei Li, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  18. UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System

    Inorganic Chemistry · 2024-03-15

    Xinwei Zhang, Zhixiang Wang, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  19. Controlling Nonlinear Optical Switch of Diarylethene by Changing Sizes of Fullerene: A Theoretical Study

    ChemistrySelect · 2024-04-09

    Xiantao Xiong, Fengyi Zhang, Yongjun Zhang, Xiaoyu Zhao, Hong‐Liang Xu, Kun Zhang, Yaxin Wang

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  20. The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution

    Materials Today Physics · 2024-04-17

    Mao‐Yin Ran, Shenghua Zhou, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  21. A Highly Optical Anisotropic Hybrid Perovskite for Efficient Manipulation of Light Polarization

    Advanced Functional Materials · 2024-05-08

    Jieyu Zheng, Xianyu Song, Yiran Wu, Yulong Lian, Yanqiang Li, Qian-Ting Xu, Yang Zhou, Ziyi Wang, Lei Wang, Junhua Luo, Sangen Zhao

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  22. [C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence

    Journal of Solid State Chemistry · 2024-06-12

    Yang Zhang, Yang Zhang, Meng-Han Lv, Shu‐Fang Li, Hongbo Huang, Bingbing Zhang, Dong Yan

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  23. First copper (II) oxo-selenite-sulfate Cu4O(SeO3)(SO4)2 and the role of a lone electron pair in open framework crystal structure formation

    Solid State Sciences · 2024-09-20

    Alisher F. Murtazoev, Konstantin Alexandrovich Lyssenko, Alexey N. Kuznetsov∥, В. А. Долгих, Peter S. Berdonosov

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  24. A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units

    Laser & Photonics Review · 2024-10-24

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  25. [C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence

    Inorganic Chemistry · 2024-11-18

    Ya-Lan Deng, Chun‐Li Hu, Jiang‐Gao Mao

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  26. From Ca 3 Be(SeO 3 ) 4 to SrBe(SeO 3 ) 2 : two unprecedented alkaline earth metal beryllium selenites with large band gaps and enhanced birefringence

    Inorganic Chemistry Frontiers · 2025-01-01

    Xinyi Wang, Xin Wen, Yuchen Yan, Jindong Chen, Guangsai Yang, Guang Peng, Ning Ye

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  27. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  28. Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

    Inorganic Chemistry Frontiers · 2025-01-01

    Ping Feng, Shenghua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  29. K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions

    New Journal of Chemistry · 2025-01-01

    Min-Quan Lin, M. Duan, Jiang-Gao Mao, Bing‐Ping Yang

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  30. The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation

    Chemical Physics Letters · 2025-02-22

    Jialong Wang, Enshen Wang, Xiuhua Cui, Peng Li, Qun Jing, Zhaohui Chen

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  31. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

    Angewandte Chemie International Edition · 2025-03-31

    Min-Quan Lin, Chun‐Li Hu, M. Duan, Bingxuan Li, Jiang‐Gao Mao, Bing‐Ping Yang

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  32. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

    Angewandte Chemie · 2025-03-31

    Min-Quan Lin, Chun‐Li Hu, M. Duan, Bingxuan Li, Jiang‐Gao Mao, Bing‐Ping Yang

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  33. (CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units

    Inorganic Chemistry · 2025-05-20

    Ru‐Ling Tang, Yue‐Qi Wei, Yi‐Lei Lv, Bing-Wei Miao, Cheng Chen, Wenlong Liu

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  34. Rb2HSc(IO3)6 – a new member of the iodate family with a structural unit [M(IO3)6]

    Solid State Sciences · 2025-06-25

    O. P. Grigorieva, В. А. Тафеенко, Alexey N. Kuznetsov∥, Peter S. Berdonosov, В. А. Долгих

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  35. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  36. Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials

    Chemical Science · 2026-01-01

    Yuwei Kang, Can Hui Yang, Yunjie Wang, Qi Wu

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  37. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

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  38. Unveiling the Superior Birefringence Property of a Record‐Birefringent Crystal with Unique Building Block

    Angewandte Chemie International Edition · 2026-01-27

    Kaijie Xie, Zhiyong Bai, Weiqi Huang, Ji Qi, Tingjuan Lin, Muhammad Zeeshan, Yanqiang Li, Yang Zhou, Junhua Luo, Sangen Zhao

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  39. Unveiling the Superior Birefringence Property of a Record‐Birefringent Crystal with Unique Building Block

    Angewandte Chemie · 2026-01-27

    Kaijie Xie, Zhiyong Bai, Weiqi Huang, Ji Qi, Tingjuan Lin, Muhammad Zeeshan, Yanqiang Li, Yang Zhou, Junhua Luo, Sangen Zhao

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  40. Ferroelastic phase transition in lead bismuth borate, PbBiOBO3

    Journal of Physics and Chemistry of Solids · 2026-05-12

    P. Becker, Ivana Cı́sařová, Irena Matulková, Ivan Němec, Jan Rohlíček, L. Bohatý

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