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RESEARCH PAPER · Chemistry of Materials · 2021

CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation

Lin Lin, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic GenerationOriginalStability of quantum dot-sensitized solar cells: A review and prospects84Achieving a strong second harmonic generation response and a wide band gap in a Hg-based material41Ba 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond7Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions16Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodate24Li-Free ternary sulphide Cs 5 Ga 9 S 16 with excellent nonlinear optical performance similar to classic LiGaS 213Metal oxyhalides: an emerging family of nonlinear optical materials124Unprecedented boat-shaped [Mo 2 O 5 (IO 3 ) 4 ] 2− polyanions induced a strong second harmonic generation response31Wide bandgaps and strong SHG responses of hetero-oxyfluorides by dual-fluorination-directed bandgap engineering28HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response29Heteroanionic Melilite Oxysulfide: A Promising Infrared Nonlinear Optical Candidate with a Strong Second-Harmonic Generation Response, Sufficient Birefringence, and Wide Bandgap65Laser damage mechanism and threshold improvement of nonlinear optical La 3 Ga 5.5 Nb 0.5 O 14 crystal for a mid-infrared high-intensity laser12A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups19ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22Birefringence Dispersion Management of Langasite Nonlinear Crystals for the Improvement of Mid-Infrared Amplification10Trade-Off for Better Balanced Nonlinear Optical Performance with Disordered Si in ZnGeP217Recent advances in F-containing iodate nonlinear optical materials6Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates112Growth and Optical Properties of Large-Sized NaVO2(IO3)2(H2O) Crystals for Second-Harmonic Generation Applications12Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure6A review on the advancements in the characterization of the high-pressure properties of iodates44Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS324Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions15Single-Crystalline Li2Sn(IO3)6 Microwires: Combining Optical-Waveguiding and Frequency-Doubling Functions5A survey of stereoactive oxysalts for linear and nonlinear optical applications40NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy8Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain2Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation8Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap16Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold6Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements8Unraveling the Deep‐Level Defects Induced Optical Losses in LilnSe2 Crystal toward Enhancement of Mid‐Infrared Laser Radiation13A3Sc(SO4)3 (A = K, Rb, Cs): Three Deep‐Ultraviolet Transparent Alkali‐Scandium Sulfates with Strong Second‐Harmonic Generation Response and High Thermal Stability14SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8Prediction and Evaluation of Li 2 ZnS 2 Crystals as Mid‐Infrared Nonlinear Optical Material with High Thermal Conductivity7Relativistic Effect Engineered Ag 2 Hg 1– x Cd x I 4 Crystals: Achieving Optimal Balance between Bandgap and Nonlinear Optical Performance2Chiral Ligand-Induced Second-Harmonic Generation Response in Helical One-Dimensional Hybrid Lead Bromides9A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate6Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence10LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation0Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2Solution-Grown Cs2HgI4 Bulk Crystals: Achieving Strong SHG and High Damage Threshold Synergistically for IR Nonlinear Optics1IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F20

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  1. Stability of quantum dot-sensitized solar cells: A review and prospects

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    Akash S. Rasal, Sudesh Yadav, Anil Ashok Kashale, Ali Altaee, Jia‐Yaw Chang

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  2. Achieving a strong second harmonic generation response and a wide band gap in a Hg-based material

    Inorganic Chemistry Frontiers · 2022-01-01

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  3. Ba 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond

    Dalton Transactions · 2022-01-01

    Ying Hou, Hongyi Li, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  4. Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions

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    Jin Chen, Qianqian Chen, Fei‐Fei Mao, Zhen Liu, Bingxuan Li, Xiaohui Wu, Ke‐Zhao Du

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  5. Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodate

    Journal of Materials Chemistry C · 2022-01-01

    Mengmeng Ding, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  6. Li-Free ternary sulphide Cs 5 Ga 9 S 16 with excellent nonlinear optical performance similar to classic LiGaS 2

    Inorganic Chemistry Frontiers · 2022-01-01

    Jin-Xu Zhao, Xiao‐Ming Jiang, Wen‐Fa Chen, Shao‐Min Pei, Bin‐Wen Liu, Guo‐Cong Guo

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  7. Metal oxyhalides: an emerging family of nonlinear optical materials

    Chemical Science · 2022-01-01

    Xinglong Chen, Kang Min Ok

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  8. Unprecedented boat-shaped [Mo 2 O 5 (IO 3 ) 4 ] 2− polyanions induced a strong second harmonic generation response

    Chemical Communications · 2022-01-01

    Wei Zeng, Xuehua Dong, Yao Tian, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  9. Wide bandgaps and strong SHG responses of hetero-oxyfluorides by dual-fluorination-directed bandgap engineering

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    Yilei Hu, Xingxing Jiang, Tianhui Wu, Yanyan Xue, Chao Wu, Zhipeng Huang, Zheshuai Lin, Jun Qiang Xu, Mark Graeme Humphrey, Chi Zhang

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  10. HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups

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    Ru‐Ling Tang, Mei Yan, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  11. One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response

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    Haonan Liu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  12. Heteroanionic Melilite Oxysulfide: A Promising Infrared Nonlinear Optical Candidate with a Strong Second-Harmonic Generation Response, Sufficient Birefringence, and Wide Bandgap

    ACS Applied Materials & Interfaces · 2022-05-11

    Ruiqi Wang, Fei Liang, Xin Liu, Yi Xiao, Qianqian Liu, Xian Zhang, Li‐Ming Wu, Ling Chen, Fuqiang Huang

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  13. Laser damage mechanism and threshold improvement of nonlinear optical La 3 Ga 5.5 Nb 0.5 O 14 crystal for a mid-infrared high-intensity laser

    Optical Materials Express · 2022-08-03

    Yuzhou Wang, Fei Liang, Dazhi Lu, Shuxian Wang, Jiyang Wang, Haohai Yu, Huaijin Zhang

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  14. A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups

    Scripta Materialia · 2022-10-10

    Yu Huang, Zhi Gang Fang, Bing‐Ping Yang, Xueying Zhang, Jiang‐Gao Mao

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  15. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

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  16. Birefringence Dispersion Management of Langasite Nonlinear Crystals for the Improvement of Mid-Infrared Amplification

    Crystal Growth & Design · 2022-12-06

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  17. Trade-Off for Better Balanced Nonlinear Optical Performance with Disordered Si in ZnGeP2

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  18. Recent advances in F-containing iodate nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

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  19. Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates

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  20. Growth and Optical Properties of Large-Sized NaVO2(IO3)2(H2O) Crystals for Second-Harmonic Generation Applications

    Inorganic Chemistry · 2023-01-16

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  21. Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure

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  22. A review on the advancements in the characterization of the high-pressure properties of iodates

    Progress in Materials Science · 2023-03-01

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  23. Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS3

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  24. Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions

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  25. A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions

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  26. Single-Crystalline Li2Sn(IO3)6 Microwires: Combining Optical-Waveguiding and Frequency-Doubling Functions

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  28. NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy

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  29. Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain

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  30. Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation

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  31. Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

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  32. Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides

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