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RESEARCH PAPER · Chemistry of Materials · 2020

Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution

Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Ru‐Ling Tang, Jin Chen, Zhi Gang Fang, Bingxuan Li, Jiang‐Gao Mao

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Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site SubstitutionOriginal[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42Ba 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution8Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties8In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219NaGaI 3 O 9 F: a new alkali metal gallium iodate combined with IO 3 − and IO 3 F 2− units16Systematic centricity control using a chiral template: novel noncentrosymmetric polar niobium oxyfluorides and tantalum fluorides directed by chiral histidinium cations, [( l -hisH 2 )NbOF 5 ], [( d -hisH 2 )NbOF 5 ], [( l -hisH 2 )TaF 7 ], and [( d -hisH 2 )TaF 7 ]8Ultraviolet nonlinear optical crystals A 3 SrBi(P 2 O 7 ) 2 (A = K, Rb) with large second harmonic generation responses15A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response3A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance35High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies323Hydrogen‐Bond‐Driven Synergistically Enhanced Hyperpolarizability: Chiral Coordination Polymers with Nonpolar Structures Exhibiting Unusually Strong Second‐Harmonic Generation87Hydrogen‐Bond‐Driven Synergistically Enhanced Hyperpolarizability: Chiral Coordination Polymers with Nonpolar Structures Exhibiting Unusually Strong Second‐Harmonic Generation19A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation50Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses5An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution73An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution10AMoO3(IO3) (A = Na and K): Two promising optical materials via properly assembling the Λ-shaped basic building units19A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]4From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence53K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units6Ba 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond7CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions22HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response19Polar lanthanide copper iodates LnCu(IO3)5 (Ln = La, Ce, Pr, and Nd): Synthesis, crystal structure and characterization6Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements22A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups19Growth and Optical Properties of Large-Sized NaVO2(IO3)2(H2O) Crystals for Second-Harmonic Generation Applications12C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O: An Unprecedented Asymmetric Guanidinium Polyiodate with a Strong Second-Harmonic-Generation Response and a Wide Band Gap16CsHfF4(IO3): A Hafnium Iodate Exhibiting a Strong Second-Harmonic-Generation Effect and a Wide Band Gap Achieved by Mixed-Ligand Acentric Coordination8Alignment of Λ-Shaped Basic Building Units to Construct One New KMoO3(IO3) Polar Polymorph11Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites70A survey of stereoactive oxysalts for linear and nonlinear optical applications40Bandgap reduction and efficiency enhancement in Cs 2 AgBiBr 6 double perovskite solar cells through gallium substitution65Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation8From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates13Improving Cs2agbibr6 Double Perovskite Solar Cells Through Graphdiyne Doping: A Stride Towards Enhanced Performance0Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43Bandgap Engineering and Enhancing Optoelectronic Performance of a Lead-Free Double Perovskite Cs2AgBiBr6 Solar Cell via Al Doping43Improving Cs2AgBiBr6 double perovskite solar cells through graphdiyne doping: A Stride towards enhanced performance17Enhancing solar cell efficiency: lead-free double perovskite solar cells Cs2AgBiBr6 with magnesium-doped and Zn2SnO4 electron transport layer6Polyfluorene incorporation for superior performance and band gap reduction: enhancing Cs2AgBiBr6 double perovskite solar cells6SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8Enhancing efficiency in double perovskite solar cells through bandgap reduction via organic polymer doping11Enhancing the efficiency and stability of Cs2AgBiBr6 solar cells via MAPbBr3 decoration7Bandgap engineering and efficiency enhancement in Cs2AgBiBr6 solar cells through MAPbI2Br incorporation0Optimizing the solar cell performance based on terbium doped Cs2AgBiBr6 absorber and Zn2SnO4 electron transport layer1Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3Λ‐Shaped Dimers Enables Polar Antiperovskites Through A‐Site Displacement Mechanism0

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  1. [GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution

    Chemical Science · 2021-01-01

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Zhi Gang Fang, Yuan Hua Lin, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  2. Ba 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution

    Chemical Communications · 2021-01-01

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Zhi Gang Fang, Yu Huang, Jiang‐Gao Mao

    Read original paper ↗ ·

  3. Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties

    CrystEngComm · 2021-01-01

    Yunseung Kuk, Kang Min Ok

    Read original paper ↗ ·

  4. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·

  5. NaGaI 3 O 9 F: a new alkali metal gallium iodate combined with IO 3 − and IO 3 F 2− units

    Dalton Transactions · 2021-01-01

    Dandan Wang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  6. Systematic centricity control using a chiral template: novel noncentrosymmetric polar niobium oxyfluorides and tantalum fluorides directed by chiral histidinium cations, [( l -hisH 2 )NbOF 5 ], [( d -hisH 2 )NbOF 5 ], [( l -hisH 2 )TaF 7 ], and [( d -hisH 2 )TaF 7 ]

    Inorganic Chemistry Frontiers · 2021-01-01

    HeeJung Choi, Kang Min Ok

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  7. Ultraviolet nonlinear optical crystals A 3 SrBi(P 2 O 7 ) 2 (A = K, Rb) with large second harmonic generation responses

    Inorganic Chemistry Frontiers · 2021-01-01

    Shiwei Liu, Bingbing Zhang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  8. A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response

    Crystal Growth & Design · 2021-02-19

    Dongmei Wang, Zhiyong Bai, Lehui Liu, Lei Hu, Yisheng Huang, Feifei Yuan, Dongshan Wei, Zhoubin Lin, Lizhen Zhang

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  9. A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance

    Chemistry of Materials · 2021-04-07

    Xiaohan Zhang, Bing‐Ping Yang, Chun‐Li Hu, Jin Chen, Q. Huang, Jiang‐Gao Mao

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  10. High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies

    Accounts of Chemical Research · 2021-05-27

    Jin Chen, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  11. Hydrogen‐Bond‐Driven Synergistically Enhanced Hyperpolarizability: Chiral Coordination Polymers with Nonpolar Structures Exhibiting Unusually Strong Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2021-06-07

    Joonhyuk Kee, Kang Min Ok

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  12. Hydrogen‐Bond‐Driven Synergistically Enhanced Hyperpolarizability: Chiral Coordination Polymers with Nonpolar Structures Exhibiting Unusually Strong Second‐Harmonic Generation

    Angewandte Chemie · 2021-06-07

    Joonhyuk Kee, Kang Min Ok

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  13. A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation

    Chemistry of Materials · 2021-06-23

    Yilei Hu, Xingxing Jiang, Chao Wu, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·

  14. Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]

    Crystal Growth & Design · 2021-06-24

    Xiaoqing Jiang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  15. Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses

    Crystal Growth & Design · 2021-07-22

    Chao Wu, Lin Lin, Tianhui Wu, Wenyan Dan, Zhipeng Huang, Chi Zhang

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  16. An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution

    Angewandte Chemie International Edition · 2021-09-28

    Ying Hou, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  17. An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution

    Angewandte Chemie · 2021-09-28

    Ying Hou, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  18. AMoO3(IO3) (A = Na and K): Two promising optical materials via properly assembling the Λ-shaped basic building units

    Journal of Alloys and Compounds · 2021-10-29

    Jin Chen, Chun‐Li Hu, Yilin Li, Qianqian Chen, Bingxuan Li, Jiang‐Gao Mao

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  19. A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]

    CrystEngComm · 2021-11-11

    Dandan Wang, Xiaoqing Jiang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  20. From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence

    Chemistry of Materials · 2021-11-22

    Tianhui Wu, Xingxing Jiang, Yiran Zhang, Zujian Wang, Hongyuan Sha, Chao Wu, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  21. K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units

    Inorganic Chemistry · 2021-12-17

    Jun Sun, Tushagu Abudouwufu, Congcong Jin, Zhiyong Guo, Min Zhang

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  22. Ba 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond

    Dalton Transactions · 2022-01-01

    Ying Hou, Hongyi Li, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  23. CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions

    Inorganic Chemistry Frontiers · 2022-01-01

    Nan Ma, Chun‐Li Hu, Jin Chen, Zhi Gang Fang, Yu Huang, Bingxuan Li, Jiang‐Gao Mao

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  24. HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response

    Journal of Alloys and Compounds · 2022-01-11

    Yinglei Han, Xin Lei Zhao, Feng Xu, Bingxuan Li, Ning Ye, Min Luo

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  25. Polar lanthanide copper iodates LnCu(IO3)5 (Ln = La, Ce, Pr, and Nd): Synthesis, crystal structure and characterization

    Journal of Solid State Chemistry · 2022-01-23

    Lei Geng, Chang‐Yu Meng, Quan Yan

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  26. Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements

    Inorganic Chemistry · 2022-02-14

    Yu Huang, Ting-Kun Jiang, Bing‐Ping Yang, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  27. A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups

    Scripta Materialia · 2022-10-10

    Yu Huang, Zhi Gang Fang, Bing‐Ping Yang, Xueying Zhang, Jiang‐Gao Mao

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  28. Growth and Optical Properties of Large-Sized NaVO2(IO3)2(H2O) Crystals for Second-Harmonic Generation Applications

    Inorganic Chemistry · 2023-01-16

    Xiang Xu, Bingxuan Li, Lingxiong Huang, Bing‐Ping Yang, Ge Zhang, Jiang‐Gao Mao

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  29. C(NH2)3(I3O8)(HI3O8)(H2I2O6)(HIO3)4·3H2O: An Unprecedented Asymmetric Guanidinium Polyiodate with a Strong Second-Harmonic-Generation Response and a Wide Band Gap

    Inorganic Chemistry · 2023-01-19

    Dong Yan, Meng-Meng Ren, Fei‐Fei Mao, Yu Ma, Ru‐Ling Tang, Bingbing Zhang, Yao Ma, Xiu‐Du Zhang, Shu‐Fang Li

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  30. CsHfF4(IO3): A Hafnium Iodate Exhibiting a Strong Second-Harmonic-Generation Effect and a Wide Band Gap Achieved by Mixed-Ligand Acentric Coordination

    Inorganic Chemistry · 2023-02-15

    Yu Huang, Bingxuan Li, Chun‐Li Hu, Bing‐Ping Yang, Jiang‐Gao Mao

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  31. Alignment of Λ-Shaped Basic Building Units to Construct One New KMoO3(IO3) Polar Polymorph

    Inorganic Chemistry · 2023-02-22

    Qing Li, Haonan Liu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  32. Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions

    ACS Materials Letters · 2023-05-08

    Jiale Chen, Pengcheng Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  33. Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites

    Coordination Chemistry Reviews · 2023-05-22

    Zhiyong Bai, Kang Min Ok

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  34. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

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  35. Bandgap reduction and efficiency enhancement in Cs 2 AgBiBr 6 double perovskite solar cells through gallium substitution

    RSC Advances · 2024-01-01

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  36. Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation

    Journal of Materials Chemistry C · 2024-01-01

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  37. From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates

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  38. Improving Cs2agbibr6 Double Perovskite Solar Cells Through Graphdiyne Doping: A Stride Towards Enhanced Performance

    SSRN Electronic Journal · 2024-01-01

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  39. Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization

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  40. Bandgap Engineering and Enhancing Optoelectronic Performance of a Lead-Free Double Perovskite Cs2AgBiBr6 Solar Cell via Al Doping

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  41. Improving Cs2AgBiBr6 double perovskite solar cells through graphdiyne doping: A Stride towards enhanced performance

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  42. Enhancing solar cell efficiency: lead-free double perovskite solar cells Cs2AgBiBr6 with magnesium-doped and Zn2SnO4 electron transport layer

    Journal of Sol-Gel Science and Technology · 2024-09-12

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  43. Polyfluorene incorporation for superior performance and band gap reduction: enhancing Cs2AgBiBr6 double perovskite solar cells

    Journal of Sol-Gel Science and Technology · 2024-10-14

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  44. SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap

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  45. Enhancing efficiency in double perovskite solar cells through bandgap reduction via organic polymer doping

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  46. Enhancing the efficiency and stability of Cs2AgBiBr6 solar cells via MAPbBr3 decoration

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  47. Bandgap engineering and efficiency enhancement in Cs2AgBiBr6 solar cells through MAPbI2Br incorporation

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  48. Optimizing the solar cell performance based on terbium doped Cs2AgBiBr6 absorber and Zn2SnO4 electron transport layer

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  49. Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials

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  50. Λ‐Shaped Dimers Enables Polar Antiperovskites Through A‐Site Displacement Mechanism

    Advanced Functional Materials · 2026-08-30

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