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RESEARCH PAPER · Materials Horizons · 2024

A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformationOriginal[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification46Reticular chemistry-aided effective design of new second-order nonlinear optical selenites11Structural strategy for advancing nonlinear optical effects in 1D-[MX 2 ] ∞ chains: internal distortion and atomic types2Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction26Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation153UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System16The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution28Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4Synthesis and characterization of novel double perovskite K2AgBiBr612RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units22Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides22“Three functions in one”: multifunctional rare-earth cyamelurates with magnetism, luminescence, and giant optical nonlinearity6A wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units2Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Prismatic crystal field stabilized divalent rare-earth chalcogenide REIIBII6CIII6QVI16 with bifunctionality30Unprecedented v-shaped [SeO2E] units stabilized in KM[Se2O5]2[SeO2] (M= Al and Ga) constructed by nanoconfinement strategy6A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy22A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy6From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal4From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal29A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property5Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence55La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13(CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units10Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains23Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains8Decorated BN nanocones as NLO-active nanocarriers of nitrosourea anticancer drug: A DFT study2A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy7Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence3Orientational control of [IO 3 ] groups enables strong optical anisotropy and second-harmonic generation in noncentrosymmetric Pb(IO 3 ) 20Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals12Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap2

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41 direct citing papers saved.

  1. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  2. Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)

    Inorganic Chemistry Frontiers · 2024-01-01

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  3. Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification

    Chemical Science · 2024-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  4. Reticular chemistry-aided effective design of new second-order nonlinear optical selenites

    Materials Horizons · 2024-01-01

    Qian Li, Yi Zheng, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

    Read original paper ↗ ·

  5. Structural strategy for advancing nonlinear optical effects in 1D-[MX 2 ] ∞ chains: internal distortion and atomic types

    RSC Advances · 2024-01-01

    Chaoyi Zhu

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  6. Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction

    Inorganic Chemistry · 2024-02-16

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  7. Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation

    Journal of the American Chemical Society · 2024-03-08

    Pengfei Li, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  8. UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System

    Inorganic Chemistry · 2024-03-15

    Xinwei Zhang, Zhixiang Wang, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  9. The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution

    Materials Today Physics · 2024-04-17

    Mao‐Yin Ran, Shenghua Zhou, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  10. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  11. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  12. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  13. Synthesis and characterization of novel double perovskite K2AgBiBr6

    Optical Materials · 2024-08-06

    S. Janaki, S. Lephe, Gifrin Fredik Raj S M, S. Sahaya Jude Dhas, Arun Jose L

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  14. RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps

    Inorganic Chemistry · 2024-10-08

    Junjiang Li, Huanke Zhao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  15. A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units

    Laser & Photonics Review · 2024-10-24

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  16. Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides

    Chemistry of Materials · 2024-12-03

    Mao-Yin Ran, Sheng-Hua Zhou, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  17. “Three functions in one”: multifunctional rare-earth cyamelurates with magnetism, luminescence, and giant optical nonlinearity

    Chemical Science · 2025-01-01

    Jing Zhang, Yuxiao Liu, Fangyan Wang, Pifu Gong, Zhaoyi Li, Xinyuan Zhang, Fei Liang, Shu Hai Guo, Zhanggui Hu, Yicheng Wu

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  18. A wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units

    Dalton Transactions · 2025-01-01

    Guansong Zheng, Wang Zhao, Xiaoyu Wu, Hongshan Wang, Yi Du, Juanjuan Lu, Xiaodong Zhou, Junjie Li

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  19. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

    Dalton Transactions · 2025-01-01

    Shihua Ma, Lei Geng, Baozhu Zhu, Changyu Meng

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  20. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  21. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  22. Prismatic crystal field stabilized divalent rare-earth chalcogenide REIIBII6CIII6QVI16 with bifunctionality

    The Innovation Materials · 2025-01-01

    Linan Wang, Hongshan Wang, Qi Sun, Zuxin Chen, Fei Tang, Shilie Pan, Junjie Li, Miriding Mutailipu

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  23. Unprecedented v-shaped [SeO2E] units stabilized in KM[Se2O5]2[SeO2] (M= Al and Ga) constructed by nanoconfinement strategy

    The Innovation Materials · 2025-01-01

    Yi Zheng, Qian Li, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  24. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie International Edition · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Fang Kong, Jiang‐Gao Mao

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  25. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  26. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie · 2025-02-22

    Xinyang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  27. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie International Edition · 2025-02-22

    Xin‐Yang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  28. A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property

    Chinese Journal of Structural Chemistry · 2025-03-24

    Qi Sun, Hongshan Wang, Linlin Liu, Zuxin Chen, Junjie Li, Shilie Pan

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  29. Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence

    Journal of the American Chemical Society · 2025-04-07

    Ya-Lan Deng, Chun‐Li Hu, Xiang Xu, Mingzhi Zhang, Jiang‐Gao Mao

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  30. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  31. (CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units

    Inorganic Chemistry · 2025-05-20

    Ru‐Ling Tang, Yue‐Qi Wei, Yi‐Lei Lv, Bing-Wei Miao, Cheng Chen, Wenlong Liu

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  32. Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains

    Angewandte Chemie International Edition · 2025-07-01

    Congcong Jin, Yang Li, Jin Seong Kim, Joshua Lim, Hongbo Huang, Chong‐An Chen, Jihyun Lee, Yejin Heo, Bingbing Zhang, Joon Ik Jang, Kang Min Ok

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  33. Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains

    Angewandte Chemie · 2025-07-01

    Congcong Jin, Yang Li, Jin Seong Kim, Joshua Lim, Hongbo Huang, Chong‐An Chen, Jihyun Lee, Yejin Heo, Bingbing Zhang, Joon Ik Jang, Kang Min Ok

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  34. Decorated BN nanocones as NLO-active nanocarriers of nitrosourea anticancer drug: A DFT study

    Computational and Theoretical Chemistry · 2025-08-09

    Maryam Souri

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  35. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  36. KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy

    Small · 2025-12-15

    Lei Hou, Siyu Li, Wencong Li, Bingchen Xiao, Yaoqing Chu, Bingbing Zhang, Ying Wang, Xinglong Chen, Lili Liu

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  37. Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence

    Crystal Growth & Design · 2025-12-25

    Han Bing Luo, Siyu Chen, Bailiang Li, Liling Cao, Xuehua Dong, Ling Huang, Guohong Zou

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  38. Orientational control of [IO 3 ] groups enables strong optical anisotropy and second-harmonic generation in noncentrosymmetric Pb(IO 3 ) 2

    Dalton Transactions · 2026-01-01

    Jialong Wang, Lele Dou, Yunfeng Li, XiuHua Cui, Qun Jing, Ming‐Hsien Lee

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  39. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

    Journal of the American Chemical Society · 2026-03-05

    Chong‐An Chen, Yang Li, Congcong Jin, S. D. Lee, Zhihua Yang, Kang Min Ok

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  40. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  41. The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap

    Applied Physics Letters · 2026-06-15

    Xinyue Shi, Xueqing Liu, Yipeng Pang, Yuan Fang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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