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RESEARCH PAPER · Advanced Functional Materials · 2024

Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite Family

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Learning From Nature: The Rational Non‐Centrosymmetric Structural Design in the Honeycomb‐Like Gaudefroyite FamilyOriginalA wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units2Hetero‐Anionic Oxychalcogenides with Structures and Properties Tuned by the O:S Ratio14K2PbB5P3O17: A Mixed-Coordinated Borophosphate with Enhanced Birefringence Driven by the [B2O5] Unit5Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution21Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution6Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy34Achieving excellent nonlinear optical performance via “dimensionality elevation”-driven transformation from centrosymmetric to non-centrosymmetric structures1Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals14Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals3LnEuGa3OS6 (Ln = La, Pr, Nd): three dual rare earth metal-based oxychalcogenides with good IR nonlinear optical performances1Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals0Shape‐Topology‐Driven Design of Deep Ultraviolet Nonlinear Optical Crystals: Engineering [CH 3 PO 3 ]–Metal‐Oxo Layered Frameworks for Enhanced SHG, DUV Transparency3Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances2Chiral Lead-Oxyiodide Nonlinear Optical Crystals Constructed on l -Malate Groups5Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals131D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation7Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV nonlinear optical material due to π-conjugated cation and hydrogen bonding intervention1Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties1Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials1Parallel arrangement of functional building blocks: toward performance synergy in oxalate borate ultraviolet nonlinear optical crystals0Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0The Parallel Coplanar Alignment of Planar Non‐π‐Conjugated [Pb 3 Br 3 ] Rings for a Stable Ultraviolet Nonlinear Optical Crystal0

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  1. A wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units

    Dalton Transactions · 2025-01-01

    Guansong Zheng, Wang Zhao, Xiaoyu Wu, Hongshan Wang, Yi Du, Juanjuan Lu, Xiaodong Zhou, Junjie Li

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  2. Hetero‐Anionic Oxychalcogenides with Structures and Properties Tuned by the O:S Ratio

    Advanced Functional Materials · 2025-01-17

    Shaoxin Cui, Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  3. K2PbB5P3O17: A Mixed-Coordinated Borophosphate with Enhanced Birefringence Driven by the [B2O5] Unit

    Inorganic Chemistry · 2025-02-24

    Huanhuan Cheng, Meng Cheng, Abudukadi Tudi, Xueling Hou

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  4. Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution

    Angewandte Chemie International Edition · 2025-03-17

    Lingli Wu, Chensheng Lin, Haotian Tian, Yan Xin Tao, Bingxuan Li, Huixin Fan, Yujie Fan, Shunda Yang, Min Luo

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  5. Engineering an Excellent β ‐BaB 2 O 4 ‐Inspired UV Nonlinear Optical Material Through Secondary Building Unit Substitution

    Angewandte Chemie · 2025-03-17

    Lingli Wu, Chensheng Lin, Haotian Tian, Tao Yan, Bingxuan Li, Huixin Fan, Yujie Fan, Shunda Yang, Min Luo

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  6. Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy

    Journal of the American Chemical Society · 2025-05-15

    Tinghui Zhang, Fei Liang, Conggang Li, Ning Ye, Zhanggui Hu

    Read original paper ↗ ·
  7. Achieving excellent nonlinear optical performance via “dimensionality elevation”-driven transformation from centrosymmetric to non-centrosymmetric structures

    Science China Chemistry · 2025-06-28

    Lin‐Tao Jiang, Jun-Long Chen, Ming‐Shu Zhang, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  8. Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals

    Angewandte Chemie International Edition · 2025-08-10

    Lingli Wu, Chensheng Lin, Huixin Fan, Shunda Yang, Tao Yan, Yunxia Song, Min Luo

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  9. Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals

    Angewandte Chemie · 2025-08-10

    Lingli Wu, Chensheng Lin, Huixin Fan, Shunda Yang, Tao Yan, Yunxia Song, Min Luo

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  10. LnEuGa3OS6 (Ln = La, Pr, Nd): three dual rare earth metal-based oxychalcogenides with good IR nonlinear optical performances

    Materials Today Chemistry · 2025-09-17

    Jiaxue Wang, Binqiang Chai, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  11. Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals

    Chemistry - A European Journal · 2025-10-09

    Ying‐Jie Jia, Yi-Gang Chen, Bingbing Zhang, Yao Guo, Xian‐Ming Zhang

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  12. Shape‐Topology‐Driven Design of Deep Ultraviolet Nonlinear Optical Crystals: Engineering [CH 3 PO 3 ]–Metal‐Oxo Layered Frameworks for Enhanced SHG, DUV Transparency

    Laser & Photonics Review · 2025-11-03

    Cheng Hu, Lingli Wu, Chensheng Lin, Yujie Fan, Chao Wang, Huixin Fan, Tao Yan, Min Luo

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  13. Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances

    Inorganic Chemistry Frontiers · 2025-11-24

    Jiaxue Wang, Yixin Song, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  14. Chiral Lead-Oxyiodide Nonlinear Optical Crystals Constructed on l -Malate Groups

    Inorganic Chemistry · 2025-12-08

    Yiting Luo, Shuangcheng Li, Jialin Zeng, Senfu Lei, Zilong Geng, Yulu Wu, Wenjing Yang, Ruibiao Fu, Zuju Ma

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  15. Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals

    Coordination Chemistry Reviews · 2026-02-02

    Ailijiang Abudurusuli, Linan Wang, Junben Huang, Xueling Hou, Miriding Mutailipu, Shilie Pan, Junjie Li

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  16. 1D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation

    Chemistry - A European Journal · 2026-02-09

    Mubashar Ilyas, Lin Xiong, Li Zhang, Maida, Maroof Ahmad Khan, Muhammad Abbas, Nagesh Manurkar, Mudassar Ilyas, Niu Zhang, Hui Li

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  17. Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV nonlinear optical material due to π-conjugated cation and hydrogen bonding intervention

    Chinese Journal of Structural Chemistry · 2026-03-07

    Lei Wu, Enshen Wang, Bao Jiang, Xueyin Fu, Kechen Sun, Maierhaba Abudoureheman, Zhaohui Chen, Qun Jing, Yuhong Su

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  18. Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties

    Science China Chemistry · 2026-03-19

    Shijie Zhao, Lili Li, Tinghui Zhang, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  19. Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials

    Materials Today Physics · 2026-07-04

    D K Li, Yujie Zhang, H Liu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  20. Parallel arrangement of functional building blocks: toward performance synergy in oxalate borate ultraviolet nonlinear optical crystals

    Science China Chemistry · 2026-07-13

    Juhui Cui, Minqiang Gai, Ke Li, Z L Yang, Xueling Hou, Shilie Pan, Miriding Mutailipu

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  21. Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects

    Advanced Optical Materials · 2026-07-21

    Xiangran Kong, Jingdong Yan, Zi Wang, Hongwei Leng, Shichao Cheng, Sue Hao, Xiaoran Niu, Zuotao Lei, Chunhui Yang

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  22. Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures

    Laser & Photonics Review · 2026-08-15

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xin-Tao Wu

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  23. The Parallel Coplanar Alignment of Planar Non‐π‐Conjugated [Pb 3 Br 3 ] Rings for a Stable Ultraviolet Nonlinear Optical Crystal

    Advanced Optical Materials · 2026-08-27

    Xiaofan Tong, Zuju Ma, Yulu Wu, Ruibiao Fu, Wenjing Yang, Jiacheng Chen, Qian Zeng

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