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RESEARCH PAPER · Materials Chemistry Frontiers · 2022

Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds

Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compoundsOriginalFrom AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties27From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency21The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 485The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)47Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route8Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap21Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra27(NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence22A survey of stereoactive oxysalts for linear and nonlinear optical applications40Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds22Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application49Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions25A2Hgx(SeO3)y (A = K, Rb, Cs): Three Alkali Metal Mercury Selenites Featuring Unique 1D [HgOm(SeO3)n]∞ Chains13A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation41Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification46AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap20Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction26Metal Methanesulfonates with Mixed Anionic Groups with Large Band Gaps and Enhanced Birefringence50Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation153UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System16MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence7Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements8Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions29Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy16La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13The crystal chemistry and topology of modular structures. I. Selenites of rare-earth elements5ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems2A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap2Piperazinium sulfate – selenous acid cocrystal: a new organically templated non-centrosymmetric compound0Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1

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  1. From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

    Bo Zhang, Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Fang Kong, Jiang‐Gao Mao

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  2. From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency

    Inorganic Chemistry Frontiers · 2023-01-01

    Pengfei Li, Chun‐Li Hu, Bing-Xuan Li, Jiang‐Gao Mao, Fang Kong

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  3. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 4

    Angewandte Chemie International Edition · 2023-02-27

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  4. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)4

    Angewandte Chemie · 2023-02-27

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  5. Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route

    Inorganic Chemistry · 2023-04-07

    Xuemei Wen, Ying Long, Daibing Luo, Ling Huang, Hongmei Zeng, Xin Wang, Guohong Zou, Zhien Lin

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  6. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

    Journal of Alloys and Compounds · 2023-05-15

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

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  7. AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2023-05-24

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  8. Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra

    Inorganic Chemistry · 2023-05-31

    Jinxuan Ren, Yuqi Chen, Liying Ren, Yuqiao Zhou, Xuehua Dong, Daojiang Gao, Ling Huang, Liling Cao, Ning Ye

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  9. (NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence

    Small · 2023-07-25

    Nan Ma, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  10. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  11. Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds

    Advanced Optical Materials · 2023-09-01

    Pengfei Li, Ya-Ping Gong, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  12. Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application

    Small · 2023-10-02

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  13. Ln 2 F 2 (OH 2 )(MoO 3 ) 2 (SeO 3 ) 2 : Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions

    Advanced Science · 2023-10-23

    Yun‐Xiang Ma, Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  14. A2Hgx(SeO3)y (A = K, Rb, Cs): Three Alkali Metal Mercury Selenites Featuring Unique 1D [HgOm(SeO3)n]∞ Chains

    Inorganic Chemistry · 2023-12-11

    Jinxuan Ren, Hui Cui, Linhong Cheng, Yuqiao Zhou, Xuehua Dong, Daojiang Gao, Ling Huang, Liling Cao, Ning Ye

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  15. A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

    Materials Horizons · 2024-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  16. Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification

    Chemical Science · 2024-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  17. AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2024-01-18

    Mengmeng Zhu, Junbo Wang, Lei Hou, Yiwen Yuan, Lili Liu, Yaoqing Chu, Chunmei Huang

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  18. Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction

    Inorganic Chemistry · 2024-02-16

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao, Fang Kong

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  19. Metal Methanesulfonates with Mixed Anionic Groups with Large Band Gaps and Enhanced Birefringence

    Chemistry of Materials · 2024-02-16

    Mingli Liang, Yujie Zhang, Eugene Izvarin, Michael J. Waters, James M. Rondinelli, P. Shiv Halasyamani

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  20. Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation

    Journal of the American Chemical Society · 2024-03-08

    Pengfei Li, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  21. UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System

    Inorganic Chemistry · 2024-03-15

    Xinwei Zhang, Zhixiang Wang, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  22. MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence

    Journal of Solid State Chemistry · 2024-05-12

    Yueling Sun, Lei Huai, An-Hua Gong

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  23. Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements

    Inorganic Chemistry · 2024-05-23

    Yurui Wang, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  24. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  25. From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions

    Chinese Chemical Letters · 2024-11-03

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  26. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  27. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

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  28. Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy

    Laser & Photonics Review · 2025-04-10

    Piao Tang, Xin Wen, Yuchen Yan, Cao Xue, Jindong Chen, Chensheng Lin, Min Luo, Ning Ye, Guang Peng

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  29. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  30. The crystal chemistry and topology of modular structures. I. Selenites of rare-earth elements

    Structural Chemistry · 2025-09-08

    Sergey M. Aksenov

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  31. ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems

    Inorganic Chemistry Frontiers · 2025-12-20

    Tian-Tian He, C Hu, Ya-Ping Gong, Jiang‐Gao Mao, Fang Kong

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  32. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  33. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  34. The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap

    Applied Physics Letters · 2026-06-15

    Xinyue Shi, Xueqing Liu, Yipeng Pang, Yuan Fang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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  35. Piperazinium sulfate – selenous acid cocrystal: a new organically templated non-centrosymmetric compound

    Zeitschrift für Kristallographie - Crystalline Materials · 2026-07-24

    Oleg I. Siidra, Dmitri O. Charkin, Leonid A. Olender, Nikita V. Chukanov, Dmitri N. Dmitriev, M.S. Kozin, Sergey Yu. Stefanovich

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  36. Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units

    Coordination Chemistry Reviews · 2026-08-12

    Meiqi Liu, Miao Zhang, Ziyang Wang, Shizheng Li, Yang Zhao, Jiahang Liu, Jianmin Gu, Weiwei Cao, Desong Wang, Tianhui Wu

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