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RESEARCH PAPER · Advanced Functional Materials · 2023

Small Changes, Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B‐Site

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Small Changes, Big Impact: Tungsten Bronzes with Extremely Large Second Harmonic Generation Achieved by the Transition Metal Doping on the B‐SiteOriginalBreaking the bottleneck of simultaneously wide band gap and large nonlinear optical coefficient by a “pore reconstruction” strategy in a salt-inclusion chalcogenide26MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra2Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold39Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites71Pinched hysteresis loop and internal bias field in Ba4(La0.2Nd0.2Sm0.2Eu0.2Y0.2)2Ti4Nb6O30 tungsten bronze ceramics8A I B 3 II C 2 III Q 6 VI X VII : A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS 3 ] and Polycations25Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence9Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence41EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response4Role of Incommensurate Modulation in Ba4(Sm1–xLax)2Ti4Nb6O30 Tetragonal Tungsten Bronzes6Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective109Ca 2 La(MS 4 )(BS 3 ) (M = Ge/Si and Sn/Si): high-performance infrared nonlinear optical materials designed using an atomic site co-occupancy strategy9Chemical Substitution‐Driven Design of a High‐Performance Noncentrosymmetric Bismuth Molybdenum Selenite10Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties11A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy22A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy6Synergically Assembling Advantageous Groups toward High‐Performance Infrared Nonlinear Optical Materials A II CdSiSe 4 (A II = Sr, Ba)41SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold4Wide permittivity stability against temperature of high-permittivity and low-loss (Sr6-Ca )Ti2Nb8O30 tungsten bronze ceramics1A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3[Pb(ptz)(OH)(H2O)]: A Hybrid Nonlinear Optical Crystal with Large Birefringence0pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals1pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals141D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation8Topology-Guided Discovery of BaIn 2 Si 7 P 12 : A Quaternary Diamond-like Framework Phosphide with Giant Second-Harmonic Generation and High Laser-Induced Damage Threshold24Achieving phase matching in infrared nonlinear optical crystal Cd3ZnSiS6 via isovalent substitution from Cd4SiS60

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  1. Breaking the bottleneck of simultaneously wide band gap and large nonlinear optical coefficient by a “pore reconstruction” strategy in a salt-inclusion chalcogenide

    Materials Horizons · 2023-01-01

    Shao‐Min Pei, Bin‐Wen Liu, Wen‐Fa Chen, Xiao‐Ming Jiang, Guo‐Cong Guo

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  2. MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Xin Su, Ling Luo, Junjie Li, Feng Yu

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  3. Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold

    Advanced Optical Materials · 2023-05-17

    Jiazheng Zhou, Linan Wang, Yu Chu, Hongshan Wang, Shilie Pan, Junjie Li

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  4. Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites

    Coordination Chemistry Reviews · 2023-05-22

    Zhiyong Bai, Kang Min Ok

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  5. Pinched hysteresis loop and internal bias field in Ba4(La0.2Nd0.2Sm0.2Eu0.2Y0.2)2Ti4Nb6O30 tungsten bronze ceramics

    Journal of Applied Physics · 2023-07-18

    Ying Wang, Xiao Li Zhu, Shu Ya Wu, Xiao Qiang Liu, Xiang Ming Chen

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  6. A I B 3 II C 2 III Q 6 VI X VII : A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS 3 ] and Polycations

    Small · 2023-11-27

    Jiazheng Zhou, Ketian Hou, Yu Chu, Zhihua Yang, Junjie Li, Shilie Pan

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  7. Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

    Angewandte Chemie · 2023-12-20

    Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  8. Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

    Angewandte Chemie International Edition · 2023-12-20

    Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  9. EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response

    Inorganic Chemistry · 2024-05-30

    Yunxia Song, Chensheng Lin, Chao Wang, Yuqiao Zhou, Shenghao Fang, Pengxiang Dong, Bingxuan Li, Ning Ye, Xin Lei Zhao, Min Luo

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  10. Role of Incommensurate Modulation in Ba4(Sm1–xLax)2Ti4Nb6O30 Tetragonal Tungsten Bronzes

    Chemistry of Materials · 2024-07-02

    Jia Wen Song, Yuan Gao, Yi Bang Ou, Xiang Tao Luo, Xing Yu Chen, Xing Yu Chen, Wen Ya Wang, Ying Wang, Shu Ya Wu, Xiao Qiang Liu, Xiao Li Zhu, He Tian, Xiang Ming Chen, Xiang Ming Chen

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  11. Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective

    Advanced Functional Materials · 2024-12-15

    Miriding Mutailipu, Junjie Li, Shilie Pan

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  12. Ca 2 La(MS 4 )(BS 3 ) (M = Ge/Si and Sn/Si): high-performance infrared nonlinear optical materials designed using an atomic site co-occupancy strategy

    Inorganic Chemistry Frontiers · 2025-01-01

    Ya‐Xiang Han, Chun‐Li Hu, Jiang‐Gao Mao

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  13. Chemical Substitution‐Driven Design of a High‐Performance Noncentrosymmetric Bismuth Molybdenum Selenite

    Advanced Optical Materials · 2025-01-17

    Hieu Minh Ngo, Yunseung Kuk, Jihyun Lee, Jiachen Lu, Zhiyong Bai, Chun‐Li Hu, Kang Min Ok

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  14. Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties

    Chemistry of Materials · 2025-01-20

    Yunseung Kuk, Zhiyong Bai, Yang Li, Kang Min Ok

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  15. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie International Edition · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Fang Kong, Jiang‐Gao Mao

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  16. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  17. Synergically Assembling Advantageous Groups toward High‐Performance Infrared Nonlinear Optical Materials A II CdSiSe 4 (A II = Sr, Ba)

    Advanced Functional Materials · 2025-03-24

    Hongshan Wang, Ran An, Zhihua Yang, Shilie Pan, Junjie Li

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  18. SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold

    Optics Express · 2025-03-27

    Hongshan Wang, Ran An, Yi Du, Shilie Pan, Junjie Li

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  19. Wide permittivity stability against temperature of high-permittivity and low-loss (Sr6-Ca )Ti2Nb8O30 tungsten bronze ceramics

    Journal of Alloys and Compounds · 2025-07-01

    Zihang Chen, Yaqing Hu, Huitao Guo, Yiyang Cai, Yanwen Li, Wenzhong Lü, Wen Lei

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  20. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  21. [Pb(ptz)(OH)(H2O)]: A Hybrid Nonlinear Optical Crystal with Large Birefringence

    Inorganic Chemistry · 2025-10-09

    De-Xuan Jiang, Yuhang Wang, Yuxiao Wang, Ling Gao, Song‐De Han, Qi Wei, Li Wei, Guo‐Yu Yang

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  22. pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals

    Angewandte Chemie · 2025-11-06

    Wei Zeng, Jing Zhang, Yao Tian, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Kang Min Ok, Guohong Zou

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  23. pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals

    Angewandte Chemie International Edition · 2025-11-06

    Wei Zeng, Jing Zhang, Yao Tian, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Kang Min Ok, Guohong Zou

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  24. 1D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation

    Chemistry - A European Journal · 2026-02-09

    Mubashar Ilyas, Lin Xiong, Li Zhang, Maida, Maroof Ahmad Khan, Muhammad Abbas, Nagesh Manurkar, Mudassar Ilyas, Niu Zhang, Hui Li

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  25. Topology-Guided Discovery of BaIn 2 Si 7 P 12 : A Quaternary Diamond-like Framework Phosphide with Giant Second-Harmonic Generation and High Laser-Induced Damage Threshold

    Journal of the American Chemical Society · 2026-02-16

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  26. Achieving phase matching in infrared nonlinear optical crystal Cd3ZnSiS6 via isovalent substitution from Cd4SiS6

    Journal of Solid State Chemistry · 2026-04-02

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