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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2020

Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation

Lin Lin, Xingxing Jiang, Chao Wu, Longhua Li, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic GenerationOriginalFirst chiral fluorinated lead vanadate selenite Pb 2 (V 2 O 4 F)(VO 2 )(SeO 3 ) 3 with five asymmetric motifs and large optical properties24Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds39In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.518Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O5CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation47A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation50A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation64Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo 2 O 8 F150Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain15Nonlinear optical properties of a new polar bismuth tellurium oxide fluoride, Bi3F(TeO3)(TeO2F2)315From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence53Two molybdenyl carbonates with different dimensional structures exhibiting huge differences in band gaps7Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodate24Metal oxyhalides: an emerging family of nonlinear optical materials124Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra20Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19Efficient Strategy for Investigating the Third-Order Nonlinear Optical (NLO) Properties of Solid-State Coordination Polymers34A 0.5 H 2 C 6 N 7 O 3 ·4H 2 O (A = Ca 2+ , Sr 2+ ) iso-cyamelurates with ultra-large π-conjugated group and excellent nonlinear optical properties10Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials20A survey of stereoactive oxysalts for linear and nonlinear optical applications40Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Pb 2 Ga 3 F 6 (SeO 3 ) 2 X 3 ·2H 2 O (X = Cl, Br): two new HTO-type members exhibiting large NLO effects mediated by ionic mixing and substitution strategies10AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap20Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups11Chemical Substitution‐Driven Design of a High‐Performance Noncentrosymmetric Bismuth Molybdenum Selenite10New Selenite–Molybdate Family M3(SeO3)2(Mo2O6F2) (M = Co, Ni, Cu): Structure and Magnetism0Extended π-conjugation of D–A ligand enabling a CuI-based hybrid compound as sensitive fluorescent sensor and efficient photodegradation catalyst for tetracycline1Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence1A New Infrared Nonlinear Optical Crystal Ba 5 Zn 3 Ga 2 Sn 2 Se 15 with Congruent Melting Behavior Based on Mixed-Metal T2-Supertetrahedral Units1

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  1. First chiral fluorinated lead vanadate selenite Pb 2 (V 2 O 4 F)(VO 2 )(SeO 3 ) 3 with five asymmetric motifs and large optical properties

    Dalton Transactions · 2021-01-01

    Lin Lin, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  2. Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds

    Chemical Communications · 2021-01-01

    Pengfei Li, Chun‐Li Hu, Ya-Ping Gong, Fang Kong, Jiang‐Gao Mao

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  3. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  4. Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

    Chemical Communications · 2021-01-01

    Fang Kong, Ting-Kun Jiang, Jiang‐Gao Mao

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  5. Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.5

    Chemical Communications · 2021-01-01

    Shuangshuang Shi, Chensheng Lin, Dan Zhao, Min Luo, Liling Cao, Guang Peng, Ning Ye

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  6. Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O

    Journal of Solid State Chemistry · 2021-02-28

    Chao Wu, Lin Lin, Tianhui Wu, Zhipeng Huang, Chi Zhang

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  7. CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation

    Chemistry of Materials · 2021-05-07

    Lin Lin, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  8. A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation

    Chemistry of Materials · 2021-06-23

    Yilei Hu, Xingxing Jiang, Chao Wu, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  9. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  10. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  11. Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo 2 O 8 F

    Journal of the American Chemical Society · 2021-08-09

    Yilei Hu, Chao Wu, Xingxing Jiang, Zujian Wang, Zhipeng Huang, Zheshuai Lin, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  12. Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain

    European Journal of Inorganic Chemistry · 2021-10-12

    Wen‐Dong Yao, Mei Yan, Xiaohui Li, Wenlong Liu, Ru‐Ling Tang

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  13. Nonlinear optical properties of a new polar bismuth tellurium oxide fluoride, Bi3F(TeO3)(TeO2F2)3

    Journal of Alloys and Compounds · 2021-11-11

    Jee Yoon Chung, Seongbeom Yeon, Hongsun Ryu, Tae‐Soo You, Joon Ik Jang, Kang Min Ok

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  14. From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence

    Chemistry of Materials · 2021-11-22

    Tianhui Wu, Xingxing Jiang, Yiran Zhang, Zujian Wang, Hongyuan Sha, Chao Wu, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  15. Two molybdenyl carbonates with different dimensional structures exhibiting huge differences in band gaps

    Inorganic Chemistry Frontiers · 2021-11-26

    Yunqiao Guo, Yalan Deng, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  16. Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodate

    Journal of Materials Chemistry C · 2022-01-01

    Mengmeng Ding, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  17. Metal oxyhalides: an emerging family of nonlinear optical materials

    Chemical Science · 2022-01-01

    Xinglong Chen, Kang Min Ok

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  18. Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra

    Inorganic Chemistry · 2022-01-10

    Yuanyu Yang, Yao Guo, Bingbing Zhang, Ting Wang, Yi-Gang Chen, Xiaohui Hao, Xiaoxiu Yu, Xian‐Ming Zhang

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  19. Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal

    Inorganic Chemistry · 2022-07-13

    Jinmiao Jiao, Fei Liang, Conggang Li, Tao Han, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  20. Efficient Strategy for Investigating the Third-Order Nonlinear Optical (NLO) Properties of Solid-State Coordination Polymers

    Inorganic Chemistry · 2022-07-27

    Kangshuai Geng, Xiaoqian Yang, Yujie Zhao, Yang Cui, Jie Ding, Hongwei Hou

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  21. A 0.5 H 2 C 6 N 7 O 3 ·4H 2 O (A = Ca 2+ , Sr 2+ ) iso-cyamelurates with ultra-large π-conjugated group and excellent nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaoguang Du, Fangyan Wang, Fei Liang, Zhanggui Hu, Yicheng Wu, Xinyuan Zhang

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  22. Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials

    Inorganic Chemistry · 2023-08-02

    Weiyi Wang, Xinyue Wang, Lu Xiong Xu, Die Zhang, Jiale Xue, Shuyao Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  23. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  24. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

    Materials Chemistry Frontiers · 2024-01-01

    Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang

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  25. Pb 2 Ga 3 F 6 (SeO 3 ) 2 X 3 ·2H 2 O (X = Cl, Br): two new HTO-type members exhibiting large NLO effects mediated by ionic mixing and substitution strategies

    Journal of Materials Chemistry C · 2024-01-01

    Lili Liu, Junbo Wang, Bingchen Xiao, Xunchi Li, Yaoqing Chu, Tongqing Sun, P. Shiv Halasyamani

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  26. AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2024-01-18

    Mengmeng Zhu, Junbo Wang, Lei Hou, Yiwen Yuan, Lili Liu, Yaoqing Chu, Chunmei Huang

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  27. Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups

    Inorganic Chemistry · 2024-10-11

    Yanyan Ding, Mengmeng Zhu, Junbo Wang, Bo Li, Hai-Xin Qi, Lili Liu, Yaoqing Chu

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  28. Chemical Substitution‐Driven Design of a High‐Performance Noncentrosymmetric Bismuth Molybdenum Selenite

    Advanced Optical Materials · 2025-01-17

    Hieu Minh Ngo, Yunseung Kuk, Jihyun Lee, Jiachen Lu, Zhiyong Bai, Chun‐Li Hu, Kang Min Ok

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  29. New Selenite–Molybdate Family M3(SeO3)2(Mo2O6F2) (M = Co, Ni, Cu): Structure and Magnetism

    Crystal Growth & Design · 2025-01-25

    Wenhao Zhang, Chao Dong, Meiyan Cui, Tianyu Zhu, Zhiying Zhao, Junfeng Wang, Zhangzhen He

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  30. Extended π-conjugation of D–A ligand enabling a CuI-based hybrid compound as sensitive fluorescent sensor and efficient photodegradation catalyst for tetracycline

    Journal of Catalysis · 2025-08-09

    Yali Yang, Bing Shao, Yi Huang, Bi‐Liu Lan, Min Pan, Zi-Ling Li, Zhong Zhang

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  31. Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2025-11-06

    Tianhui Wu, Jiahang Liu, Meiqi Liu, Xuan Li, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  32. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

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  33. Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence

    Dalton Transactions · 2026-01-01

    Jingsha Xu, Xiaofeng Zhang, Shanshan Chen, Weiyi Wang, Wenbo Qiu, Weizhao Cai, Liujiang Zhou

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  34. A New Infrared Nonlinear Optical Crystal Ba 5 Zn 3 Ga 2 Sn 2 Se 15 with Congruent Melting Behavior Based on Mixed-Metal T2-Supertetrahedral Units

    Crystal Growth & Design · 2026-06-29

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