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RESEARCH PAPER · Elsevier eBooks · 2003

The Actinides

Carol J. Burns, Mary P. Neu, Hakim Boukhalfa, Keith E. Gutowski, Nicholas J. Bridges, Robin Don Rogers

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The ActinidesOriginalEDTA and Mixed-Ligand Complexes of Tetravalent and Trivalent Plutonium64The Actinoids0A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La)62A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La)73Thorium and Thorium Compounds4Extremely Stable Thorium(IV) Dialkyl Complexes Supported by Rigid Tridentate 4,5-Bis(anilido)xanthene and 2,6-Bis(anilidomethyl)pyridine Ligands85Complexation of Pu(IV) with the Natural Siderophore Desferrioxamine B and the Redox Properties of Pu(IV)(siderophore) Complexes70Luminescence from Neptunyl(VI) Species in Solution40Pentavalent Uranium Oxide via Reduction of [UO 2 ] 2+ Under Hydrothermal Reaction Conditions †83Luminescence from the ligand to metal charge transfer state of the neptunyl (V) ion and its complexes in solution4Synthesis and Properties of a Fifteen‐Coordinate Complex: The Thorium Aminodiboranate [Th(H 3 BNMe 2 BH 3 ) 4 ]15Synthesis and Properties of a Fifteen‐Coordinate Complex: The Thorium Aminodiboranate [Th(H3BNMe2BH3)4]98The unusual stability of [NpO2Cl4]2−: Synthesis and characterisation of [NpO2(DPPMO2)2Cl]2[NpO2Cl4] and [Ph3PNH2]2[NpO2Cl4]19Synthesis and structural studies of a bis(carbamoyl methyl) sulfoxide complex of uranyl nitrate5The Reaction Chemistry of Plutonyl(VI) Chloride Complexes with Triphenyl Phosphineoxide and Triphenyl Phosphinimine32Highly Efficient Separation of Actinides from Lanthanides by a Phenanthroline-Derived Bis-triazine Ligand418Use of Soft Heterocyclic N-Donor Ligands To Separate Actinides and Lanthanides348Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes323BTBPs versus BTPhens: Some Reasons for Their Differences in Properties Concerning the Partitioning of Minor Actinides and the Advantages of BTPhens165Exploring Actinide Materials Through Synchrotron Radiation Techniques104A new solvated complex of the uranyl ion (UO22+) with 8-hydroxyquinoline8Coordination Modes of Americium in the Am2(C2O4)3(H2O)6·4H2O Oxalate: Synthesis, Crystal Structure, Spectroscopic Characterizations and Comparison in the M2(C2O4)3(H2O)6·nH2O (M = Ln, An) Series37Synthesis, Structures, and Proton Self-Exchange Reaction of μ3-Oxido/Hydroxido Bridged Trinuclear Uranyl(VI) Complexes with Tridentate Schiff-Base Ligands15Exploring Actinide Materials through Synchrotron Radiation Techniques4Actinides: Pentavalent Organometallics1Continuous Shape Measures Study of the Coordination Spheres of Actinide Complexes – Part 1: Low Coordination Numbers19Electrochemical recovery of plutonium from aqueous carbonate waste solutions4Comparative DFT study of americium and europium complexation with 2,9-bis(1,2-diazin-3-yl)-1,10-phenanthroline ligand in gas phase3Structural modulation of insulin by hydrophobic and hydrophilic molecules12A new mixed-ligand mononuclear Co(II) complex derived from 4,4,4-trifluoro-1-phenylbutane-1,3-dione and 1,10-phenanthroline: Synthesis, structural elucidation and quantum-computational studies4Untitled work0Uranium separation from urine matrix using amidoximated crosslinked polyacrylonitrile adsorbent2Prediction of Actinide–Ligand Complex Stability Constants by Machine Learning8Equatorial Ligation Controls 5f Electron Binding in Penta- and Hexavalent Uranyl Acetate Complexes1

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  1. EDTA and Mixed-Ligand Complexes of Tetravalent and Trivalent Plutonium

    Inorganic Chemistry · 2004-08-28

    Hakim Boukhalfa, Sean D. Reilly, Wayne H. Smith, Mary P. Neu

    Read original paper ↗ ·

  2. The Actinoids

    ChemInform · 2004-09-06

    C. J. Burns, Mary P. Neu, Hakim Boukhalfa, Keith E. Gutowski, N. J. Bridges, R. D. Rogers

    Read original paper ↗ ·

  3. A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La)

    Angewandte Chemie · 2006-02-06

    Andrew J. Gaunt, Brian L. Scott, Mary P. Neu

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  4. A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La)

    Angewandte Chemie International Edition · 2006-02-06

    Andrew J. Gaunt, Brian L. Scott, Mary P. Neu

    Read original paper ↗ ·

  5. Thorium and Thorium Compounds

    Kirk-Othmer Encyclopedia of Chemical Technology · 2006-09-15

    David L. Clark, Mary P. Neu, Wolfgang Runde, D. Webster Keogh

    Read original paper ↗ ·

  6. Extremely Stable Thorium(IV) Dialkyl Complexes Supported by Rigid Tridentate 4,5-Bis(anilido)xanthene and 2,6-Bis(anilidomethyl)pyridine Ligands

    Organometallics · 2007-01-01

    Carlos A. Cruz, David J. H. Emslie, L.E. Harrington, James F. Britten, Craig M. Robertson

    Read original paper ↗ ·

  7. Complexation of Pu(IV) with the Natural Siderophore Desferrioxamine B and the Redox Properties of Pu(IV)(siderophore) Complexes

    Inorganic Chemistry · 2007-01-11

    Hakim Boukhalfa, Sean D. Reilly, Mary P. Neu

    Read original paper ↗ ·

  8. Luminescence from Neptunyl(VI) Species in Solution

    Journal of the American Chemical Society · 2007-02-13

    Caytie E. Talbot-Eeckelaers, Simon J. A. Pope, Amanda J. Hynes, Roy Copping, Chris J. Jones, Robin J. Taylor, Stephen Faulkner, Daniel Sykes, Francis R. Livens, Iain May

    Read original paper ↗ ·

  9. Pentavalent Uranium Oxide via Reduction of [UO 2 ] 2+ Under Hydrothermal Reaction Conditions †

    Inorganic Chemistry · 2008-10-09

    Nebebech Belai, M. Frisch, Eugene S. Ilton, Bruce Ravel, Christopher L. Cahill

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  10. Luminescence from the ligand to metal charge transfer state of the neptunyl (V) ion and its complexes in solution

    IOP Conference Series Materials Science and Engineering · 2010-03-01

    Rebecca Bradshaw, Daniel Sykes, Louise S. Natrajan, Robin J. Taylor, Francis R. Livens, Stephen Faulkner

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  11. Synthesis and Properties of a Fifteen‐Coordinate Complex: The Thorium Aminodiboranate [Th(H 3 BNMe 2 BH 3 ) 4 ]

    Angewandte Chemie · 2010-03-20

    Scott R. Daly, P.M.B. Piccoli, Arthur J. Schultz, Tanya Kumanova Todorova, Laura Gagliardi, Gregory S. Girolami

    Read original paper ↗ ·

  12. Synthesis and Properties of a Fifteen‐Coordinate Complex: The Thorium Aminodiboranate [Th(H3BNMe2BH3)4]

    Angewandte Chemie International Edition · 2010-03-20

    Scott R. Daly, P.M.B. Piccoli, Arthur J. Schultz, Tanya Kumanova Todorova, Laura Gagliardi, Gregory S. Girolami

    Read original paper ↗ ·

  13. The unusual stability of [NpO2Cl4]2−: Synthesis and characterisation of [NpO2(DPPMO2)2Cl]2[NpO2Cl4] and [Ph3PNH2]2[NpO2Cl4]

    Comptes Rendus Chimie · 2010-06-01

    S.M. Cornet, Michael P. Redmond, David Collison, Clint A. Sharrad, M. Helliwell, John E. Warren

    Read original paper ↗ ·

  14. Synthesis and structural studies of a bis(carbamoyl methyl) sulfoxide complex of uranyl nitrate

    Journal of Coordination Chemistry · 2010-09-14

    Sadhan Bijoy Deb, S. Kannan, Michael G. B. Drew

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  15. The Reaction Chemistry of Plutonyl(VI) Chloride Complexes with Triphenyl Phosphineoxide and Triphenyl Phosphinimine

    Inorganic Chemistry · 2010-09-14

    Claude Berthon, N. Boubals, I. A. Charushnikova, David Collison, S.M. Cornet, Christophe Den Auwer, Andrew J. Gaunt, Nikolas Kaltsoyannis, Iain May, Sebastien Petit, Michael P. Redmond, Sean D. Reilly, Brian L. Scott

    Read original paper ↗ ·

  16. Highly Efficient Separation of Actinides from Lanthanides by a Phenanthroline-Derived Bis-triazine Ligand

    Journal of the American Chemical Society · 2011-07-19

    Frank W. Lewis, Laurence M. Harwood, Michael James Hudson, Michael G. B. Drew, Jean François Desreux, Geoffrey Vidick, Nouri Bouslimani, Giuseppe Modolo, Andreas Wilden, Michal Sypula, Trong-Hung Vu, Jean‐Pierre Simonin

    Read original paper ↗ ·

  17. Use of Soft Heterocyclic N-Donor Ligands To Separate Actinides and Lanthanides

    Inorganic Chemistry · 2012-08-06

    Michael James Hudson, Laurence M. Harwood, Dominic M. Laventine, Frank W. Lewis

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  18. Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes

    Chemical Reviews · 2012-11-07

    M.B. Jones, Andrew J. Gaunt

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  19. BTBPs versus BTPhens: Some Reasons for Their Differences in Properties Concerning the Partitioning of Minor Actinides and the Advantages of BTPhens

    Inorganic Chemistry · 2013-04-24

    Frank W. Lewis, Laurence M. Harwood, Michael James Hudson, Michael G. B. Drew, Véronique Hubscher‐Bruder, Vladimira S. Videva, Françoise Arnaud‐Neu, K. Štamberg, Shyam Vyas

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  20. Exploring Actinide Materials Through Synchrotron Radiation Techniques

    Advanced Materials · 2014-08-28

    Wei‐Qun Shi, Li‐Yong Yuan, Cong‐Zhi Wang, Lin Wang, Lei Mei, Chengliang Xiao, Li Zhang, Zi‐Jie Li, Yuliang Zhao, Zhifang Chai

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  21. A new solvated complex of the uranyl ion (UO22+) with 8-hydroxyquinoline

    Inorganica Chimica Acta · 2014-12-10

    Masoud Mirzaei, Azam Hassanpoor, Antonio Bauzá, Joel T. Mague, Antonio Frontera

    Read original paper ↗ ·

  22. Coordination Modes of Americium in the Am2(C2O4)3(H2O)6·4H2O Oxalate: Synthesis, Crystal Structure, Spectroscopic Characterizations and Comparison in the M2(C2O4)3(H2O)6·nH2O (M = Ln, An) Series

    Inorganic Chemistry · 2015-12-16

    C. Tamain, Bénédicte Arab-Chapelet, Murielle Rivenet, X.F. Le Goff, Gaël Loubert, S. Grandjean, F. Abraham

    Read original paper ↗ ·

  23. Synthesis, Structures, and Proton Self-Exchange Reaction of μ3-Oxido/Hydroxido Bridged Trinuclear Uranyl(VI) Complexes with Tridentate Schiff-Base Ligands

    Inorganic Chemistry · 2017-03-10

    Takashi Yoshimura, Masayuki Nakaguchi, Keisuke Morimoto

    Read original paper ↗ ·

  24. Exploring Actinide Materials through Synchrotron Radiation Techniques

    Unknown journal · 2018-02-16

    Wei‐Qun Shi, Li‐Yong Yuan, Cong‐Zhi Wang, Lin Wang, Lei Mei, Chengliang Xiao, Li Zhang, Zi‐Jie Li, Yuliang Zhao, Zhifang Chai

    Read original paper ↗ ·

  25. Actinides: Pentavalent Organometallics

    Encyclopedia of Inorganic and Bioinorganic Chemistry · 2018-09-14

    Jesse Murillo, Skye Fortier

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  26. Continuous Shape Measures Study of the Coordination Spheres of Actinide Complexes – Part 1: Low Coordination Numbers

    European Journal of Inorganic Chemistry · 2021-07-26

    Santiago Álvarez

    Read original paper ↗ ·

  27. Electrochemical recovery of plutonium from aqueous carbonate waste solutions

    Chemical Communications · 2021-12-17

    Rahul Agarwal, Rama Mohana Rao Dumpala, Manoj K. Sharma, D. M. Noronha, J.S. Gamare, Kavitha Jayachandran, Chiranjit Nandi, Santu Kaity

    Read original paper ↗ ·

  28. Comparative DFT study of americium and europium complexation with 2,9-bis(1,2-diazin-3-yl)-1,10-phenanthroline ligand in gas phase

    Computational and Theoretical Chemistry · 2022-01-01

    Jaanus Burk, Lauri Sikk, Kaido Tämm, Peeter Burk

    Read original paper ↗ ·

  29. Structural modulation of insulin by hydrophobic and hydrophilic molecules

    RSC Advances · 2023-01-01

    Shahnaz Begum, Hasan Parvej, Ramkrishna Dalui, Swarnali Paul, Sanhita Maity, Nayim Sepay, Mohd Faiz Afzal, Umesh Chandra Halder

    Read original paper ↗ ·

  30. A new mixed-ligand mononuclear Co(II) complex derived from 4,4,4-trifluoro-1-phenylbutane-1,3-dione and 1,10-phenanthroline: Synthesis, structural elucidation and quantum-computational studies

    Journal of Molecular Structure · 2023-12-02

    M.K. Hema, Chimatahalli Shanthakumar Karthik, Jothi Ramalingam Rajabathar, Hamad A. Al‐Lohedan, Hassan Al-Saigh, Selvaraj Arokiyaraj, Dafellah M Aldayan, Neratur Krishnappagowda Lokanath

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  31. Untitled work

    Journal of Research in Chemistry · 2025-01-01

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  32. Uranium separation from urine matrix using amidoximated crosslinked polyacrylonitrile adsorbent

    Journal of Radioanalytical and Nuclear Chemistry · 2025-01-06

    Supreetha P. Prabhu, Amit Kanjilal, Sonali Gondane, Pramilla D. Sawant, Awadhesh Kumar, Probal Chaudhury, Mukund S. Kulkarni

    Read original paper ↗ ·

  33. Prediction of Actinide–Ligand Complex Stability Constants by Machine Learning

    The Journal of Physical Chemistry A · 2025-05-08

    Junhong Li, Junqing Li, Ziyi Liu, Dongqi Wang

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  34. Equatorial Ligation Controls 5f Electron Binding in Penta- and Hexavalent Uranyl Acetate Complexes

    The Journal of Physical Chemistry A · 2026-02-18

    Burak A. Tufekci, Taylor Gregory, S. Y. Wang, Kathryn Foreman, Tatsuya Chiba, Evangelos Miliordos, Kit H. Bowen

    Read original paper ↗ ·
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