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RESEARCH PAPER · Inorganic Chemistry · 2019

Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O5

Qian Wang, Fei Yang, Xing Wang, Jing Wen Zhou, Jia Ju, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O5OriginalCentrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size63Rb7SrY2(B5O10)3: A Rare-Earth Pentaborate with Moderate Second-Harmonic Response and Interesting Phase-Matching Behavior29Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)33Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)17Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions21(NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization31RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence37Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff Edges26PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material120K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence61A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters50The study of structure evolvement of KTiOPO4 family and their nonlinear optical properties98CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure49A new rare-earth borate birefringent crystal with quasi-two-dimensional [BO 3 ] layers23K 3 Na(TaF 7 )(SiF 6 ): a mixed-anion pentanary fluoride with zero-dimensional anions exhibiting a large band gap14NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers10Optimization of fluxes for Yb 3+ :YMgB 5 O 10 crystal growth and intense multi-wavelength emission characteristics in spectra and laser performances14BO3 Triangle and B@Zn2O3 Cationic Layer in the Structure of the Hybrid Zinc Acetate Borate [ZnAc]·[ZnBO3]9Three-in-One Strategy Constructing a Series of Hybrid Tetrahedral Motif-Based Selenides with Balanced Second-Order Nonlinear Optical Performance12Two Chiral Metal Complex Templated Aluminoborates Constructed from Three Types of Oxoboron Clusters17Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials33K5Mg2La3(BO3)6: An Efficient, Deep-Ultraviolet Nonlinear Optical Material70Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)214NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents38Syntheses, structures and optical properties of two B 3 O 7 cluster-based borates9Cd4InO(BO3)3: A New Nonlinear Optical Crystal Exhibiting Strong Second Harmonic Generation Effect and Moderate Birefringence2Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate36Yin–Yang Complementarity Strategy Achieving Giant Optical Anisotropy in a Metal-free Birefringent Material C(NH2)3(HC4O4)14Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates58Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties24Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Efficient Synthesis, Spectroscopic Characterization, and Nonlinear Optical Properties of Novel Salicylaldehyde-Based Thiosemicarbazones: Experimental and Theoretical Studies37Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates18Achieving strong second harmonic generation effects induced via dimensional increase of PbX 6 octahedra and halogen substitutes in (C 10 H 11 N 3 )PbX 4 (X = Cl or Br)26Modulating the birefringence of two-dimensional hybrid lead bromide perovskites using pyridine derivative cations11Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O3M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units19Enhanced optical anisotropy of six-coordinated silica polymorphs via high-pressure hydrothermal treatment1Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices1Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal6LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response2Anionic configuration extension induced birefringence enhancement in vanadium iodate oxyfluorides0

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  1. Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size

    Inorganic Chemistry Frontiers · 2019-01-01

    Qian Wang, Lei Wang, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  2. Rb7SrY2(B5O10)3: A Rare-Earth Pentaborate with Moderate Second-Harmonic Response and Interesting Phase-Matching Behavior

    Inorganic Chemistry · 2019-07-02

    Yunfei Li, Fei Liang, Huimin Song, Wang Liu, Zheshuai Lin, Guochun Zhang, Yicheng Wu

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  3. Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)

    Inorganic Chemistry · 2019-07-31

    Ya-Ping Gong, Yun‐Xiang Ma, Shao‐Ming Ying, Jiang‐Gao Mao, Fang Kong

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  4. Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)

    Inorganic Chemistry · 2019-09-18

    Wenyao Zhang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  5. Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions

    Dalton Transactions · 2019-10-27

    Ru‐Ling Tang, Chun‐Li Hu, Jianghe Feng, Zhi Gang Fang, Yan Chen, Fang Kong, Jiang‐Gao Mao

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  6. (NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization

    Chemical Communications · 2020-01-01

    Yalan Deng, Lei Wang, Yuwei Ge, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  7. RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence

    Chemical Communications · 2020-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  8. Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2020-02-10

    Wenyao Zhang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  9. PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material

    Chemistry of Materials · 2020-02-11

    Shujuan Han, Miriding Mutailipu, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  10. K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence

    Journal of Alloys and Compounds · 2020-04-15

    Fei Yang, Lei Wang, Yuwei Ge, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  11. A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters

    Inorganic Chemistry · 2020-05-22

    Xuehua Dong, Ying Long, Xiaoyu Zhao, Ling Huang, Hongmei Zeng, Zhien Lin, Xin Wang, Guohong Zou

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  12. The study of structure evolvement of KTiOPO4 family and their nonlinear optical properties

    Coordination Chemistry Reviews · 2020-08-08

    Fei Yang, Lei Wang, Ling Huang, Guohong Zou

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  13. CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure

    Inorganic Chemistry · 2020-08-26

    Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  14. A new rare-earth borate birefringent crystal with quasi-two-dimensional [BO 3 ] layers

    Journal of Materials Chemistry C · 2021-01-01

    Hongyuan Sha, Bingxuan Li, Zheyao Xiong, Zujian Wang, Caiping Liu, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  15. K 3 Na(TaF 7 )(SiF 6 ): a mixed-anion pentanary fluoride with zero-dimensional anions exhibiting a large band gap

    Dalton Transactions · 2021-01-01

    Ru‐Ling Tang, Xin Lian, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  16. NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers

    New Journal of Chemistry · 2021-01-01

    Zilong Chen, Junwei Feng, Bin Dai, Feng Yu

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  17. Optimization of fluxes for Yb 3+ :YMgB 5 O 10 crystal growth and intense multi-wavelength emission characteristics in spectra and laser performances

    Journal of Materials Chemistry C · 2021-01-01

    Shijia Sun, Bingxuan Li, Fei Lou, Xingjun Shi, Weidong Chen, Feifei Yuan, Lizhen Zhang, Zhoubin Lin, Degao Zhong, Yisheng Huang, Bing Teng

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  18. BO3 Triangle and B@Zn2O3 Cationic Layer in the Structure of the Hybrid Zinc Acetate Borate [ZnAc]·[ZnBO3]

    Inorganic Chemistry · 2021-01-08

    Wei Li, Jun-Xia Deng, Chun‐Yang Pan

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  19. Three-in-One Strategy Constructing a Series of Hybrid Tetrahedral Motif-Based Selenides with Balanced Second-Order Nonlinear Optical Performance

    Inorganic Chemistry · 2021-04-15

    Xiaohui Li, Wen‐Dong Yao, Yu-Long Wei, Sheng‐Ping Guo

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  20. Two Chiral Metal Complex Templated Aluminoborates Constructed from Three Types of Oxoboron Clusters

    Inorganic Chemistry · 2021-04-23

    Dan Qin, Hai-Liang Pei, Chong‐An Chen, Guo‐Yu Yang

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  21. Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials

    Inorganic Chemistry · 2021-05-14

    Yuwei Ge, Qiang Wang, Fei Yang, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  22. K5Mg2La3(BO3)6: An Efficient, Deep-Ultraviolet Nonlinear Optical Material

    Chemistry of Materials · 2021-05-21

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  23. Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)2

    Crystal Growth & Design · 2021-09-17

    Yunqiao Guo, Die Zhang, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  24. NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents

    Journal of Alloys and Compounds · 2021-11-24

    Die Zhang, Qiang Wang, Ting Zheng, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  25. Syntheses, structures and optical properties of two B 3 O 7 cluster-based borates

    CrystEngComm · 2022-01-01

    Chong‐An Chen, Guo‐Yu Yang

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  26. Cd4InO(BO3)3: A New Nonlinear Optical Crystal Exhibiting Strong Second Harmonic Generation Effect and Moderate Birefringence

    Crystals · 2022-02-15

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  27. Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

    Inorganic Chemistry · 2022-03-01

    Wen-Zhuo Zhao, Yinan Zhang, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  28. Yin–Yang Complementarity Strategy Achieving Giant Optical Anisotropy in a Metal-free Birefringent Material C(NH2)3(HC4O4)

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    Hongmei Wang, Qiang Wang, Qin Wang, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  29. Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates

    Science China Materials · 2022-07-05

    Die Zhang, Qiang Wang, Ting Zheng, Liling Cao, Kang Min Ok, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  30. Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties

    Inorganic Chemistry · 2023-01-06

    Xuyan Li, Jinhua Li, Jian‐Wen Cheng, Guo‐Yu Yang

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  31. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  32. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  33. Efficient Synthesis, Spectroscopic Characterization, and Nonlinear Optical Properties of Novel Salicylaldehyde-Based Thiosemicarbazones: Experimental and Theoretical Studies

    ACS Omega · 2023-04-07

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  34. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

    Molecules · 2023-06-28

    Jinɡjinɡ Li, Weifeng Chen, You‐Zhao Lan, Jian‐Wen Cheng

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  35. A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates

    Chemical Science · 2024-01-01

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  36. Achieving strong second harmonic generation effects induced via dimensional increase of PbX 6 octahedra and halogen substitutes in (C 10 H 11 N 3 )PbX 4 (X = Cl or Br)

    Inorganic Chemistry Frontiers · 2024-01-01

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  37. Modulating the birefringence of two-dimensional hybrid lead bromide perovskites using pyridine derivative cations

    Inorganic Chemistry Frontiers · 2024-01-01

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  38. Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O

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  39. M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion

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    Weifeng Chen, Mei-Jun Zou, Jinɡjinɡ Li, Yinan Zhang, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  40. Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units

    Science China Chemistry · 2024-08-19

    Jinbin Fan, Ziting Yan, Zilong Chen, Huimin Li, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  41. Enhanced optical anisotropy of six-coordinated silica polymorphs via high-pressure hydrothermal treatment

    Journal of Materials Chemistry C · 2024-11-14

    Junwei Li, Yanqiang Li, Weiqi Huang, Takayuki Ishii, Yanhao Lin, Binbin Yue, Sangen Zhao, Qingyang Hu

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  42. Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices

    New Journal of Chemistry · 2024-11-20

    Changyou Liu, Xu Liu, Qiuyuan Feng, Ketian Hou, Bei Zhang, Juanjuan Lu

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  43. Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal

    Chinese Chemical Letters · 2025-01-07

    Ning Yang, Huijian Zhao, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Conggang Li

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  44. LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-12-11

    Mingyue Gu, Hu Liu, Xianchao Zhu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  45. Anionic configuration extension induced birefringence enhancement in vanadium iodate oxyfluorides

    Chemical Communications · 2026-01-01

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