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RESEARCH PAPER · Chemical Communications · 2020

RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence

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RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringenceOriginalBa 4 Ca(B 2 O 5 ) 2 F 2 : π-conjugation of B 2 O 5 in the planar pentagonal layer achieving large second harmonic generation of pyro -borate34BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase19Na 2 La 2 B 10 O 19 : a new lanthanum sodium borate with infinite 2D layer 2∞[B 10 O 19 ] 8− and moderate birefringence4RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers9SrAlB3O6F2: A Fluoroaluminoborate with [Al2B6O14F4] Units and Large Birefringence22NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate7Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion133Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion13CsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group8Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4Potential optical functional crystals with large birefringence: Recent advances and future prospects322LiB5O5F2(OH)4: A new deep-ultraviolet birefringent crystal with [B5O5F2(OH)4] anionic group28An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains185NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge5Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence18Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units18Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge14Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge9CaB2O2F4: A Novel [BOF2]∞-Based Structural Template with a Strong Second Harmonic Generation Response and Large Band Gap2Li4AAl(SO4)2F4 (A = Cs, Rb): two deep-UV fluoroaluminosulfates with special motif [AlS2O8F4]1Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure6Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence9YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Borosilicate-Based Framework: Synthesis, Single-Crystal Structure Study, and Physical Properties5Enhanced Birefringence in Phosphates via “Two Steps in One”: d0 Transition Metal Regulation and Fluorination Synergistic Strategy7Review on birefringence in borates based on birefringence-active functional groups and arrangements57Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units19Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge3Anion-Ordered [B3O5(OH)2] Induced by Crystal Water with Deep Ultraviolet Transparency and Large Birefringence in Boron-Rich Borophosphates4High‐Throughput Discovery of Large Birefringence Materials in Mixed‐N Hf‐O Systems0[C 3 N 2 H 5 ]B 7 O 10 F 2 : Demonstrating a New Hydrogen‐Bond‐Induced Intralayer Charge‐Balanced Structure Model with Large Birefringence3Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation0

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  1. Ba 4 Ca(B 2 O 5 ) 2 F 2 : π-conjugation of B 2 O 5 in the planar pentagonal layer achieving large second harmonic generation of pyro -borate

    Chemical Science · 2021-01-01

    Shuaishuai Li, Xiaomeng Liu, Hongping Wu, Zhongfu Song, Hongwei Yu, Zheshuai Lin, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  2. BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase

    Chemical Communications · 2021-01-01

    Wenbin Zhang, Siru Guo, Shujuan Han, Liying Wang, Xin Hua Zhou, Zhihua Yang, Shilie Pan

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  3. Na 2 La 2 B 10 O 19 : a new lanthanum sodium borate with infinite 2D layer 2∞[B 10 O 19 ] 8− and moderate birefringence

    New Journal of Chemistry · 2021-01-01

    Chengfa Wu, Junwei Feng, Feng Yu

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  4. RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers

    Dalton Transactions · 2021-01-01

    Rui Zhang, Xin Su, Jie Zhang, Mingyao Xiong, Yineng Huang

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  5. SrAlB3O6F2: A Fluoroaluminoborate with [Al2B6O14F4] Units and Large Birefringence

    Inorganic Chemistry · 2021-06-24

    Shuo Bai, Xiaodong Zhang, Bingbing Zhang, Ling Li, Ying Wang

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  6. NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate

    Chemistry - An Asian Journal · 2021-08-20

    Rui Zhang, Jie Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  7. Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion

    Angewandte Chemie International Edition · 2021-12-21

    Huanhuan Cheng, Fuming Li, Zhihua Yang, Shilie Pan

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  8. Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion

    Angewandte Chemie · 2021-12-21

    Huanhuan Cheng, Fuming Li, Zhihua Yang, Shilie Pan

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  9. CsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group

    Dalton Transactions · 2022-01-01

    Xinyue Wang, Bingbing Zhang, Daqing Yang, Ying Wang

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  10. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Zhikang Chen, Kewang Zhang, Bei Zhang, Jun Zhang

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  11. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  12. LiB5O5F2(OH)4: A new deep-ultraviolet birefringent crystal with [B5O5F2(OH)4] anionic group

    Science China Materials · 2022-03-23

    Zilong Chen, Hao Zeng, Dongdong Chu, Fangfang Zhang, Meng Cheng, Zhihua Yang, Shilie Pan

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  13. An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains

    Light Science & Applications · 2022-08-12

    Fangfang Zhang, Xinglong Chen, Min Zhang, Wenqi Jin, Shujuan Han, Zhihua Yang, Shilie Pan

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  14. NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2022-08-18

    Yu Dang, Dongdong Chu, Zhihua Yang, Hongsheng Shi, Shilie Pan

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  15. Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation

    Materials Today Chemistry · 2023-01-01

    Huanhuan Cheng, Z. Li, Fromenteze Zhang, Zhihua Yang, Shilie Pan

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  16. BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-01-04

    Jinbin Fan, Mengfan Wu, Bingliang Cheng, Jian Wei Han

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  17. Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence

    Inorganic Chemistry · 2023-01-09

    Gang-Xiang Liu, Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  18. Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-03

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  19. Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units

    Inorganic Chemistry · 2023-02-16

    Mei Hu, Nuerbiye Tuerhong, Zhaohui Chen, Qun Jing, Ming‐Hsien Lee

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  20. Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge

    Science China Chemistry · 2023-02-23

    Huan Pei, Xuefei Wang, Jie Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  21. Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-03-16

    Tuohetijiang Baiheti, Abudukadi Tudi, Minqiang Gai, Xuping Wang, Shujuan Han

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  22. CaB2O2F4: A Novel [BOF2]∞-Based Structural Template with a Strong Second Harmonic Generation Response and Large Band Gap

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    Evgenii Tikhonov, Huanhuan Cheng, Abudukadi Tudi, Congwei Xie, Shilie Pan, Zhihua Yang

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  23. Li4AAl(SO4)2F4 (A = Cs, Rb): two deep-UV fluoroaluminosulfates with special motif [AlS2O8F4]

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    Bao Jiang, Yuchen Yan, Xinglong Liu, Boxuan Zhang, Zhaohui Chen

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  24. Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure

    Inorganic Chemistry · 2023-05-09

    Shuzhao Huang, Liang Zhu, Ivan A. Kruglov, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  25. Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence

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  26. YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra

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    Dong‐Xue Jiao, Huili Zhang, Xiao-Fei Li, Chao He, Jinhua Li, Qi Wei, Guo‐Yu Yang

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  27. Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates

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  28. Borosilicate-Based Framework: Synthesis, Single-Crystal Structure Study, and Physical Properties

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  29. Enhanced Birefringence in Phosphates via “Two Steps in One”: d0 Transition Metal Regulation and Fluorination Synergistic Strategy

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  30. Review on birefringence in borates based on birefringence-active functional groups and arrangements

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  31. Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units

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  32. Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)

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  33. CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge

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  34. Anion-Ordered [B3O5(OH)2] Induced by Crystal Water with Deep Ultraviolet Transparency and Large Birefringence in Boron-Rich Borophosphates

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