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RESEARCH PAPER · Inorganic Chemistry · 2019

Rb7SrY2(B5O10)3: A Rare-Earth Pentaborate with Moderate Second-Harmonic Response and Interesting Phase-Matching Behavior

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Rb7SrY2(B5O10)3: A Rare-Earth Pentaborate with Moderate Second-Harmonic Response and Interesting Phase-Matching BehaviorOriginalLiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates44Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)17A new non-centrosymmetric Gd-based borate crystal Rb 7 SrGd 2 (B 5 O 10 ) 3 : growth, structure, and nonlinear optical and magnetic properties24New double holmium borates: Rb3HoB6O12 and Rb3Ho2B3O910Nonlinear-Optical Crystal Rb3YB6O12 with Condensed B5O10 Blocks That Exhibits an Intriguing Structural Arrangement and a Short Ultraviolet Absorption Edge26Syntheses, structure determination and characterization of two novel non-centrosymmetric mixed alkali rare-earth orthoborates: K3Li3RE7(BO3)9 (RE=Dy, Tb)7Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Borates: A Rich Source for Optical Materials1089Efficient Bi 3+ to Eu 3+ energy transfer and color tunable emissions in K 7 CaY 2 (B 5 O 10 ) 3 -based phosphors22Large Magnetocaloric Effect in Li3K9Gd3(BO3)7 Crystal Featuring Sandwich-Like Three-Dimensional Framework22A non–centrosymmetric compound K7Li2Y2B15O30 by introducing more alkali metals into A7MRe2B15O30 family10Two non-centrosymmetric mixed alkali metal and alkaline earth metal scandium borate nonlinear optical materials with short ultraviolet cutoff edges14Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals12A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups22A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates18Assembly of π‐Conjugated [B 3 O 6 ] Units by Mer‐Isomer [YO 3 F 3 ] Octahedra to Design a UV Nonlinear Optical Material, Cs 2 YB 3 O 6 F 211Assembly of π‐Conjugated [B3O6] Units by Mer‐Isomer [YO3F3] Octahedra to Design a UV Nonlinear Optical Material, Cs2YB3O6F297Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4Search for New Members of the Abre(B15o30)N Family with Significant Shg Effects Based on Chemical Substitution Strategy0Search for New Members of the Abre(B15o30)N Family with Significant Shg Effects Based on Chemical Substitution Strategy0Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups3Rb 7 PbY 2 (B 5 O 10 ) 3 : A Noncentrosymmetric Rare-Earth Borate Nonlinear Optical Crystal with [B 5 O 10 ] Unit16Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Search for new nonlinear optical materials via chemical substitution and combined structural studies in alkali metal rare-earth borates3K 7 MgY 2 (B 5 O 10 ) 3 : a novel ultraviolet nonlinear optical crystal based on the [B 5 O 10 ] functional unit2Two scandium borate UV NLO crystals designed through chemical element substitution1Two Rare Earth-Based Sulfates with Enhanced Birefringence and Broad Optical Transparency Window0Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials0

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  1. LiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates

    Inorganic Chemistry Frontiers · 2019-01-01

    Xianghe Meng, Fei Liang, Jian Tang, Kaijin Kang, Wenlong Yin, Tixian Zeng, Bin Kang, Zheshuai Lin, Mingjun Xia

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  2. Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)

    Inorganic Chemistry · 2019-09-18

    Wenyao Zhang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  3. A new non-centrosymmetric Gd-based borate crystal Rb 7 SrGd 2 (B 5 O 10 ) 3 : growth, structure, and nonlinear optical and magnetic properties

    Dalton Transactions · 2020-01-01

    Wang Liu, Xiaomeng Liu, Jun Shen, Yunfei Li, Huimin Song, Jingcheng Feng, Zheshuai Lin, Guochun Zhang

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  4. New double holmium borates: Rb3HoB6O12 and Rb3Ho2B3O9

    Solid State Sciences · 2020-04-22

    Alexey Karpovich Subanakov, Evgeniy V. Kovtunets, Баир Гармаевич Базаров, Sesegma G. Dorzhieva, Jibzema G. Bazarova

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  5. Nonlinear-Optical Crystal Rb3YB6O12 with Condensed B5O10 Blocks That Exhibits an Intriguing Structural Arrangement and a Short Ultraviolet Absorption Edge

    Inorganic Chemistry · 2020-09-04

    Zhen Jia, Qindan Zeng, Pifu Gong, Dong Yan, Xiuling Zhang, Bingwei Xin, Zheshuai Lin, Mingjun Xia

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  6. Syntheses, structure determination and characterization of two novel non-centrosymmetric mixed alkali rare-earth orthoborates: K3Li3RE7(BO3)9 (RE=Dy, Tb)

    Solid State Sciences · 2020-10-01

    P.Y. Chen, Guirong Wang

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  7. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

    Inorganic Chemistry Frontiers · 2020-10-26

    Pengfei Li, Chun‐Li Hu, Fang Kong, Shao‐Ming Ying, Jiang‐Gao Mao

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  8. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  9. Efficient Bi 3+ to Eu 3+ energy transfer and color tunable emissions in K 7 CaY 2 (B 5 O 10 ) 3 -based phosphors

    Dalton Transactions · 2021-01-01

    Hua Chen, Yan Gao, Pengfei Jiang, Rihong Cong, Tao Yang

    Read original paper ↗ ·
  10. Large Magnetocaloric Effect in Li3K9Gd3(BO3)7 Crystal Featuring Sandwich-Like Three-Dimensional Framework

    Inorganic Chemistry · 2021-04-12

    Wang Liu, Fei Liang, Yuwei Chen, Huimin Song, Jingcheng Feng, Jun Shen, Zheshuai Lin, Heng Tu, Guochun Zhang

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  11. A non–centrosymmetric compound K7Li2Y2B15O30 by introducing more alkali metals into A7MRe2B15O30 family

    Journal of Solid State Chemistry · 2021-10-04

    Jingfang Zhou, Rukang K. Li

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  12. Two non-centrosymmetric mixed alkali metal and alkaline earth metal scandium borate nonlinear optical materials with short ultraviolet cutoff edges

    Dalton Transactions · 2023-01-01

    Wenhao Liu, Ming‐Hsien Lee, Ruixin Guo, Jiyong Yao

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  13. Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals

    Crystal Growth & Design · 2023-08-21

    Chengfa Wu, Yu Dang, Jianbang Chen, Xueling Hou, Hongsheng Shi

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  14. A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups

    Chemical Science · 2024-01-01

    Shuaifeng Li, Weiming Li, Xiang Li, Guangsai Yang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  15. A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates

    Chemical Science · 2024-01-01

    Jie Song, Huijian Zhao, Conggang Li, Ning Ye, Zhanggui Hu, Yicheng Wu

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  16. Assembly of π‐Conjugated [B 3 O 6 ] Units by Mer‐Isomer [YO 3 F 3 ] Octahedra to Design a UV Nonlinear Optical Material, Cs 2 YB 3 O 6 F 2

    Angewandte Chemie · 2024-05-07

    Hongping Wu, Zhijun Wei, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  17. Assembly of π‐Conjugated [B3O6] Units by Mer‐Isomer [YO3F3] Octahedra to Design a UV Nonlinear Optical Material, Cs2YB3O6F2

    Angewandte Chemie International Edition · 2024-05-08

    Hongping Wu, Zhijun Wei, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  18. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  19. K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

    Inorganic Chemistry · 2024-12-19

    Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu

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  20. Search for New Members of the Abre(B15o30)N Family with Significant Shg Effects Based on Chemical Substitution Strategy

    SSRN Electronic Journal · 2025-01-01

    Xiaoqin Ma, Shaohua Liu, Wei Wei, Qianzhen Zhang, Xifa Long, Yun Yang

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  21. Search for New Members of the Abre(B15o30)N Family with Significant Shg Effects Based on Chemical Substitution Strategy

    SSRN Electronic Journal · 2025-01-01

    Xiaoqin Ma, Shaohua Liu, Wei Wei, Qianzhen Zhang, Xifa Long, Yun Peng Yang

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  22. Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups

    Dalton Transactions · 2025-01-01

    Yixin Song, Hongwei Yu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·
  23. Rb 7 PbY 2 (B 5 O 10 ) 3 : A Noncentrosymmetric Rare-Earth Borate Nonlinear Optical Crystal with [B 5 O 10 ] Unit

    Inorganic Chemistry · 2025-03-14

    Xinyu Gao, Qing‐Yu Liu, Zhihua Yang, Jian Wei Han, Shilie Pan

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  24. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

    Coordination Chemistry Reviews · 2025-08-26

    Bailin Chen, Shuai An, Xueling Hou, Shilie Pan

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  25. Search for new nonlinear optical materials via chemical substitution and combined structural studies in alkali metal rare-earth borates

    Journal of Molecular Structure · 2025-09-17

    Xiaoqin Ma, Shaohua Liu, Wei Wei, Qianzhen Zhang, Xifa Long, Yun Mo Yang

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  26. K 7 MgY 2 (B 5 O 10 ) 3 : a novel ultraviolet nonlinear optical crystal based on the [B 5 O 10 ] functional unit

    New Journal of Chemistry · 2026-01-01

    Haozhen Liu, Shiyu Du, Paipai Zhang, Jiawei Zhao, Yanna Chen, Donghai An

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  27. Two scandium borate UV NLO crystals designed through chemical element substitution

    Chemical Communications · 2026-01-01

    Zelong Liu, Huijian Zhao, Longyun Xu, Ning Jia, Ning Ye, Zhanggui Hu, Conggang Li

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  28. Two Rare Earth-Based Sulfates with Enhanced Birefringence and Broad Optical Transparency Window

    Crystal Growth & Design · 2026-09-08

    Chang Liu, Ji Qi, Zhenchao Bai, Yong Wang, Weiqi Huang, Lina Li, Junhua Luo

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  29. Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials

    Advanced Optical Materials · 2026-09-30

    Bailin Chen, Yaqi Jin, Hucai Yang, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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