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RESEARCH PAPER · Inorganic Chemistry · 2019

Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)

Ya-Ping Gong, Yun‐Xiang Ma, Shao‐Ming Ying, Jiang‐Gao Mao, Fang Kong

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Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)OriginalAg4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis36BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains11MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings23Mixed-valent selenium compounds: Noncentrosymmetric Cd3(SeO3)2(SeO4) and Hg3(SeO3)2(SeO4) and centrosymmetric Pb2(SeO3) (SeO4)22Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)15Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds39Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.518Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution26Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity55Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain15Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds36Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra20Advances in second-order nonlinear optical sulfates38Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties36Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties2Anhydrous copper tellurite disulfate Cu 3 TeO 3 (SO 4 ) 2 featuring the coexistence of spin singlets and a long-range antiferromagnetic order1From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties27Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity30Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41A survey of stereoactive oxysalts for linear and nonlinear optical applications40Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25Exploring new horizons in mid-to-far infrared nonlinear optical crystals: the significant potential of trigonal pyramidal [TeS 3 ] 2− functional units18Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency10Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence1RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates4Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1

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  1. Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis

    Science China Materials · 2019-10-22

    Xiaoxue Wang, Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  2. BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains

    Dalton Transactions · 2020-01-01

    Ting Wang, Yi-Gang Chen, Yao Guo, Fang Wang, Qi Song, Ying‐Jie Jia, Xian‐Ming Zhang

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  3. MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings

    Journal of Solid State Chemistry · 2020-02-29

    Pengfei Li, Fang Kong, Jiang‐Gao Mao

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  4. Mixed-valent selenium compounds: Noncentrosymmetric Cd3(SeO3)2(SeO4) and Hg3(SeO3)2(SeO4) and centrosymmetric Pb2(SeO3) (SeO4)

    Journal of Solid State Chemistry · 2020-03-02

    Meng Shang, P. Shiv Halasyamani

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  5. Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)

    Journal of Alloys and Compounds · 2020-08-28

    Hye‐Eun Lee, Hongil Jo, Min Hyung Lee, Kang Min Ok

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  6. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

    Inorganic Chemistry Frontiers · 2020-10-26

    Pengfei Li, Chun‐Li Hu, Fang Kong, Shao‐Ming Ying, Jiang‐Gao Mao

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  7. Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds

    Chemical Communications · 2021-01-01

    Pengfei Li, Chun‐Li Hu, Ya-Ping Gong, Fang Kong, Jiang‐Gao Mao

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  8. Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap

    Journal of Materials Chemistry C · 2021-01-01

    Qinke Xu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  9. Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

    Chemical Communications · 2021-01-01

    Fang Kong, Ting-Kun Jiang, Jiang‐Gao Mao

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  10. Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.5

    Chemical Communications · 2021-01-01

    Shuangshuang Shi, Chensheng Lin, Dan Zhao, Min Luo, Liling Cao, Guang Peng, Ning Ye

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  11. Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution

    Inorganic Chemistry · 2021-04-06

    Yingwei Lu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  12. Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity

    Inorganic Chemistry · 2021-07-21

    Qi Wei, Kui Wang, Chao He, Li Wei, Xiao-Fei Li, Shuo Zhang, Xing‐Tao An, Jinhua Li, Guo‐Ming Wang

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  13. Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain

    European Journal of Inorganic Chemistry · 2021-10-12

    Wen‐Dong Yao, Mei Yan, Xiaohui Li, Wenlong Liu, Ru‐Ling Tang

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  14. Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds

    Materials Chemistry Frontiers · 2022-01-01

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  15. Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra

    Inorganic Chemistry · 2022-01-10

    Yuanyu Yang, Yao Guo, Bingbing Zhang, Ting Wang, Yi-Gang Chen, Xiaohui Hao, Xiaoxiu Yu, Xian‐Ming Zhang

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  16. Advances in second-order nonlinear optical sulfates

    Coordination Chemistry Reviews · 2022-02-17

    Yaoguo Shen, Wenyue Tang, Xiaoxin Lin

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  17. Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties

    Angewandte Chemie International Edition · 2022-10-04

    Ebube E. Oyeka, Michal Jerzy Winiarski, Hanna Świątek, Wyatt L. Balliew, Colin D. McMillen, Mingli Liang, Maurice Sorolla, T. Thao Tran

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  18. Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties

    Angewandte Chemie · 2022-10-04

    Ebube E. Oyeka, Michal Jerzy Winiarski, Hanna Świątek, Wyatt L. Balliew, Colin D. McMillen, Mingli Liang, Maurice Sorolla, T. Thao Tran

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  19. Anhydrous copper tellurite disulfate Cu 3 TeO 3 (SO 4 ) 2 featuring the coexistence of spin singlets and a long-range antiferromagnetic order

    Dalton Transactions · 2023-01-01

    Alisher F. Murtazoev, Peter S. Berdonosov, Konstantin Alexandrovich Lyssenko, В. А. Долгих, Z. V. Pchelkina, Konstantin V. Zakharov, Michael Y. Geidorf, Tatyana M. Vasilchikova, О. С. Волкова, Alexander N. Vasiliev

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  20. From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

    Bo Zhang, Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Fang Kong, Jiang‐Gao Mao

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  21. Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity

    Inorganic Chemistry · 2023-04-21

    Xiao-Fei Li, Kui Wang, Chao He, Jinhua Li, Xing‐Tao An, Jie Pan, Qi Wei, Guo‐Ming Wang, Guo‐Yu Yang

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  22. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

    Journal of Alloys and Compounds · 2023-05-15

    Pengfei Li, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

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  23. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

    Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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  24. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  25. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Xiaoyan Zhou, Xiang Mao, Pu Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  26. Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )

    Chemical Science · 2024-01-01

    Bo Zhang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  27. Exploring new horizons in mid-to-far infrared nonlinear optical crystals: the significant potential of trigonal pyramidal [TeS 3 ] 2− functional units

    Chemical Science · 2025-01-01

    Bo Zhang, Sheng-Hua Zhou, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  28. Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

    Inorganic Chemistry · 2025-01-24

    Jiale Xue, Shuyao Wang, Xiande Peng, Zhengyan Lin, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  29. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

    Inorganic Chemistry · 2025-04-08

    Xi-Ming Dong, Kai Huang, Hui‐Yan Zhao, Chao He, Xing‐Tao An, Qi Wei, Guo‐Yu Yang

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  30. Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence

    Dalton Transactions · 2026-01-01

    Jingsha Xu, Xiaofeng Zhang, Shanshan Chen, Weiyi Wang, Wenbo Qiu, Weizhao Cai, Liujiang Zhou

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  31. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, Jiarui Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

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  32. The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates

    Advanced Functional Materials · 2026-03-16

    Qinghe Li, Lilin Yang, Hongyuan Sha, Dongling Yang, Zujian Wang, Xiaoming Yang, Rongbing Su, Bin Su, Chao He, Xifa Long

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  33. Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units

    Coordination Chemistry Reviews · 2026-08-12

    Meiqi Liu, Miao Zhang, Ziyang Wang, Shizheng Li, Yang Zhao, Jiahang Liu, Jianmin Gu, Weiwei Cao, Desong Wang, Tianhui Wu

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