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RESEARCH PAPER · Journal of Alloys and Compounds · 2020

K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence

Fei Yang, Lei Wang, Yuwei Ge, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringenceOriginalThe study of structure evolvement of KTiOPO4 family and their nonlinear optical properties98α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth24α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth210Switchable NLO response induced by rotation of the fulvalene diruthenium-linked polyoxometalate derivatives4An antimony( iii ) borate with large birefringence exhibiting unwonted [B 5 O 11 ] fundamental building blocks and dimeric [Sb 2 O 6 ] clusters26Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 254Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26Na3SO4H – ein erster Vertreter der Materialklasse der Sulfathydride1Na3SO4H—The First Representative of the Material Class of Sulfate Hydrides16Synthesis and Crystal Structure of Some Ba-Apatites7Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution26Synthesis, Crystal Structures, and Thermal Analyses of Two New Antimony Tellurite Sulfates: [Sb2(TeO4)](SO4) and [Sb2(TeO3)2](SO4)10Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials33Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity55Tourmaline with ultraviolet optical nonlinearity: Emergent material discovery from mineral5NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence19A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency15A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency96KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence23Nain(C2o4)(Hpo4)(H2o)5: An Ultraviolet Transparent Nonlinear Optical Oxalate-Phosphate with Large Birefringence0Performance of optical materials with the derivative of planar π-conjugated groups: Recent advances and future prospects37«Ellestadite»-type anionic [PO4]3– → [SO4]2– substitutions in β-Ca3(PO4)2 type compounds: A new route to design the inorganic phosphors14Yin–Yang Complementarity Strategy Achieving Giant Optical Anisotropy in a Metal-free Birefringent Material C(NH2)3(HC4O4)14Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates58Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy38Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap9BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response32Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity30AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap21A survey of stereoactive oxysalts for linear and nonlinear optical applications40A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction6Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23Photochromic apatite skeletal structure materials: recent advances and potential applications14Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence18The Birefringence Modulation in Short‐Wave Ultraviolet Sulfates with Functional π‐Conjugated Cations and Polymerized Heteroleptic Tetrahedral Anions18Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence10Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates6Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio7Optimization of Functional Building Blocks Generates a Substantial Improvement in Birefringence from Sn2OSO4 to Sn3O2(OH)(HSO4)6A2Cd(PO3)4 (A = K, Rb, Cs): Series of cadmium polyphosphates with infinite 1[(PO3)4]ꝏ chains and deep ultraviolet transparency windows2Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials150Cation tuning in anionic framework hydroborates: tailored deep-ultraviolet optical crystals with large birefringence1Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain10Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5Structure modulation by cationic modification of sulfates using planar CS(NH 2 ) 25Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy17From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect14Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs8A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )1Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence1Na 2 SnSO 4 F 2 : an ultraviolet-transparent sulfate crystal with large birefringence driven by stereochemically active tin( ii )1The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates4Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals1Enhancing Birefringence of Sulphates by Polarity Modification in Planar Cations0Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0

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  1. The study of structure evolvement of KTiOPO4 family and their nonlinear optical properties

    Coordination Chemistry Reviews · 2020-08-08

    Fei Yang, Lei Wang, Ling Huang, Guohong Zou

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  2. α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth

    Angewandte Chemie · 2020-11-10

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  3. α‐SnF 2 : A UV Birefringent Material with Large Birefringence and Easy Crystal Growth

    Angewandte Chemie International Edition · 2020-11-10

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  4. Switchable NLO response induced by rotation of the fulvalene diruthenium-linked polyoxometalate derivatives

    Journal of Molecular Structure · 2020-11-27

    Ting Zhang, Xue-Hong Wei, Ying Zuo, Tengying Ma

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  5. An antimony( iii ) borate with large birefringence exhibiting unwonted [B 5 O 11 ] fundamental building blocks and dimeric [Sb 2 O 6 ] clusters

    Inorganic Chemistry Frontiers · 2021-01-01

    Zhen Chen, Hao Zeng, Shujuan Han, Zhihua Yang, Shilie Pan

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  6. Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Lei Wang, Hongmei Wang, Die Zhang, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  7. Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap

    Journal of Materials Chemistry C · 2021-01-01

    Qinke Xu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  8. Na3SO4H – ein erster Vertreter der Materialklasse der Sulfathydride

    Angewandte Chemie · 2021-01-15

    Alexander G. Mutschke, Guy M. Bernard, Marko Bertmer, Antti J. Karttunen, C. Ritter, Vladimir K. Michaelis, Nathalie Kunkel

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  9. Na3SO4H—The First Representative of the Material Class of Sulfate Hydrides

    Angewandte Chemie International Edition · 2021-01-15

    Alexander G. Mutschke, Guy M. Bernard, Marko Bertmer, Antti J. Karttunen, C. Ritter, Vladimir K. Michaelis, Nathalie Kunkel

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  10. Synthesis and Crystal Structure of Some Ba-Apatites

    Russian Journal of Inorganic Chemistry · 2021-04-01

    E.N. Bulanov, Sergey S Petrov, Zhan Xu, Alexander Vladimirovich Knyazev, Nikolai Edwardovich Skoblikov

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  11. Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution

    Inorganic Chemistry · 2021-04-06

    Yingwei Lu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  12. Synthesis, Crystal Structures, and Thermal Analyses of Two New Antimony Tellurite Sulfates: [Sb2(TeO4)](SO4) and [Sb2(TeO3)2](SO4)

    Zeitschrift für anorganische und allgemeine Chemie · 2021-05-06

    Jiayuan Zhang, Xiao Zhao, Yuandong Wu, Dajiang Mei, Shaoguo Wen, Thomas Doert

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  13. Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials

    Inorganic Chemistry · 2021-05-14

    Yuwei Ge, Qiang Wang, Fei Yang, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  14. Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity

    Inorganic Chemistry · 2021-07-21

    Qi Wei, Kui Wang, Chao He, Li Wei, Xiaofei Li, Shuo Zhang, Xing‐Tao An, Jinhua Li, Guo‐Ming Wang

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  15. Tourmaline with ultraviolet optical nonlinearity: Emergent material discovery from mineral

    Journal of Alloys and Compounds · 2021-10-04

    Mingjun Xia, Lei Kang

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  16. NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence

    Crystal Growth & Design · 2021-12-09

    Kui Wang, Xiaofei Li, Chao He, Jinhua Li, Xing‐Tao An, Li Wei, Qi Wei, Guo‐Ming Wang

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  17. A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency

    Angewandte Chemie · 2021-12-11

    Chao Wu, Xingxing Jiang, Yilei Hu, Chunbo Jiang, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  18. A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency

    Angewandte Chemie International Edition · 2021-12-11

    Chao Wu, Xingxing Jiang, Yilei Hu, Chunbo Jiang, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  19. KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence

    Journal of Materials Chemistry C · 2022-01-01

    Xuehua Dong, Ying Long, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  20. Nain(C2o4)(Hpo4)(H2o)5: An Ultraviolet Transparent Nonlinear Optical Oxalate-Phosphate with Large Birefringence

    SSRN Electronic Journal · 2022-01-01

    Xuqi Zhang, Yanyan Xue, Lei Yang, Chao Wu, Zhipeng Huang, Jun Xu, Mark Graeme Humphrey, Chi Zhang

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  21. Performance of optical materials with the derivative of planar π-conjugated groups: Recent advances and future prospects

    Inorganic Chemistry Frontiers · 2022-01-01

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  22. «Ellestadite»-type anionic [PO4]3– → [SO4]2– substitutions in β-Ca3(PO4)2 type compounds: A new route to design the inorganic phosphors

    Ceramics International · 2022-05-11

    Dina V. Deyneko, Титков Владимир Викторович, Fedor D. Fedyunin, Dmitry A. Spassky, Sergey N. Volkov, E. Yu. Borovikova, Bogdan I. Lazoryak, Sergey M. Aksenov

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  23. Yin–Yang Complementarity Strategy Achieving Giant Optical Anisotropy in a Metal-free Birefringent Material C(NH2)3(HC4O4)

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  24. Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates

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  25. Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy

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  26. Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap

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  27. BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response

    Materials Today Physics · 2022-10-05

    Y. Long, X. Dong, Lilian Huang, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Guangtian Zou

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  28. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

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  29. Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

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  30. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

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  31. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  32. Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity

    Inorganic Chemistry · 2023-04-21

    Xiaofei Li, Kui Wang, Chao He, Jinhua Li, Xing‐Tao An, Jie Pan, Qi Wei, Guo‐Ming Wang, Guo‐Yu Yang

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  33. AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2023-05-24

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  34. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

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  35. A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction

    Inorganic Chemistry Frontiers · 2024-01-01

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  36. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

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  37. Photochromic apatite skeletal structure materials: recent advances and potential applications

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  38. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

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  39. Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence

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  40. The Birefringence Modulation in Short‐Wave Ultraviolet Sulfates with Functional π‐Conjugated Cations and Polymerized Heteroleptic Tetrahedral Anions

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  41. Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence

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  42. Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates

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  43. Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio

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  44. Optimization of Functional Building Blocks Generates a Substantial Improvement in Birefringence from Sn2OSO4 to Sn3O2(OH)(HSO4)

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  45. A2Cd(PO3)4 (A = K, Rb, Cs): Series of cadmium polyphosphates with infinite 1[(PO3)4]ꝏ chains and deep ultraviolet transparency windows

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  46. Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials

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  47. Cation tuning in anionic framework hydroborates: tailored deep-ultraviolet optical crystals with large birefringence

    New Journal of Chemistry · 2025-01-01

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  48. Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain

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  49. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

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  50. Structure modulation by cationic modification of sulfates using planar CS(NH 2 ) 2

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