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RESEARCH PAPER · Inorganic Chemistry · 2020

Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff Edges

Wenyao Zhang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff EdgesOriginalRbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence37Nonlinear-Optical Crystal Rb3YB6O12 with Condensed B5O10 Blocks That Exhibits an Intriguing Structural Arrangement and a Short Ultraviolet Absorption Edge26The synthesis, characterization, and theoretical analysis of (NH 4 ) 3 PbCl 52NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers10Recent advances of oxyfluorides for nonlinear optical applications69Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point18NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate7Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer11Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion133Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion13Two layered galloborates from centric to acentric structures: syntheses and NLO properties27MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges12Two New Nonaborates with {B9} Cluster Open-Frameworks and Short Cutoff Edges4LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks33Rb 3 B 5 O 8 F 2 and K 0.6 Rb 2.4 B 5 O 8 F 2 : two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation13KMB 4 O 6 F 3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO 3 units16Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure6Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups8Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27Fluorination strategy toward chemical and functional modification65New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19Synthesis and characterization of a two-dimensional antiferromagnet KNiB4O6F3 with triangular spin lattice5La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups6Co-ligand tuning of MOF structural anisotropy for giant optical birefringence7Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units0

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  1. RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence

    Chemical Communications · 2020-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  2. Nonlinear-Optical Crystal Rb3YB6O12 with Condensed B5O10 Blocks That Exhibits an Intriguing Structural Arrangement and a Short Ultraviolet Absorption Edge

    Inorganic Chemistry · 2020-09-04

    Zhen Jia, Qindan Zeng, Pifu Gong, Dong Yan, Xiuling Zhang, Bingwei Xin, Zheshuai Lin, Mingjun Xia

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  3. The synthesis, characterization, and theoretical analysis of (NH 4 ) 3 PbCl 5

    New Journal of Chemistry · 2020-12-26

    Liang Zhu, Wenqi Jin, Zhihua Yang, Yun Mo Yang, Shilie Pan

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  4. NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers

    New Journal of Chemistry · 2021-01-01

    Zilong Chen, Junwei Feng, Bin Dai, Feng Yu

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  5. Recent advances of oxyfluorides for nonlinear optical applications

    Inorganic Chemistry Frontiers · 2021-01-01

    Shuo Bai, Dan Wang, Hongkun Liu, Ying Wang

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  6. Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point

    Chemistry - A European Journal · 2021-05-03

    Ming Xia, Miriding Mutailipu, Fuming Li, Zhihua Yang, Shilie Pan

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  7. NaRbB3O4F3: A New Fluorooxoborate with a Short UV Cutoff Edge Enriching the Structural Chemistry of Borate

    Chemistry - An Asian Journal · 2021-08-20

    Rui Zhang, Jie Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  8. Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer

    Dalton Transactions · 2021-12-01

    Chengfa Wu, Zilong Chen, Jianbang Chen, Zhihua Yang, Fangfang Zhang, Hongsheng Shi, Shilie Pan

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  9. Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion

    Angewandte Chemie International Edition · 2021-12-21

    Huanhuan Cheng, Fuming Li, Zhihua Yang, Shilie Pan

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  10. Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion

    Angewandte Chemie · 2021-12-21

    Huanhuan Cheng, Fuming Li, Zhihua Yang, Shilie Pan

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  11. Two layered galloborates from centric to acentric structures: syntheses and NLO properties

    Chemical Communications · 2022-01-01

    Chong‐An Chen, Wenfang Liu, Guo‐Yu Yang

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  12. MM′B3O4F3 (M = K; M′ = Na, K, Cs): Alkali-Metal Fluorooxoborates with ∞1[B3O4F3] Chains and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2022-02-02

    Zhikang Chen, Kewang Zhang, Zi‐Jian Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  13. Two New Nonaborates with {B9} Cluster Open-Frameworks and Short Cutoff Edges

    Molecules · 2022-08-18

    Chong‐An Chen, Guo‐Yu Yang

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  14. LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks

    Advanced Optical Materials · 2022-12-03

    Xiaojing Li, Zilong Chen, Fuming Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  15. Rb 3 B 5 O 8 F 2 and K 0.6 Rb 2.4 B 5 O 8 F 2 : two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation

    Inorganic Chemistry Frontiers · 2022-12-06

    Ruonan Zhang, Bingliang Cheng, Xuping Wang, Rong Yang, Zhihua Yang, Shujuan Han, Shilie Pan

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  16. KMB 4 O 6 F 3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO 3 units

    Dalton Transactions · 2023-01-01

    Yanhong Wang, Shuang long Li, Yaling Dou, Hui Li, Hongcheng Lu

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  17. Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure

    Inorganic Chemistry · 2023-05-09

    Shuzhao Huang, Liang Zhu, Ivan A. Kruglov, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  18. Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups

    ACS Omega · 2023-06-02

    Yu Dang, Jingdong Yan, Xueling Hou, Hongsheng Shi

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  19. Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures

    Chemistry of Materials · 2023-07-07

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Fangfang Zhang, Zilong Chen, Xueling Hou, Zhihua Yang, Shilie Pan

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  20. Fluorination strategy toward chemical and functional modification

    Fundamental Research · 2023-12-19

    Haotian Qiu, Shilie Pan, Miriding Mutailipu

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  21. New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation

    Chemical Communications · 2024-01-01

    Chenhui Hu, Mengfan Wu, Jian Wei Han, Zhihua Yang, Shujuan Han, Shilie Pan

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  22. Synthesis and characterization of a two-dimensional antiferromagnet KNiB4O6F3 with triangular spin lattice

    Journal of Solid State Chemistry · 2024-10-18

    Hui Li, Shuang Li, Yanhong Wang, Yaling Dou, Hongcheng Lu

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  23. La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups

    ACS Materials Letters · 2024-12-19

    Ming‐Shu Zhang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  24. Co-ligand tuning of MOF structural anisotropy for giant optical birefringence

    Chemical Communications · 2025-01-01

    Svyatoslav A. Povarov, Ekaterina D Iukhnevich, Pavel V. Alekseevskiy, Dmitry I. Pavlov, Аndrei S. Potapov, Irina D. Yushina, Valentin A. Milichko, Alena N. Kulakova

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  25. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

    Coordination Chemistry Reviews · 2025-08-26

    Bailin Chen, Shuai An, Xueling Hou, Shilie Pan

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  26. Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units

    Dalton Transactions · 2026-01-01

    Cheng He, Kun Hu, Jing-Yang Zhou, Long Wu, Jian‐Han Zhang

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