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RESEARCH PAPER · Inorganic Chemistry · 2022

Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

Wen-Zhuo Zhao, Yinan Zhang, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium BorateOriginalNa 3 B 6 O 10 (HCOO): an ultraviolet nonlinear optical sodium borate-formate33Two porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra7C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups13ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair9Postsynthetic Modification of NU-1000 for Designing a Polyoxometalate-Containing Nanocomposite with Enhanced Third-Order Nonlinear Optical Performance86Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties24Recent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoborates17Data Mining and Graph Network Deep Learning for Band Gap Prediction in Crystalline Borate Materials18Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains5Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge17Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Li2RbSO4Cl with a Short Ultraviolet Absorption Edge and an Acentric Structure through Assembling Heteroleptic [LiO3Cl] Tetrahedra2Giant Mid‐Infrared Second‐Harmonic Generation Response in a Densely‐Stacked Van Der Waals Transition‐Metal Oxychloride39Giant Mid‐Infrared Second‐Harmonic Generation Response in a Densely‐Stacked Van Der Waals Transition‐Metal Oxychloride8Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12Hydroxyl-Driven Enhanced Birefringence in Borophosphates3Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families17Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties37NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units6Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties17NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges6M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10Two polyoxovanadoborates with over 100 nuclei assembled from a {V14Co12B72} cluster13Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8Three Polyoxovanadoborates Constructed from “Sandwich”-Type {V10B24}, {V10B28}, and {V12B32} Clusters5Li6[{BO3}{B15O21(OH)6}]: An Acentric Layered Borate Constructed from Unprecedented Oxoboron Cluster Building Units6Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9Hydroxyl-induced structural reconstruction: two new potassium hepta-borates with deep-UV transparency and enhanced birefringence1CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties0NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence2Assembly of Functional Units for Constructing an Ultraviolet-Transparent Nonlinear Optical Mixed Alkaline Metal Borate-Formate1K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units2

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  1. Na 3 B 6 O 10 (HCOO): an ultraviolet nonlinear optical sodium borate-formate

    Inorganic Chemistry Frontiers · 2022-01-01

    Yinan Zhang, Qing-Fen Li, Bing-Ben Chen, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  2. Two porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra

    CrystEngComm · 2022-01-01

    Yazhuo Dong, Chong‐An Chen, Juan Chen, Jian‐Wen Cheng, Jinhua Li, Guo‐Yu Yang

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  3. C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups

    Journal of Solid State Chemistry · 2022-08-28

    Dong Yan, Yao Ma, Ru‐Ling Tang, Liang Hu, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Shu‐Fang Li

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  4. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

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  5. Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair

    Inorganic Chemistry · 2022-11-01

    Lihan Deng, Mengfan Wu, Zhihua Yang, Shujuan Han, Shilie Pan

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  6. Postsynthetic Modification of NU-1000 for Designing a Polyoxometalate-Containing Nanocomposite with Enhanced Third-Order Nonlinear Optical Performance

    Inorganic Chemistry · 2022-11-14

    Yangdan Pan, Soheila Sanati, Marzieh Nadafan, Reza Abazari, Junkuo Gao, Alexander M. Kirillov

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  7. Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties

    Inorganic Chemistry · 2023-01-06

    Xuyan Li, Jinhua Li, Jian‐Wen Cheng, Guo‐Yu Yang

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  8. Recent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoborates

    Chinese Journal of Structural Chemistry · 2023-02-17

    Qingfen Li, Weifeng Chen, You‐Zhao Lan, Jian‐Wen Cheng

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  9. Data Mining and Graph Network Deep Learning for Band Gap Prediction in Crystalline Borate Materials

    Inorganic Chemistry · 2023-03-08

    Ruihan Wang, Yeshuang Zhong, Xuehua Dong, Meng Du, Haolun Yuan, Yurong Zou, Xin Wang, Zhien Lin, Dingguo Xu

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  10. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  11. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  12. Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains

    Inorganic Chemistry · 2023-06-12

    Ru‐Ling Tang, Lei Huai, Wenlong Liu

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  13. Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-06-15

    Wenhao Liu, Pifu Gong, Weiqi Huang, Mengran Sun, Sangen Zhao, Zheshuai Lin, Jiyong Yao

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  14. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

    Molecules · 2023-06-28

    Jinɡjinɡ Li, Weifeng Chen, You‐Zhao Lan, Jian‐Wen Cheng

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  15. Li2RbSO4Cl with a Short Ultraviolet Absorption Edge and an Acentric Structure through Assembling Heteroleptic [LiO3Cl] Tetrahedra

    Inorganic Chemistry · 2023-08-08

    Huanhuan Cheng, Fuming Li, Juanjuan Lu, Xueling Hou

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  16. Giant Mid‐Infrared Second‐Harmonic Generation Response in a Densely‐Stacked Van Der Waals Transition‐Metal Oxychloride

    Angewandte Chemie International Edition · 2023-08-23

    Congcong Jin, Xingxing Jiang, Chao Wu, Kaining Duanmu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  17. Giant Mid‐Infrared Second‐Harmonic Generation Response in a Densely‐Stacked Van Der Waals Transition‐Metal Oxychloride

    Angewandte Chemie · 2023-08-23

    Congcong Jin, Xingxing Jiang, Chao Wu, Kaining Duanmu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  18. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-09-04

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Zhihua Yang, Xifa Long, Yun Mo Yang

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  19. Hydroxyl-Driven Enhanced Birefringence in Borophosphates

    Inorganic Chemistry · 2023-11-22

    Yang Xia, Wen-Bin Zhang, Xueting Pan, Xueling Hou, Shujuan Han

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  20. Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families

    Solid State Sciences · 2023-12-15

    Sergey N. Volkov, Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, Daria A. Banaru, Yulia A. Vaitieva, Maria Georgievna Krzhizhanovskaya, N. A. Yamnova, Vadim E. Kireev, Alevtina N. Gosteva, Nikita Sergeyevich Tsvetov, Yevgeny E. Savchenko, Р. С. Бубнова

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  21. Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives

    Dalton Transactions · 2024-01-01

    Jingyi Lu, Yangfeifei Ou, Congcong Jin, Jian‐Wen Cheng

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  22. KBa 3 M 2 F 14 Cl (M = Zr, Hf): novel short-wavelength mixed metal halides with the largest second-harmonic generation responses contributed by mixed functional moieties

    Chemical Science · 2024-01-01

    Mei Yan, Chun‐Li Hu, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  23. NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units

    Journal of Materials Chemistry C · 2024-01-01

    Chenhui Hu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

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  24. Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties

    Chemistry - A European Journal · 2024-03-18

    Weifeng Chen, J. Lu, Jingjing Li, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  25. NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2024-04-24

    Huanhuan Zhao, Die Xu, Zhaohui Chen

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  26. M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion

    Inorganic Chemistry · 2024-05-09

    Weifeng Chen, Mei-Jun Zou, Jinɡjinɡ Li, Yinan Zhang, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  27. Two polyoxovanadoborates with over 100 nuclei assembled from a {V14Co12B72} cluster

    Science China Chemistry · 2024-05-31

    Shuangxue Wu, Yujiao Dong, Yang Yang, Chao Qin, Chunyi Sun, Wei Guan, Xinlong Wang, Zhong‐Min Su

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  28. Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework

    Inorganic Chemistry · 2024-12-31

    Juan Chen, Dan Qin, Guo‐Yu Yang

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  29. Three Polyoxovanadoborates Constructed from “Sandwich”-Type {V10B24}, {V10B28}, and {V12B32} Clusters

    Inorganic Chemistry · 2025-02-06

    Shuangxue Wu, Yao-Mei Fu, Xinyue Chu, Liang Zhao, Meng Yuan, Xinlong Wang, Zhong‐Min Su

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  30. Li6[{BO3}{B15O21(OH)6}]: An Acentric Layered Borate Constructed from Unprecedented Oxoboron Cluster Building Units

    Crystal Growth & Design · 2025-08-20

    Jin-Ni Zhao, Juan Chen, Guo‐Yu Yang

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  31. Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions

    Chinese Journal of Structural Chemistry · 2025-09-01

    Yangfeifei Ou, Xiaoliang Zhou, You‐Zhao Lan, Jian‐Wen Cheng

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  32. Hydroxyl-induced structural reconstruction: two new potassium hepta-borates with deep-UV transparency and enhanced birefringence

    Inorganic Chemistry Frontiers · 2025-11-15

    Meng Cheng, Wenbin Zhang, Wenqi Jin, Артем Ромаевич Оганов, Zhihua Yang, Shilie Pan

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  33. CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties

    Dalton Transactions · 2026-01-01

    Kelibinuer Wulamu, Ziting Yan, Dongdong Chu, Juanjuan Lu, Yanhui Zhang, Hong Du

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  34. NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-27

    Bailin Chen, Yansheng Jiang, Hangwei Jia, Shuai An, Xueling Hou, Shilie Pan

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  35. Assembly of Functional Units for Constructing an Ultraviolet-Transparent Nonlinear Optical Mixed Alkaline Metal Borate-Formate

    Inorganic Chemistry · 2026-05-22

    Mei-Jun Zou, Dong-Ling Liu, Xiao-Liang Zhou, Yi-Nan Zhang, You‐Zhao Lan, Jian‐Wen Cheng

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  36. K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units

    Inorganic Chemistry · 2026-05-28

    Xueqing Liu, Xinyue Shi, Yuan Fang, Yipeng Pang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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