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RESEARCH PAPER · Science China Chemistry · 2024

Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units

Jinbin Fan, Ziting Yan, Zilong Chen, Huimin Li, Zhihua Yang, Fangfang Zhang, Shilie Pan

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Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] unitsOriginalUnveiling Charge Dependent Law to Enhance Birefringence in 2‐Aminopyrimidine Family21CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge3Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution17RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence1High-index faceted jagged PtPdTe nanotubes for methanol oxidation reaction2Achieving excellent nonlinear optical performance via “dimensionality elevation”-driven transformation from centrosymmetric to non-centrosymmetric structures1A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units8Cation-modulated aligned arrangement of [B3O7] units in an unprecedented 2∞[B3O5] layer with remarkable birefringence10Achieving large birefringence in oxalate crystals by a hydrogen bond-directed strategy1La(SO3NH2)2NO3·H2O: synergistic anion engineering of the first rare-earth nitrate sulfamate defying transparency-birefringence-nonlinearity trade-offs in ultraviolet nonlinear optics8Advances in weak-bonded assembly as materials in catalysis and friction applications1Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals1Achieving record birefringence in metal-free semiorganic sulfate crystals via tetrahedral anionic group substitution0Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups0Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials3Targeted hydroxyl fluorination for first-principles design of deep-ultraviolet nonlinear optical crystals: multi-property optimization & chromatic dispersion modulation in Li 2 CsB 7 O 10 F 41Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates0Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5

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  1. Unveiling Charge Dependent Law to Enhance Birefringence in 2‐Aminopyrimidine Family

    Advanced Optical Materials · 2024-12-16

    Muhammad Sharjeel Arif, Xu Liu, Zi‐Jian Li, Hangwei Jia, Yansheng Jiang, Zhihua Yang, Xueling Hou, Shilie Pan

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  2. CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge

    Chemical Communications · 2025-01-01

    Jinbin Fan, Luyong Zhang, Zilong Chen, Huimin Li, Zhihua Yang, Yun Mo Yang, Fangfang Zhang, Shilie Pan

    Read original paper ↗ ·

  3. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  4. Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution

    Materials Horizons · 2025-01-01

    Muhammad Sharjeel Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  5. RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence

    Dalton Transactions · 2025-01-01

    Yujing Zheng, Ke Li, Ling Huang, Fangfang Zhang

    Read original paper ↗ ·

  6. High-index faceted jagged PtPdTe nanotubes for methanol oxidation reaction

    Science China Chemistry · 2025-05-30

    Qing Hu, Peipei Li, Mengqian Li, Jiacong Wu, Jinyu Ding, Wenya Fan, Qinyuan Hu, Qingxia Chen, Xingchen Jiao

    Read original paper ↗ ·

  7. Achieving excellent nonlinear optical performance via “dimensionality elevation”-driven transformation from centrosymmetric to non-centrosymmetric structures

    Science China Chemistry · 2025-06-28

    Lin‐Tao Jiang, Jun-Long Chen, Ming‐Shu Zhang, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  8. A novel metal-free crystal demonstrating superior birefringence attributed to the synergistic interaction of dual π-conjugated units

    Science China Materials · 2025-07-07

    Die-Xue Yang, Ru‐Ling Tang, Yi‐Lei Lv, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  9. Cation-modulated aligned arrangement of [B3O7] units in an unprecedented 2∞[B3O5] layer with remarkable birefringence

    Science China Materials · 2025-07-28

    Ziting Yan, Dongdong Chu, Zhihua Yang, Shilie Pan, Min Zhang

    Read original paper ↗ ·

  10. Achieving large birefringence in oxalate crystals by a hydrogen bond-directed strategy

    Science China Chemistry · 2025-08-08

    Yan-Zhen Xie, Hua Huang, Qingran Ding, Jian Lei, Yu-Ling Wang, Qing‐Yan Liu

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  11. La(SO3NH2)2NO3·H2O: synergistic anion engineering of the first rare-earth nitrate sulfamate defying transparency-birefringence-nonlinearity trade-offs in ultraviolet nonlinear optics

    Science China Chemistry · 2025-08-08

    Huan Zhou, Meng Cheng, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  12. Advances in weak-bonded assembly as materials in catalysis and friction applications

    Chinese Chemical Letters · 2025-09-09

    Bi-Jun Geng, Dong-Yang Su, Shuxin Li, Ming Zhang, Dong Qi, Fan Lai, Xinfeng Tan, Yang Yang

    Read original paper ↗ ·

  13. Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals

    Inorganic Chemistry Frontiers · 2025-11-24

    LeHui Liu, FeiFei Yuan, YiSheng Huang, LiZhen Zhang, ZhouBin Lin

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  14. Achieving record birefringence in metal-free semiorganic sulfate crystals via tetrahedral anionic group substitution

    Chemical Science · 2026-01-01

    Yan-Zhen Xie, Hai-Yan Jiang, Yi Zhang, Hui‐Ping Xiao, Qing‐Yan Liu, Yu‐Ling Wang

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  15. Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups

    Dalton Transactions · 2026-01-01

    Haowen Li, X Y Wang, Hui Chai, Fangfang Zhang

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  16. Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials

    Inorganic Chemistry Frontiers · 2026-01-01

    Hussin Elkik, Muhammad Mujahid Iqbal, Aqsa Munawar, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  17. Targeted hydroxyl fluorination for first-principles design of deep-ultraviolet nonlinear optical crystals: multi-property optimization & chromatic dispersion modulation in Li 2 CsB 7 O 10 F 4

    Inorganic Chemistry Frontiers · 2026-01-01

    chenxu li, Haoran Wang, Min Zhang, Shilie Pan, Zhihua Yang

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  18. Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates

    Chemistry of Materials · 2026-03-04

    Luyong Zhang, Jianyi Zuo, Guangsheng Xu, Jinbin Fan, Xue Bai, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  19. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

    Read original paper ↗ ·
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