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RESEARCH PAPER · Chemical Science · 2024

A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates

Jie Song, Huijian Zhao, Conggang Li, Ning Ye, Zhanggui Hu, Yicheng Wu

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A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth boratesOriginalPolar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal10Chemical substitution towards a rare-earth borate ultraviolet NLO crystal exhibiting a strong SHG response17Tailoring UV waveplate materials via rational assembly of functional motifs in scandium fluoride phosphate2Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal6Design of rare earth borate short-wave UV nonlinear optical crystals with strengthened second harmonic generation activities via cationic modification strategy11A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 38Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite1Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence0Two scandium borate UV NLO crystals designed through chemical element substitution1Ca6Ln12O9(BO3)10 (Ln = La-Gd) - new members of NLO borates family0Normalized radial distribution as a crystal structure descriptor: applications in comparative crystal chemistry and the 'search match' problem0Cation electronic structure governs Deep-UV nonlinear optical response in MB4O7 (M = Sn, Pb, Yb) Tetraborates: Lone pairs versus 4f electrons0Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials1Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates2The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals1The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals0

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  1. Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal

    Inorganic Chemistry · 2024-10-28

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Qian Wu, Mingjun Xia

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  2. Chemical substitution towards a rare-earth borate ultraviolet NLO crystal exhibiting a strong SHG response

    Inorganic Chemistry Frontiers · 2024-11-21

    Xianghao Kong, Jing Chai, Huijian Zhao, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  3. Tailoring UV waveplate materials via rational assembly of functional motifs in scandium fluoride phosphate

    Chemical Communications · 2025-01-01

    Huijian Zhao, Conggang Li, Ning Ye, Zhanggui Hu

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  4. Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal

    Chinese Chemical Letters · 2025-01-07

    Ning Yang, Huijian Zhao, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Conggang Li

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  5. Design of rare earth borate short-wave UV nonlinear optical crystals with strengthened second harmonic generation activities via cationic modification strategy

    Chinese Chemical Letters · 2025-02-27

    Huijian Zhao, Jie Song, Shuaifeng Li, Shuaifeng Li, Xianghao Kong, Conggang Li, Ning Ye, Zhanggui Hu

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  6. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  7. Design and Synthesis of a Rare Earth Borate Ultraviolet Nonlinear Optical Crystal K 3 Lu 2 (BO 3 ) 3

    Inorganic Chemistry · 2025-10-20

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu

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  8. Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite

    Dalton Transactions · 2026-01-01

    Jingfang Zhou, Pifu Gong, Chang Gao, Mingjun Xia, Jing Yu, Hongxia Zhang, Qian Wu

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  9. Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence

    SSRN Electronic Journal · 2026-01-01

    S. D. Lee, Yunseung Kuk, Congcong Jin, Wei Zeng, Kang Min Ok

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  10. Two scandium borate UV NLO crystals designed through chemical element substitution

    Chemical Communications · 2026-01-01

    Zelong Liu, Huijian Zhao, Longyun Xu, Ning Jia, Ning Ye, Zhanggui Hu, Conggang Li

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  11. Ca6Ln12O9(BO3)10 (Ln = La-Gd) - new members of NLO borates family

    Inorganic Chemistry Communications · 2026-01-11

    M.G. Krzhizhanovskaya, G.S. Sizov, A.V. Povolotskiy, V. L. Ugolkov, E.S. Sukharzhevskaya, N.S. Vlasenko, S.K. Filatov, R.S. Bubnova

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  12. Normalized radial distribution as a crystal structure descriptor: applications in comparative crystal chemistry and the 'search match' problem

    Journal of Applied Crystallography · 2026-04-28

    Sergey Rashchenko

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  13. Cation electronic structure governs Deep-UV nonlinear optical response in MB4O7 (M = Sn, Pb, Yb) Tetraborates: Lone pairs versus 4f electrons

    Computational Condensed Matter · 2026-06-16

    M. Naveed-Ul-Haq

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  14. Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials

    Materials Today Physics · 2026-07-04

    D K Li, Yujie Zhang, H Liu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  15. Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates

    Advanced Functional Materials · 2026-07-10

    Huijian Zhao, Kangyan Fan, Conggang Li, Zelong Liu, Pifu Gong, Ning Ye, Zhanggui Hu

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  16. The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals

    Angewandte Chemie International Edition · 2026-09-10

    Xiangqing Cao, Haotian Qiu, Juanjuan Lu, Yun Mo Yang, Xueling Hou, Junjie Li, Shilie Pan, Miriding Mutailipu

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  17. The Multi‐Scale Paradigm: An Integrated Design Logic for Nonlinear Optical Crystals

    Angewandte Chemie · 2026-09-10

    Xiangqing Cao, Haotian Qiu, Juanjuan Lu, Yun Mo Yang, Xueling Hou, Junjie Li, Shilie Pan, Miriding Mutailipu

    Read original paper ↗ ·
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