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RESEARCH PAPER · Science Advances · 2019

Li substituent tuning of LED phosphors with enhanced efficiency, tunable photoluminescence, and improved thermal stability

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Li substituent tuning of LED phosphors with enhanced efficiency, tunable photoluminescence, and improved thermal stabilityOriginalA single-phase white light emitting phosphor Ba 3 Y(PO 4 ) 3 :Ce 3+ /Tb 3+ /Mn 2+ : luminescence, energy transfer and thermal stability26Aliovalent substitution toward reinforced structural rigidity in Ce 3+ -doped garnet phosphors featuring improved performance44An insight into the preferential substitution and structure repair in Eu 2+ -doped whitlockite-type phosphors based on the combined experimental and theoretical calculations21Design of a novel scandium silicate based blue-emitting phosphor with high efficiency and robust thermal stability for warm WLEDs and field emission displays37Lithium ion doping triggered splendid quantum efficiency and thermal stability in Li 2 SrSiO 4 : x Eu 2+ phosphors for optical thermometry and high luminous efficiency white-LED31Tuning of the Compositions and Multiple Activator Sites toward Single-Phased White Emission in (Ca 9– x Sr x )MgK(PO 4 ) 7 :Eu 2+ Phosphors for Solid-State Lighting115The structure and photoluminescence properties of a novel orange emission phosphor Ba3Sc1.9Al0.1B4O12: Eu2+ excited by NUV light10Controllable Eu 2+ -Doped Orthophosphate Blue-/Red-Emitting Phosphors: Charge Compensation and Lattice-Strain Control49Eu3+-doped ZnLaB5O10: A suitable candidate for near ultraviolet LED pumped red phosphor19Structural origin of blue luminescence in Ce-doped Ba2Y5B5O17 and Ba3Y2B6O15 with multiple cation sites and occupational disorder9High brightness and precise adjustment of multicolor-tunable luminescence of Lu2GeO5:Tb3+, Eu3+ phosphors for white LEDs14The enhancement of emission intensity and enlargement of color gamut by a simple local structure substitution with highly thermal stability preserved7Double perovskite (Gd0.85-xYx)2MgTiO6:0.3Eu3+ red phosphors for white LEDs with excellent high temperature performance8Structure–Optical Behavior Correlation, Optimized Photoluminescence, and DFT Calculation of La7O6(BO3)(PO4)2:Sm3+ Micropowder for Solid State Lighting33Efficient energy transfer induced tunable emission in Ce3+ and Eu2+ co-doped Ba1.2Ca0.8SiO4 phosphor12Engineering of K3YSi2O7To Tune Photoluminescence with Selected Activators and Site Occupancy118Highly thermal-stable yellow-emitting tantalate phosphor Ca2YTaO6:Dy3+ for white-LEDs35Giant Photoluminescence Improvement and Controllable Emission Adjustment in Bi3+-Activated Ca4ZrGe3O12 Phosphors for High-Quality White Light-Emitting Diodes42Luminescence properties of double perovskite Gd2MgTiO6:Tb3+ phosphors by solid-state reaction method7Photoluminescence Control of UCr 4 C 4 -Type Phosphors with Superior Luminous Efficiency and High Color Purity via Controlling Site Selection of Eu 2+ Activators112New strategy of designing a novel yellow-emitting phosphor Na4Hf2Si3O12:Eu2+ for multifunctional applications21Studying crystal-field splitting difference of Eu3+ ions from orthorhombic to cubic Ca4Al6SO166Electronic structure, energy transfer mechanism and thermal quenching behavior of K3YB6O12:Dy3+, Eu3+ phosphor39Nano Wave Plates Structuring and Index Matching in Transparent Hydroxyapatite‐YAG: Ce Composite Ceramics for High Luminous Efficiency White Light‐Emitting Diodes136Designing High‐Performance LED Phosphors by Controlling the Phase Stability via a Heterovalent Substitution Strategy76Photoluminescence control and abnormal Eu 3+ orange emission in Ln 3+ (Ln 3+ = Ce 3+ , Eu 3+ )-doped oxyapatite-type phosphors17Identifying Near‐Infrared Persistent Luminescence in Cr3+‐Doped Magnesium Gallogermanates Featuring Afterglow Emission at Extremely Low Temperature69Achieving high thermal stability of different rare-earth ions in a single matrix host via the manipulation of the local structure by a solid solution14An in-situ synthesized multiphase phosphor Mg0.6-xAl2Si1.8O7.2: xEu2+ with a broad emission spectrum and thermal anti-quenching property9Cuboid-Size-Controlled Color-Tunable Eu-Doped Alkali–Lithosilicate Phosphors86Highly Efficient Green‐to‐Yellowish‐Orange Emitting Eu2+‐Doped Pyrophosphate Phosphors with Superior Thermal Quenching Resistance for w‐LEDs99Zero-thermal-quenching of Mn4+ far-red-emitting in LaAlO3 perovskite phosphor via energy compensation of electrons’ traps194Color tuning of β-Ca3(PO4)2-type phosphor with enhanced quantum efficiency via self-charge compensation for healthy and warm solid state lighting application55A novel Mn4+-activated Li3CsGe8O18 red phosphor and cation substitution induced photoluminescence improvement11Tunable chromaticity and high color rendering index of WLEDs with CaAlSiN 3 :Eu 2+ and YAG:Ce 3+ dual phosphor‐in‐silica‐glass42Highly efficient phosphor-glass composites by pressureless sintering262Activation of infrared emission in (iodine, nickel) Co-Doped CdS nanobelts for solar cells and optoelectronic applications7A high quantum efficiency CaAlSiN3:Eu2+ phosphor-in-glass with excellent optical performance for white light-emitting diodes and blue laser diodes188Role of Lithium Codoping in Enhancing the Scintillation Yield of Aluminate Garnets15High-efficiency fully concentrated Na3Eu(VO4)2 phosphor with excellent thermal stability for white light-emitting diodes4Predicting Thermal Quenching in Inorganic Phosphors149Local Structure Distortion Induced Broad Band Emission in the All-Inorganic BaScO2F:Eu2+ Perovskite55A single Mn2+ ions activated fluosilicate glass with continuously tunable broadband emission from 475 nm to 800 nm8Two targets with one strategy: Insights into the role of aluminum atoms on the luminescence properties and thermal stability in Mn4+-doped calcium aluminozincate phosphor16Ternary solid solution phosphors Ca1--Li Al1--Si1++N3-O :Ce3+ with enhanced thermal stability for high-power laser lighting67Cation sites modification enhanced luminescence and thermal quenching characteristic in the blue light-emitting Na3Sc2-xZnx(PO4)3:0.03Eu2+ phosphors10Great emission enhancement of high-efficient broadband K3YSi2O7: Eu red phosphor via enhancing crystallinity44Localized Charge Accumulation Driven by Li+ Incorporation for Efficient LED Phosphors with Tunable Photoluminescence77Manipulating the redistribution of single dopant via crystal-site engineering approach in Ba4Gd3(K1-xNax)3(PO4)6F2:Eu2+ phosphors for warm white light emitting diodes45Improving thermal stability and quantum efficiency through solid solution for Ce3+-activated (Ba1-Sr )3Y2(BO3)4 phosphors16Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications241Highly efficient Eu3+-activated Ca2Gd8Si6O26 red-emitting phosphors: A bifunctional platform towards white light-emitting diode and ratiometric optical thermometer applications49Tunable photoemission and energy transfer of heavily Bi3+,Eu3+ co-doped Y4GeO8 phosphors41Defect engineering in trivalent ion doped ceria through vanadium assisted charge compensation: insight using photoluminescence, positron annihilation and electron spin resonance spectroscopy22Enhancing the near-infrared photocatalytic activity and upconversion luminescence of BiOCl:Yb 3+ –Er 3+ nanosheets with polypyrrole in situ modification25Heteronuclear NMR Spectroscopy in the Undergraduate Curriculum: Direct and Indirect Effects0Highly efficient green-emitting phosphor Sr 4 Al 14 O 25 :Ce,Tb with low thermal quenching and wide color gamut upon UV-light excitation for backlighting display applications57Turning-on persistent luminescence out of chromium-doped zinc aluminate nanoparticles by instilling antisite defects under mild conditions13High lumen density of Al 2 O 3 ‐LuAG: Ce composite ceramic for high‐brightness display39Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors12Single phase white LED phosphor Ca3YAl3B4O15:Ce3+,Tb3+,Sm3+ with superior performance: Color-tunable and energy transfer study184Luminescent properties of Na2GdMg2(VO4)3:Eu3+ red phosphors for NUV excited pc-WLEDs59Enhancement of fluorescence and magnetic properties of CeF3:RE3+ (Tb, Gd) nanoparticles via multi-band UV excitation and Li doping regulation36A single-phase full-color phosphor Sr2Ca2La(PO4)3O:Eu2+,Tb3+,Mn2+: Photoluminescence and energy transfer16Designed glass frames full color in white light-emitting diodes and laser diodes lighting79Improving CRI and Luminous Efficiency of Phosphor-Converted Full-Spectrum WLEDs by Powder Sedimentation Packaging27Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146Synthesis, structure and photoluminescence properties of Ca2YTaO6:Bi3+\Eu3+ double perovskite white light emitting phosphors50Photoluminescence Spectra Changes and Thermal Stability Improvement for Ba 1.98 Mg 1−x Al 2x Si 2−x O 7 :0.02Eu 2+ Green Phosphor with Al–Al replacing Si–Mg1Single phase multi color emitting Ca 2 LuTaO 6 : Dy 3+ /Eu 3+ double perovskite oxide phosphors31Robust thermal performance of red-emitting phosphor composites for white light-emitting diodes: Energy transfer and oxygen-vacancy induced electronic localization43Europium‐doped NaBaB9O15 phosphors with controllable blue/red dual-band emissions through self-reduction for plant growth LEDs18Turning on the luminescence of Sr5(PO4)3Cl: Eu2+ by doping of La, Gd and Lu ions for full-spectrum lighting application18Rapid Synthesis of Red‐Emitting Sr2Sc0.5Ga1.5O5:Eu2+ Phosphors and the Tunable Photoluminescence Via Sr/Ba Substitution92Local structure and luminescent properties of Cs2KGaF6:Mn4+ phosphor for backlight white LEDs32Bi3+ occupancy rearrangement in K2-xAxMgGeO4 phosphor to achieve ultra-broad-band white emission based on alkali metal substitution engineering38Selective Addition of Al 3+ into Ba 2 SiO 4 :Eu 2+ Phosphor to Improve Its Luminescence and Thermal Stability3Controllable structural ordering via chemical substitution to the efficient and thermally stable luminescence in NASICON-type phosphor Series: Na1+Hf2−Sc (PO4)3:Eu12Na Replaces Rb towards High‐Performance Narrow‐Band Green Phosphors for Backlight Display Applications54Composition and structure design of three-layered composite phosphors for high color rendering chip-on-board light-emitting diode devices84Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications173Fluorescence regulation derived from Eu 3+ in miscible-order fluoride-phosphate blocky phosphor7Enhanced up-conversion luminescence and temperature sensing property of Ba3-xSrxLu4O9:Tm3+/Yb3+ phosphors44Robust thermal performance and color purity of samarium based deep red emitting phosphor for near-UV chip-based high-color-rendering34Dilute Element Compounds: A Route to Enriching Inorganic Functional Materials5Color tunability imparted by multi-peak emissions of Eu3+ in fluoride-phosphate phosphors3Bright Red-Emitting Ca3LuAl3B4O15:Ce3+,Sm3+ Phosphors with High Thermal Stability for Elevating the Color Rendering of Near-Ultraviolet-Based White-Light-Emitting Diodes21An efficient far‐red emission Sr 2 InSbO 6 :Mn 4+ , M (M = Li + , Na + , and K + ) phosphors for plant cultivation LEDs46Improved photoluminescence and multi-mode optical thermometry of Er3+/Yb3+ co-doped (Ba,Sr)3Lu4O9 phosphors66Rare-earth single atom based luminescent composite nanomaterials: Tunable full-color single phosphor and applications in WLEDs52Achievement of high-efficiency sunlight-like emission in Rb2CaP2O7: Ce3+, Eu2+ phosphors16NaAlSiO4: Eu2+ Glass Ceramics: Self‐Reduced In Situ Growth and High‐Power LED/LD Lighting44Bifunctional samarium activated red-emitting and thermal resistant phosphor for simultaneous field emission displays and white light-emitting diodes32Tailoring Luminescent Properties of SrS:Ce by Modulating Defects: Sr-Deficiency and Na+ Doping1Two strategies to achieve color adjustment of Eu2+-doped garnet Lu2Mg2Al2Si2O12 phosphors14Enhancement of Eu2+ photoluminescence behavior in NaBaB9O15 based on the K+ doping13Composition and Antithermal Quenching of Noninteger Stoichiometric Eu2+-Doped Na-β-Alumina with Cyan Emission for Near-UV WLEDs37Variation from Zero to Negative Thermal Quenching of Phosphor with Assistance of Defect States45Crystal structure, luminescence properties and thermal stability of novel Sr2CaLa(VO4)3: Sm3+ phosphor synthesized by the combustion method45A novel single-phased white light emitting phosphor with single Eu2+ doped whitlockite structure25Correlated Na+ Ion Migration Invokes Zero Thermal Quenching in a Sodium Superionic Conductor-type Phosphor25A full visible LED enabled by a broadband yellow emission nepheline phosphor derived from a europium doped SOD zeolite16A novel red-emitting phosphor K 2 MgGeO 4 :Eu 3+ for WLEDs: zero-thermal quenching induced by heterovalent substitution27Achieving stable photoluminescence by double thiacalix[4]arene-capping: the lanthanide-oxo cluster core matters10Broad luminescence tuning in Mn 2+ -doped Rb 2 Zn 3 (P 2 O 7 ) 2 via doping level control based on multiple synergies11Compensation effect of electron traps for enhanced fluorescence intensity ratio thermometry performance22Highly thermostable white-emitting Ca 9 ZnK(PO 4 ) 7 :Ce 3+ ,Dy 3+ single-phase phosphor with tunable photoluminescence and energy transfer31Multimodal dynamic color-tunable persistent luminescent phosphor Ca 3 Al 2 Ge 3 O 12 :Mn 2+ ,Cr 3+ for anti-counterfeiting and industrial inspection27Temperature-Responsive Photoluminescence and Elastic Properties of 1D Lead Halide Perovskites R- and S-(Methylbenzylamine)PbBr36Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors23Tailoring the Luminescent Properties of SrS:Ce3+ by Sr-Deficiency and Na+ Doping15Effect of ionic couple substitution on the enhanced photoluminescence properties of (BaMg)1-x(KxAl10+x)O17:Eu2+ phosphor for white LEDs application7Thermal-responsive dynamic color-tunable persistent luminescence from green to deep red for advanced anti-counterfeiting76Suppressing Non‐Radiative Relaxation through Single‐Atom Metal Modification for Enhanced Fluorescence Efficiency in Molybdenum Disulfide Quantum Dots22Suppressing Non‐Radiative Relaxation through Single‐Atom Metal Modification for Enhanced Fluorescence Efficiency in Molybdenum Disulfide Quantum Dots6Interstitial Li + Occupancy Enabling Radiative/Nonradiative Transition Control toward Highly Efficient Cr 3+ -Based Near-Infrared Luminescence83Active thermal-fuse for stopping blue light leakage of white light-emitting diodes driven by constant current10All‐Inorganic Functional Phosphor–Glass Composites by Light Curing Induced 3D Printing for Next‐Generation Modular Lighting Devices18A Zero-Thermal-Quenching Blue Phosphor for Sustainable and Human-Centric WLED Lighting133Ultrastable Photoluminescence Enabled by 1D Rare-Earth Metal–Organic Frameworks Based on Double Thiacalix[4]arene-Capped Nodes19A Triple-Doped Phosphor Strategy for the Conversion of Cool and Warm White Light10Engineering the local structure of ZnGa2O4: Cr3+ via Mg substitution to realize superior luminescence19Zero-thermal-quenching of LiAl5O8: Eu2+, Mn2+ phosphors by energy transfer and defects engineering26Novel Sm3+-activated YCa4O(BO3)3 phosphors with high quantum efficiency and thermal stability for red-backlight display and indoor illumination28To Luminesce or to Change Valence? Insight into the Wavelength Dependency of the Reversible Valence Switching of Europium in Sr3SiO512Tuning the thermal quenching properties of Ga3+-modified LiTaO3:Bi3+ phosphor through defect engineering strategy12Layered array Al2O3-LuAG: Ce composite ceramic phosphors for high-brightness display20A Negative-Thermal-Quenching Phosphor Achieved by Energy Transfer0Eu 2+ and Mn 2+ co-doped Lu 2 Mg 2 Al 2 Si 2 O 12 phosphors for high sensitivity and multi-mode optical pressure sensing38Large Negative Thermal Quenching of Upconversion Luminescence Through Selective Excitation in a Yag:Yb/Er Transparent Ceramics0RETRACTED: Revolutionizing Material Science: Exploring the Novel Applications of Thermally-Enhanced Processes in Next-Generation Materials1Photoluminescence and mixed-valence tuning of Eu in Sr2(Al,Ga)2SiO7 phosphors for sensitive thermometric applications9Highly Stable and Photoluminescent CsPbBr3/Cs4PbBr6 Composites for White-Light-Emitting Diodes and Visible Light Communication28Engineering charge-transfer interactions for red-emitting SrLa(Sc,Ga)O4:Ce3+ phosphor with improved thermal stability23Local Structure and Self‐Defect Evolution under Nonstoichiometric Effect Unlock Zero‐Thermal‐Quenching15Correlating O-deficiency and luminescence property of Tb3+ doped SrO16A universal hydrochloric acid-assistant powder-to-powder strategy for quick and mass preparation of lead-free perovskite microcrystals64Synthesis and optical properties of highly efficient Na3KMg7(PO4)6:Eu2+ blue phosphor for full-spectrum white-light-emitting diodes: The role of Li2CO3 flux30Cyan-to-yellow color tunable NaAlSiO4:Eu2+ with high quantum efficiency and thermal stability for white light-emitting diodes14Large negative thermal quenching of upconversion luminescence through selective excitation in a YAG:Yb/Er transparent ceramics8High-Quantum-Efficiency Blue Phosphors with Superior Thermal Stability Derived from Eu3+-Doped Faujasite Y Zeolite11Sheaf-like Manganese-Doped Zinc Silicate with Enhanced Photoluminescence Performance0Eco-Friendly Zn–Ag–In–Ga–S Quantum Dots: Amorphous Indium Sulfide Passivated Silver/Sulfur Vacancies Achieving Efficient Red Light-Emitting Diodes34Self‐Trapped Excitons‐Based Warm‐White Afterglow by Room‐Temperature Engineering toward Intelligent Multi‐Channel Information System53Dual-mode luminous and afterglow Ca3Al2Ge3O12:Yb3+, Er3+ phosphors for anti-counterfeiting and fingerprint verification25Novel Sm3+ doped YCa4O(BO3)3 phosphors: Structural and, low and room temperature luminescent insights30A negative-thermal-quenching LaMgAl11O19: Er3+, Sm3+ phosphor achieved by energy transfer from Er3+ to Sm3+11Highly Efficient Narrow-Band Green-Emitting Na 3 K 5 (Li 3 SiO 4 ) 8 :Eu 2+ Phosphor with Low Thermal Quenching50Tunable afterglow Ca 1 − x Sr x Al 2 O 4 :Eu 2+ , Nd 3+ phosphors with dependence of an excitation wavelength3Defect compensation and intervalence charge transfer state-based Pr 3+ -doped niobate antithermal quenching phosphors5

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  2. Aliovalent substitution toward reinforced structural rigidity in Ce 3+ -doped garnet phosphors featuring improved performance

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  3. An insight into the preferential substitution and structure repair in Eu 2+ -doped whitlockite-type phosphors based on the combined experimental and theoretical calculations

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  4. Design of a novel scandium silicate based blue-emitting phosphor with high efficiency and robust thermal stability for warm WLEDs and field emission displays

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  5. Lithium ion doping triggered splendid quantum efficiency and thermal stability in Li 2 SrSiO 4 : x Eu 2+ phosphors for optical thermometry and high luminous efficiency white-LED

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