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RESEARCH PAPER · Chemistry of Materials · 2020

Local Structure Distortion Induced Broad Band Emission in the All-Inorganic BaScO2F:Eu2+ Perovskite

Shruti Hariyani, Jakoah Brgoch

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Local Structure Distortion Induced Broad Band Emission in the All-Inorganic BaScO2F:Eu2+ PerovskiteOriginalDual-color upconversion photoluminescence induced by disordered Yb3+-Ti4+ pairs and defects in highly stable langbeinite-type Rb2Ti0.80Yb1.20(PO4)3 single crystal6Insight into the crystal structure and photoluminescence properties of an extremely broadband yellow-emitting phosphor Sr 8 MgCe(PO 4 ) 7 :Eu 2+11Ba 3 YB 3 O 9 based phosphor ceramic plates with excellent thermal stability for wLED applications18Magical polyhedral twist via chemical unit co-substitution in LaAlO 3 :Mn 4+ to greatly enhance the zero phonon line for high-efficiency plant-growth LEDs49Ultra-bright green-emitting phosphors with an internal quantum efficiency of over 90% for high-quality WLEDs39Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors11A Study on the Anti-thermal Dy3+/Eu3+ Co-doped BaLa4Si3O13 Red Phosphors for White-Light-Emitting Diodes and Optical Thermometry Applications41Regulating anti-site defects in MgGa2O4:Mn4+ through Mg2+/Ge4+ doping to greatly enhance broadband red emission for plant cultivation27Warm white light emission, thermochromic property and long persistent luminescence derived from multi-sites of Eu2+/Eu3+ in host lattice71Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction12Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230Novel Cyan-Green-Emitting Bi3+-Doped BaScO2F, R+ (R = Na, K, Rb) Perovskite Used for Achieving Full-Visible-Spectrum LED Lighting51A green emitting (Ba,Ca)ScO 2 F:Bi 3+ ,K + perovskite phosphor with high efficiency and good thermal stability for LED backlight displays6Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba 1− x Sr x ScO 2 F:Eu 2+12A super stable Near-Infrared garnet phosphor resistant to thermal Quenching, thermal degradation and hydrolysis57Polyhedron engineering by chemical unit co-substitution in LaAlO3:0.02Pb2+ to generate multimode and condition-sensitive luminescence for dynamic anticounterfeiting34Mechanochemical Fabrication of a Mn4+-Activated Inorganic Rb2KTiOF5 Perovskite Red Phosphor for White Light-Emitting Diodes3Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group19Unraveling the Evolution of Luminescence Center in an Eu‐Doped Orthophosphate: Beyond the Probe Limitation to Trace Activator5Luminescence in the solid state7Design of novel cyan phosphor Ca7NaLu(PO4)6:Eu2+ for full-visible-spectrum white LED: enhanced thermal stability and tuned emission by neighbor cation effect30Cationic pair substitution in LaAlO 3 :Mn 4+ for octahedral-tilting-dependent zero-phonon line15Enhanced optical properties and mechanisms of Ba-doped LaMnO3 perovskite ceramic coating13Quantifying rigidity for thermally stable Cr 3+ phosphors9Color tunable (Ba,Ca)ScO2F: Eu2+, Bi3+, K+ perovskite with dependence of excitation wavelength for advanced anti-counterfeiting application9Active learning to overcome exponential-wall problem for effective structure prediction of chemical-disordered materials17A novel ultra-broadband red LaGeSbO6:Mn4+ phosphor with excellent responsiveness to phytochrome PFR for plant growth21Cerium Ion Promoting the Emission of Self-Trapped Excitons of Quasi-2D Europium Halide Perovskites for Self-Activated White Light-Emitting10Emergence of a Lanthanide Chalcogenide as an Ideal Scintillator for a Flexible X‐ray Detector37Emergence of a Lanthanide Chalcogenide as an Ideal Scintillator for a Flexible X‐ray Detector9Improved Thermal and Chemical Stability of Oxynitride Phosphor from Facile Chemical Synthesis for Vehicle Cornering Lights50Improved Thermal and Chemical Stability of Oxynitride Phosphor from Facile Chemical Synthesis for Vehicle Cornering Lights2Narrow-Band Deep-Blue Emission and Superior Thermal Stability of Fluoroaluminate Phosphor Based on Tungsten Bronze-Type Mineral Structure5Controlling the Luminescence of Rare-Earth Chalcogenide Iodides RE3(Ge1–xSix)2S8I (RE = La, Ce, and Pr) and Ce3Si2(S1–ySey)8I8Optical and luminescent properties of quasi-stoichiometric YAG: Cr3+ ceramics12The development of a new efficient red phosphor based on Eu2+ doped traditional inorganic oxygenate-perovskite compounds7Regulation of Anti‐Thermal Quenching and Emission Color in Eu 2+ ‐Activated Na‐Beta‐Alumina Phosphors for Full‐Spectrum Illumination11A guide to comprehensive phosphor discovery for solid-state lighting245Absolutely Structural Disorder Boosting Bandwidth toward Full‐Spectrum White Light from Single Occupancy of Activator36Revealing the Role of Organic Ligands in Deep-Blue-Emitting Colloidal Europium Bromide Perovskite Nanocrystals13Tunable photoluminescence and energy transfer in Dy 3+ and Eu 3+ co-doped NaCaGd(WO 4 ) 3 phosphors for pc-WLED applications9Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy24Tunable photoluminescence in Eu2+-activated KCaLa(PO4)2 phosphor through structural disorder3A superb blue phosphor Na3Ba2Sr(PO4)3:Eu2+ with high quantum yield and zero-thermal-quenching for plant growth LEDs5Structure and luminescence of Gd3Ga3MgSiO12:Cr3+ garnet phosphor with highly efficient broadband near-infrared emitting toward pc-LED application7Efficient and thermal stable broadband near-infrared emitting Gd2CaAl3GaZrO12:Cr3+ garnet phosphor: structure, luminescence, and pc-LED application9Probing the Charge Density and Physical Properties of Perovskite‐Derived Alkaline Oxy‐Fluoride Compounds for Supercapacitor Applications2Flexible Ba 2 LuTaO 6 :Tb 3+ /Eu 3+ Perovskites with Multicolor Luminescence and Photochromism for X‐Ray Imaging, Visual Dosimetry, and Encryption3Revealing the Multifunctionality of Quaternary Oxyfluorides ( X ScO 2 F, X = Ba, Sr, Ca, and Ra) Through First‐Principles for Future‐Ready Flexible Photovoltaics2Self-reduction regulation in europium-doped metaphosphate phosphor1Semiconducting and optical characteristics of KScO₂F, RbScO₂F and CsScO₂F for photovoltaic applications1X-ray-induced photochromism and luminescence in inorganic materials: mechanisms, defect engineering, and advanced applications0

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  1. Dual-color upconversion photoluminescence induced by disordered Yb3+-Ti4+ pairs and defects in highly stable langbeinite-type Rb2Ti0.80Yb1.20(PO4)3 single crystal

    Journal of Alloys and Compounds · 2020-12-07

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  2. Insight into the crystal structure and photoluminescence properties of an extremely broadband yellow-emitting phosphor Sr 8 MgCe(PO 4 ) 7 :Eu 2+

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  3. Ba 3 YB 3 O 9 based phosphor ceramic plates with excellent thermal stability for wLED applications

    Dalton Transactions · 2021-01-01

    Weiwei Wu, Yuanpeng Zhang, Yuanpeng Zhang, Yuepin Zhang, Yuepin Zhang, Jianxu Hu

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  4. Magical polyhedral twist via chemical unit co-substitution in LaAlO 3 :Mn 4+ to greatly enhance the zero phonon line for high-efficiency plant-growth LEDs

    Journal of Materials Chemistry C · 2021-01-01

    Siyuan Li, Qi Zhu, Xudong Sun, Ji‐Guang Li

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  5. Ultra-bright green-emitting phosphors with an internal quantum efficiency of over 90% for high-quality WLEDs

    Dalton Transactions · 2021-01-01

    Yanyan Li, Yuan Yin, Tianli Wang, Junxiao Wu, Jia Zhang, Shuaishuai Yu, Meiguang Zhang, Lei Zhao, Wenjie Wang

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  6. Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors

    ACS Sustainable Chemistry & Engineering · 2021-01-07

    Hongzhi Zhang, Yuchang Su, Zhongbao Luo, Jing Zhang, Jinyu Yang

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  7. A Study on the Anti-thermal Dy3+/Eu3+ Co-doped BaLa4Si3O13 Red Phosphors for White-Light-Emitting Diodes and Optical Thermometry Applications

    Industrial & Engineering Chemistry Research · 2021-02-10

    Fan Liao, Bingqing Shen, Weiwei Wu, Yuanpeng Zhang, Jianxu Hu

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  8. Regulating anti-site defects in MgGa2O4:Mn4+ through Mg2+/Ge4+ doping to greatly enhance broadband red emission for plant cultivation

    Journal of Materials Research and Technology · 2021-04-24

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  9. Warm white light emission, thermochromic property and long persistent luminescence derived from multi-sites of Eu2+/Eu3+ in host lattice

    Chemical Engineering Journal · 2021-06-27

    Dan Zhao, Shirui Zhang, Ruijuan Zhang, Baozhong Liu, Qingxia Yao

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  10. Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications

    Chemistry of Materials · 2021-07-13

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  11. Ca[B 8 O 11 (OH) 4 ] : Eu 2+ – A Highly Efficient Deep Blue‐Emitting Phosphor Prepared by Low‐Temperature Self‐reduction

    Chemistry - A European Journal · 2021-08-16

    Pan Liang, Wen‐Li Lian, Zhi‐Hong Liu

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  12. Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence

    Advanced Functional Materials · 2021-09-29

    Zhiyu Yang, Yifei Zhao, Yayun Zhou, Jianwei Qiao, Yu‐Chun Chuang, Мaxim S. Моlokeev, Zhiguo Xia

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  13. Novel Cyan-Green-Emitting Bi3+-Doped BaScO2F, R+ (R = Na, K, Rb) Perovskite Used for Achieving Full-Visible-Spectrum LED Lighting

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  14. A green emitting (Ba,Ca)ScO 2 F:Bi 3+ ,K + perovskite phosphor with high efficiency and good thermal stability for LED backlight displays

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  15. Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba 1− x Sr x ScO 2 F:Eu 2+

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  16. A super stable Near-Infrared garnet phosphor resistant to thermal Quenching, thermal degradation and hydrolysis

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  17. Polyhedron engineering by chemical unit co-substitution in LaAlO3:0.02Pb2+ to generate multimode and condition-sensitive luminescence for dynamic anticounterfeiting

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  18. Mechanochemical Fabrication of a Mn4+-Activated Inorganic Rb2KTiOF5 Perovskite Red Phosphor for White Light-Emitting Diodes

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  19. Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group

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  20. Unraveling the Evolution of Luminescence Center in an Eu‐Doped Orthophosphate: Beyond the Probe Limitation to Trace Activator

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  21. Luminescence in the solid state

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  22. Design of novel cyan phosphor Ca7NaLu(PO4)6:Eu2+ for full-visible-spectrum white LED: enhanced thermal stability and tuned emission by neighbor cation effect

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  23. Cationic pair substitution in LaAlO 3 :Mn 4+ for octahedral-tilting-dependent zero-phonon line

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  24. Enhanced optical properties and mechanisms of Ba-doped LaMnO3 perovskite ceramic coating

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  25. Quantifying rigidity for thermally stable Cr 3+ phosphors

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  26. Color tunable (Ba,Ca)ScO2F: Eu2+, Bi3+, K+ perovskite with dependence of excitation wavelength for advanced anti-counterfeiting application

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  27. Active learning to overcome exponential-wall problem for effective structure prediction of chemical-disordered materials

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  28. A novel ultra-broadband red LaGeSbO6:Mn4+ phosphor with excellent responsiveness to phytochrome PFR for plant growth

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  29. Cerium Ion Promoting the Emission of Self-Trapped Excitons of Quasi-2D Europium Halide Perovskites for Self-Activated White Light-Emitting

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  30. Emergence of a Lanthanide Chalcogenide as an Ideal Scintillator for a Flexible X‐ray Detector

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  31. Emergence of a Lanthanide Chalcogenide as an Ideal Scintillator for a Flexible X‐ray Detector

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  32. Improved Thermal and Chemical Stability of Oxynitride Phosphor from Facile Chemical Synthesis for Vehicle Cornering Lights

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  33. Improved Thermal and Chemical Stability of Oxynitride Phosphor from Facile Chemical Synthesis for Vehicle Cornering Lights

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  34. Narrow-Band Deep-Blue Emission and Superior Thermal Stability of Fluoroaluminate Phosphor Based on Tungsten Bronze-Type Mineral Structure

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  35. Controlling the Luminescence of Rare-Earth Chalcogenide Iodides RE3(Ge1–xSix)2S8I (RE = La, Ce, and Pr) and Ce3Si2(S1–ySey)8I

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  36. Optical and luminescent properties of quasi-stoichiometric YAG: Cr3+ ceramics

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  37. The development of a new efficient red phosphor based on Eu2+ doped traditional inorganic oxygenate-perovskite compounds

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  38. Regulation of Anti‐Thermal Quenching and Emission Color in Eu 2+ ‐Activated Na‐Beta‐Alumina Phosphors for Full‐Spectrum Illumination

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  39. A guide to comprehensive phosphor discovery for solid-state lighting

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  40. Absolutely Structural Disorder Boosting Bandwidth toward Full‐Spectrum White Light from Single Occupancy of Activator

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  44. Tunable photoluminescence in Eu2+-activated KCaLa(PO4)2 phosphor through structural disorder

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  46. Structure and luminescence of Gd3Ga3MgSiO12:Cr3+ garnet phosphor with highly efficient broadband near-infrared emitting toward pc-LED application

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  48. Probing the Charge Density and Physical Properties of Perovskite‐Derived Alkaline Oxy‐Fluoride Compounds for Supercapacitor Applications

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  49. Flexible Ba 2 LuTaO 6 :Tb 3+ /Eu 3+ Perovskites with Multicolor Luminescence and Photochromism for X‐Ray Imaging, Visual Dosimetry, and Encryption

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