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RESEARCH PAPER · Chemistry of Materials · 2020

Cuboid-Size-Controlled Color-Tunable Eu-Doped Alkali–Lithosilicate Phosphors

Mu‐Huai Fang, Carl Osby M. Mariano, Po-Yen Chen, Shu‐Fen Hu, Ru‐Shi Liu

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Cuboid-Size-Controlled Color-Tunable Eu-Doped Alkali–Lithosilicate PhosphorsOriginalDesign of core–shell phosphors with tunable luminescence and improved thermal stability by coating with g-C 3 N 418Thermally Stable and Deep Red Luminescence of Sr1–xBax[Mg2Al2N4]:Eu2+ (x = 0–1) Phosphors for Solid State and Agricultural Lighting Applications64Discovery of a Quaternary Sulfide, Ba2–xLiAlS4:Eu2+, and Its Potential as a Fast-Decaying LED Phosphor38Broadband NaK2Li[Li3SiO4]4:Ce Alkali Lithosilicate Blue Phosphors19Powder synthesis and luminescence properties of green emitting Ba2LiSi7-xAlxN12-xOx:Eu2+ phosphor7Why Do Relative Intensities of Charge Transfer and Intra-4f Transitions of Eu3+ Ion Invert in Yttrium Germanate Hosts? Unravelling the Underlying Intricacies from Experimental and Theoretical Investigations31Enticing applications of near‐infrared phosphors: Review and future perspectives44Site Occupation and Spectral Assignment in Eu 2+ -Activated β-Ca 3 (PO 4 ) 2 -Type Phosphors: Insights from First-Principles Calculations21Zero-thermal-quenching and improved chemical stability of a UCr4C4-type phosphor via crystal site engineering42A data-driven approach to predicting band gap, excitation, and emission energies for Eu 2+ -activated phosphors28Dual-emission Eu-doped Ca 2−x Sr x PN 3 nitridophosphate phosphors prepared by hot isostatic press5High-Performance NaK2Li[Li3SiO4]4:Eu Green Phosphor for Backlighting Light-Emitting Diodes52The Phase Transition and Photoluminescence Properties of (Ca9−x Sr x )Mg1.5(PO4)7:Eu2+ Solid-Solution Phosphors3The angular overlap model of ligand field theory for f elements: An intuitive approach building bridges between theory and experiment39Defect Engineering in a Eu2+-Doped β-Al2O3 Structure Blue Phosphor and Its Controllable Zero-Thermal Quenching Luminescence97Tailoring of White Luminescence in a NaLi 3 SiO 4 :Eu 2+ Phosphor Containing Broad‐Band Defect‐Induced Charge‐Transfer Emission183Na Replaces Rb towards High‐Performance Narrow‐Band Green Phosphors for Backlight Display Applications53Bismuth‐activated, narrow‐band, cyan garnet phosphor Ca 3 Y 2 Ge 3 O 12 :Bi 3+ for near‐ultraviolet‐pumped white LED application39Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Importance of Long‐Range Channel Sr Displacements for the Narrow Emission in Sr[Li2Al2O2N2]:Eu2+ Phosphor20Novel Narrow Band Cyan‐Green Phosphor LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ with Enhanced Suppression of Second Broad Band Emission17Highly efficient and zero-thermal-quenching blue-emitting Eu2+-activated K-beta-alumina phosphors72Li2CaSi2N4:Sm3+: A nitride-based red phosphor with excellent temperature sensitivity and cathodoluminescence for temperature sensor and FED26Linking Macro- and Micro-structural Analysis with Luminescence Control in Oxynitride Phosphors for Light-Emitting Diodes13Eu 2+ activated NaBa 3 Si 2 O 7 F: A new efficient blue‐emitting luminescent material for solid‐state lighting and display7Chasing Down the Eu2+ Ions: The Delicate Structure−Property Relationships in the Ultra‐Narrow Band Phosphor K1.6Na2.1Li0.3[Li3SiO4]4:Eu2+35Chemothermal pulverization: Crushing titanate crystals to obtain nanosized powders via high‐temperature treatment3Improvement of the thermal stability of bluish-cyan emitting phosphor Y 2 MgAl 4 SiO 12 :Eu 2+ using substitution cations (Zn, Ca, Sr) for white LEDs10Tuning crystal structure and luminescence of Eu 2+ -activated LiSr 1– x Ba x PO 4 solid solution for white light-emitting diodes5Development of narrow band emitting phosphors for backlighting displays and solid state lighting using a clean and green energy technology22Site occupancy and luminescence of Ce3+-doped NaK2Li[Li3SiO4]4: A first-principles study3How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Microscopic Mechanism of the Heat‐Induced Blueshift in Phosphors and a Logarithmic Energy Dependence on the Nearest Dopant–Vacancy Distance24Microscopic Mechanism of the Heat‐Induced Blueshift in Phosphors and a Logarithmic Energy Dependence on the Nearest Dopant–Vacancy Distance1Electronic and Optical Properties of Eu2+-Activated Narrow-Band Phosphors for Phosphor-Converted Light-Emitting Diode Applications: Insights from a Theoretical Spectroscopy Perspective70Role of the Rigid Host Structure in Narrow-Band Green Emission of Eu2+ in Rb2Na2(Li3SiO4)4: Insights into Electron–Phonon Coupling15Evolutionary Generation of Phosphor Materials and Their Progress in Future Applications for Light-Emitting Diodes563Towards single broadband white emission in Rb0.5K1.5CaPO4(F, Cl): Eu2+ via selective site occupancy engineering for solid-state lighting applications42Tuning emission color of Eu2+-activated phosphor through phase segregation22Highly efficient and tunable broadband UV excitable Ba9Lu2Si6O24:Eu2+, Mn2+ single-phase white-light-emitting phosphors21Eu 2+ luminescence in CaYGaO 4 olivine: a new efficient red phosphor for warm illumination47Mixed Microscopic Eu 2+ Occupancies in the Next‐Generation Red LED Phosphor Sr[Li 2 Al 2 O 2 N 2 ]:Eu 2+ (SALON:Eu 2+ )37Site‐Engineering for Controlling Multiple‐Excitation and Emission in Eu2+‐Activated CaSrSiO4 Phosphors in Marine Fisheries21From Framework to Layers Driven by Pressure – The Monophyllo‐Oxonitridophosphate β‐MgSrP3N5O2 and Comparison to its α‐Polymorph16A First-Principles Explanation of the Luminescent Line Shape of SrLiAl 3 N 4 :Eu 2+ Phosphor for Light-Emitting Diode Applications22Narrow-Band Deep-Blue Emission and Superior Thermal Stability of Fluoroaluminate Phosphor Based on Tungsten Bronze-Type Mineral Structure5Luminescence Properties of Rare Earth (Eu3+ and Sm3+)-Doped Double Perovskite Sr2YNbO6 Phosphors16Photoluminescence of Mn2+ in the Borosulfate Zn[B2(SO4)4] : Mn2+—A Tool to Detect Weak Coordination Behavior of Ligands18Photolumineszenz von Mn2+ in dem Borosulfat Zn[B2(SO4)4] : Mn2+ – Eine Möglichkeit zum Nachweis schwach koordinierender Liganden0Crystal structures and luminescence properties of Li6 MN4:Ce3+ (M = Mo, W)1On the luminescence properties of Eu2+ with multiple-site occupancy in silicate K2MgSi3O83Peculiar β-Li2TiO3: Eu3+ red light emitting dominated by electric dipole transition: Asymmetric lattice point regulation and luminescence performance14Blue Emitting SrBe1−xSi2+xO3−2xN2+2x:Eu2+ (x≈0.1)2Green‐Emitting Oxonitridoberyllosilicate Ba[BeSiON 2 ]:Eu 2+ for Wide Gamut Displays17A theoretical spectroscopy study of the photoluminescence properties of narrow band Eu 2+ -doped phosphors containing multiple candidate doping centers. Prediction of an unprecedented narrow band red phosphor10Crystal structure, Bi 3+ yellow luminescence, and high quantum efficiency of Ba 3 SbAl 3 Ge 2 O 14 :Bi 3+ phosphor for white light-emitting diodes31Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Multicationic Tetrahedra Networks: Alkaline‐Earth‐Centered Polyhedra and Non‐Condensed AlN6‐Octahedra in the Imidonitridophosphates AE2AlP8N15(NH) (AE=Ca, Sr, Ba)4Tunable Narrow‐Band Cyan‐Emission of Eu2+‐doped Nitridomagnesophosphates Ba3−xSrx[Mg2P10N20] : Eu2+ (x=0–3)1Tunable Narrow‐Band Cyan‐Emission of Eu2+‐doped Nitridomagnesophosphates Ba3−xSrx[Mg2P10N20] : Eu2+ (x=0–3)24Preparation of BaAl2-Ga Si2O8:Ce3+, M+ (Li, Na, K) blue-cyan phosphors based on charge compensation and cation substitution strategies and luminescence performance study21CaLi2PN3 – A Quaternary Chain‐Type Nitridophosphate by Medium‐Pressure Synthesis4Cyan gallate phosphor luminescence enhanced and the full-spectrum WLED applications2Luminescence Properties of Bi3+-Doped Gd2O3 Phosphor under UV and X-ray Excitation14Adamantane‐Type Nitridophosphate Phosphors AE x Li 10−2 x P 4 N 10 : Eu2 + via Medium‐Pressure Ion‐Exchange Reactions5Adamantane‐Type Nitridophosphate Phosphors AE x Li 10−2 x P 4 N 10 : Eu2 + via Medium‐Pressure Ion‐Exchange Reactions1Nitride phosphors0A Combined Experimental and Computational Study on the Broadening Mechanism of the Luminescence in Narrow-Band Eu2+-Doped Phosphors8A narrow band blue phosphor NaBa 4 Al 2 B 8 O 18 Cl 3 :Eu 2+ for white light emitting diodes5Modulating anti-thermal and concentration quenching for enhanced dysprosium emission6Preparation of blue-cyan phosphor Sr1-yAl2-Ga Si2O8:yCe3+ for high-color-rendering white LEDs via a cation substitution strategy2Designing Ultra‐Narrow‐Band Red Phosphor via Oxygen Vacancy Engineering for Transparent Display Application14Tunable photoluminescence in Eu2+-activated KCaLa(PO4)2 phosphor through structural disorder3Development of Eu 2+ ‐Doped UCr 4 C 4 ‐Type Phosphors Toward Advanced Display Applications22Activator – host structure relations of applied optical materials: a review7Uncovering the origin of emission wavelength shift and anomalous intensity enhancement at elevated temperature in phosphors1Ce 3+ ‐Activated Lithium Rare‐Earth Oxonitridolithosilicates: A New Class of LED Phosphors with Similarities to Garnets6Synergistic quantum dot and powder phosphor layer by layer designs for high-efficiency LED backlights1Eu2+-doping induced phase transformation and blue–cyan luminescence in KAlSi3O8 phosphors5Ba 2+ co-doping enhances phase purity and enables narrow–band green emission in a Sr 5/6 Li 17/6 Al 7/6 O 4 :Eu 2+ phosphor for backlight display applications1Thermally Driven Eu 2+ Site‐Selective Occupation Enables Narrow‐Band Green Emission in an Oxolithoaluminate Phosphor for Backlight Display Applications5Substitutional‐Interstitial Synergetic Solid Solution Enables Efficient Ultra‐Broadband Emission and Multicolor Luminescence2Crystal Structure and Eu 2+ Luminescence of the Lithium Alkaline‐Earth Silicate Fluoride LiBa 2 SiO 4 F0Preparation of high quantum efficiency broadband blue phosphors Ca0.87-xSrxAl2Si2O8:0.13Eu2+ for high color rendering white LEDs via a cation substitution strategy0Be Aware of Impurity Phases: Red Emission in Europium‐Doped CaYGaO 4 Caused by Unintentionally Formed CaS:Eu 2+0

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  1. Design of core–shell phosphors with tunable luminescence and improved thermal stability by coating with g-C 3 N 4

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  2. Thermally Stable and Deep Red Luminescence of Sr1–xBax[Mg2Al2N4]:Eu2+ (x = 0–1) Phosphors for Solid State and Agricultural Lighting Applications

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  3. Discovery of a Quaternary Sulfide, Ba2–xLiAlS4:Eu2+, and Its Potential as a Fast-Decaying LED Phosphor

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  4. Broadband NaK2Li[Li3SiO4]4:Ce Alkali Lithosilicate Blue Phosphors

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  5. Powder synthesis and luminescence properties of green emitting Ba2LiSi7-xAlxN12-xOx:Eu2+ phosphor

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  6. Why Do Relative Intensities of Charge Transfer and Intra-4f Transitions of Eu3+ Ion Invert in Yttrium Germanate Hosts? Unravelling the Underlying Intricacies from Experimental and Theoretical Investigations

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  7. Enticing applications of near‐infrared phosphors: Review and future perspectives

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  8. Site Occupation and Spectral Assignment in Eu 2+ -Activated β-Ca 3 (PO 4 ) 2 -Type Phosphors: Insights from First-Principles Calculations

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  9. Zero-thermal-quenching and improved chemical stability of a UCr4C4-type phosphor via crystal site engineering

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  10. A data-driven approach to predicting band gap, excitation, and emission energies for Eu 2+ -activated phosphors

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  11. Dual-emission Eu-doped Ca 2−x Sr x PN 3 nitridophosphate phosphors prepared by hot isostatic press

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  12. High-Performance NaK2Li[Li3SiO4]4:Eu Green Phosphor for Backlighting Light-Emitting Diodes

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  13. The Phase Transition and Photoluminescence Properties of (Ca9−x Sr x )Mg1.5(PO4)7:Eu2+ Solid-Solution Phosphors

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  14. The angular overlap model of ligand field theory for f elements: An intuitive approach building bridges between theory and experiment

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  15. Defect Engineering in a Eu2+-Doped β-Al2O3 Structure Blue Phosphor and Its Controllable Zero-Thermal Quenching Luminescence

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  16. Tailoring of White Luminescence in a NaLi 3 SiO 4 :Eu 2+ Phosphor Containing Broad‐Band Defect‐Induced Charge‐Transfer Emission

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  17. Na Replaces Rb towards High‐Performance Narrow‐Band Green Phosphors for Backlight Display Applications

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  18. Bismuth‐activated, narrow‐band, cyan garnet phosphor Ca 3 Y 2 Ge 3 O 12 :Bi 3+ for near‐ultraviolet‐pumped white LED application

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  31. Site occupancy and luminescence of Ce3+-doped NaK2Li[Li3SiO4]4: A first-principles study

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  38. Towards single broadband white emission in Rb0.5K1.5CaPO4(F, Cl): Eu2+ via selective site occupancy engineering for solid-state lighting applications

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  39. Tuning emission color of Eu2+-activated phosphor through phase segregation

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  41. Eu 2+ luminescence in CaYGaO 4 olivine: a new efficient red phosphor for warm illumination

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  42. Mixed Microscopic Eu 2+ Occupancies in the Next‐Generation Red LED Phosphor Sr[Li 2 Al 2 O 2 N 2 ]:Eu 2+ (SALON:Eu 2+ )

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  43. Site‐Engineering for Controlling Multiple‐Excitation and Emission in Eu2+‐Activated CaSrSiO4 Phosphors in Marine Fisheries

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  44. From Framework to Layers Driven by Pressure – The Monophyllo‐Oxonitridophosphate β‐MgSrP3N5O2 and Comparison to its α‐Polymorph

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  45. A First-Principles Explanation of the Luminescent Line Shape of SrLiAl 3 N 4 :Eu 2+ Phosphor for Light-Emitting Diode Applications

    Chemistry of Materials · 2023-07-06

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  46. Narrow-Band Deep-Blue Emission and Superior Thermal Stability of Fluoroaluminate Phosphor Based on Tungsten Bronze-Type Mineral Structure

    Materials · 2023-07-17

    Rui Lu, Jianfeng Sun

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  47. Luminescence Properties of Rare Earth (Eu3+ and Sm3+)-Doped Double Perovskite Sr2YNbO6 Phosphors

    Journal of Electronic Materials · 2023-07-30

    Youzhen Shi, Ruirui Cui, Xinyue Liu, Pengfei Yu, Jun Zhang, Chaoyong Deng

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  48. Photoluminescence of Mn2+ in the Borosulfate Zn[B2(SO4)4] : Mn2+—A Tool to Detect Weak Coordination Behavior of Ligands

    Angewandte Chemie International Edition · 2023-08-07

    Lukas Maximilian Träger, Leonard C. Pasqualini, Hubert Huppertz, Jörn Bruns, Markus Suta

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  49. Photolumineszenz von Mn2+ in dem Borosulfat Zn[B2(SO4)4] : Mn2+ – Eine Möglichkeit zum Nachweis schwach koordinierender Liganden

    Angewandte Chemie · 2023-08-07

    Lukas Maximilian Träger, Leonard C. Pasqualini, Hubert Huppertz, Jörn Bruns, Markus Suta

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  50. Crystal structures and luminescence properties of Li6 MN4:Ce3+ (M = Mo, W)

    Zeitschrift für Naturforschung B · 2023-09-21

    Martin Klotz, Markus Seibald, Dominik Baumann, Klaus Wurst, Günter Heymann, Hubert Huppertz

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