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RESEARCH PAPER · Inorganic Chemistry · 2019

Tuning of the Compositions and Multiple Activator Sites toward Single-Phased White Emission in (Ca 9– x Sr x )MgK(PO 4 ) 7 :Eu 2+ Phosphors for Solid-State Lighting

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Tuning of the Compositions and Multiple Activator Sites toward Single-Phased White Emission in (Ca 9– x Sr x )MgK(PO 4 ) 7 :Eu 2+ Phosphors for Solid-State LightingOriginal(INVITED) A review on the Eu2+ doped β-Ca3(PO4)2-type phosphors and the sites occupancy for photoluminescence tuning17An insight into the preferential substitution and structure repair in Eu 2+ -doped whitlockite-type phosphors based on the combined experimental and theoretical calculations21Crystal structure and photoluminescence tuning of novel single-phase Ca 8 ZnLu(PO 4 ) 7 :Eu 2+ ,Mn 2+ phosphors for near-UV converted white light-emitting diodes61Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes71Lithium ion doping triggered splendid quantum efficiency and thermal stability in Li 2 SrSiO 4 : x Eu 2+ phosphors for optical thermometry and high luminous efficiency white-LED31Mixing the valence control of Eu 2+ /Eu 3+ and energy transfer construction of Eu 2+ /Mn 2+ in the solid solution (1 − x )Ca 3 (PO 4 ) 2 – x Ca 9 Y(PO 4 ) 7 for multichannel photoluminescence tuning34Non-concentration quenching, good thermal stability and high quantum efficiency of K 5 Y(P 2 O 7 ) 2 :Eu 3+ /Tb 3+ phosphors with a novel two-dimensional layer structure78Tunable multicolor luminescent properties of Ca8ZnLa(PO4)7:Ce3+, Mn2+ phosphor via efficient energy transfer37Giant Photoluminescence Improvement and Controllable Emission Adjustment in Bi3+-Activated Ca4ZrGe3O12 Phosphors for High-Quality White Light-Emitting Diodes42Color tunability and energy transfer studies of a new Eu3+ doped langbeinite-type phosphate phosphor for lighting applications23Sm3+-activated Y2Mo4O15 red-emitting microparticles with admirable luminescent performance for indoor illumination25Electronic structure, energy transfer mechanism and thermal quenching behavior of K3YB6O12:Dy3+, Eu3+ phosphor39Ultra-broadband cyan-to-orange emitting Ba 1+x Sr 1−x Ga 4 O 8 :Bi 3+ phosphors: luminescence control and optical temperature sensing95A new eulytite-type Pb3Bi(PO4)3:Eu3+ red-emitting phosphor: Synthesis, structure and photoluminescence characteristics38A single-phase full-visible-spectrum phosphor for white light-emitting diodes with ultra-high color rendering18Luminescence properties and energy transfer of novel Bi 3+ and Mn 2+ -co-activated Y 3 Ga 5 O 12 single-component white light-emitting phosphor54Multiple Substitution Strategies toward Tunable Luminescence in Lu2MgAl4SiO12:Eu2+ Phosphors90Crystal structure and photoluminescence properties of blue-green-emitting Ca1−xSrxZr4(PO4)6: Eu2+ (0≤x≤1) phosphors15Discovery of blue-emitting Eu2+-activated sodium aluminate phosphor with high thermal stability via phase segregation40A novel multi-center activated single-component white light-emitting phosphor for deep UV chip-based high color-rendering WLEDs190Spectroscopic investigation of La7Ta3W4O30:Sm3+ orange-red phosphor for white LEDs38Highly Efficient Cyan-Green Emission in Self-Activated Rb3RV2O8 (R = Y, Lu) Vanadate Phosphors for Full-Spectrum White Light-Emitting Diodes (LEDs)87Site-selective occupation of Eu2+ activators toward full-visible-spectrum emission in well-designed borophosphate phosphors96Red shift properties, crystal field theory and nephelauxetic effect on Mn4+-doped SrMgAl10-yGayO17 red phosphor for plant growth LED light222Investigations on energy transfer mechanism and tunable luminescent properties of Co-doped Ca9La(PO4)7:Dy3+,Eu3+ phosphors19Bright red-luminescence of Eu3+ion-activated La10W22O81 microphosphors for noncytotoxic latent fingerprint imaging38Recent Advances in Bismuth Ion‐Doped Phosphor Materials: Structure Design, Tunable Photoluminescence Properties, and Application in White LEDs363Enhanced Visible Light-Driven Photocatalytic Activities and Photoluminescence Characteristics of BiOF Nanoparticles Determined via Doping Engineering54Great emission enhancement of high-efficient broadband K3YSi2O7: Eu red phosphor via enhancing crystallinity43Highly efficient Eu3+-activated Ca2Gd8Si6O26 red-emitting phosphors: A bifunctional platform towards white light-emitting diode and ratiometric optical thermometer applications49Enhancement of luminescence and thermal stability in Sr 2.92-x Tm x SiO 5 :Eu 2+ for white LEDs3Facile synthesis and thermoluminescence properties of nano bio-ceramic β-Ca2P2O7:Dy phosphor irradiated with 75 meV C6+ ion beam25Structure evolution and tunable magneto‐optical multifunctional property study of novel Ca 18 K 3 Sc 1‐x Sm x (PO 4 ) 14 phosphors7Complex crystal structure and photoluminescence of Bi 3+ -doped and Bi 3+ /Eu 3+ co-doped Ca 7 Mg 2 Ga 6 O 1819Realizing cool and warm white-LEDs based on color controllable (Sr,Ba) 2 Al 3 O 6 F:Eu 2+ phosphors obtained via a microwave-assisted diffusion method20Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146The Phase Transition and Photoluminescence Properties of (Ca9−x Sr x )Mg1.5(PO4)7:Eu2+ Solid-Solution Phosphors3Crystal structure, dielectric and optical properties of β-Ca3(PO4)2-type phosphates Ca9-Zn La(PO4)7:Ho3+9Preparation and photoluminescence study of Alumin o-boro silicate YAG fluorescent glass for White LED0Near-ultraviolet excited broadband orange-yellow emitting Sr8MgIn(PO4)7:Eu2+ phosphors for WLEDs with high color rendering index10Full-visible-spectrum emission with high color rendering index and low correlated color temperature enabled by a single-phased phosphor of α-Sr2V1.98P0.02O7: 0.5% Eu3+19A broadband emitting Sr8MgGa(PO4)7:Eu2+ phosphor for application in white light-emitting diodes with excellent color rendering index6Lattices selective occupation, optical spectra regulation, and photoluminescence properties of Eu2+ activated Ca9La(PO4)7 phosphor19Design principles for achieving red emission in Eu2+/Eu3+ doped inorganic solids83Enhancement of luminescence in Sr9MgK(PO4)7:Eu2+ phosphor by doping Ce3+ ions for white LEDs8Li + Ion Induced Full Visible Emission in Single Eu 2+ ‐Doped White Emitting Phosphor: Eu 2+ Site Preference Analysis, Luminescence Properties, and WLED Applications93Site occupation engineering of activator in a green phosphor Sr8CaLu(PO4)7: Eu2+ with high quantum yield for solid state lighting23Synthesis, luminescent properties, and thermal stabilities of Gd2(1-x)Eu2x(MoyW1-yO4)3 (0≤x≤0.2, 0≤y≤1) solid solution phosphors7Regulating photoluminescence behavior by neighboring-cation-size in Sr8CaX(PO4)7: Eu2+ (X = Al and Ga) phosphors for high color rendering solid-state lighting source41Tailored Luminescence Output of Bi3+-Doped BaGa2O4 Phosphors with the Assistance of the Introduction of Sr2+ Ions as Secondary Cations23Single-phase white-emitting phosphors Ba3Bi(PO4)3:Dy3+, Eu3+ with tunable correlated color temperature and high thermal stability towards light emitting applications13Effect of [Ln3+–Si4+] (Ln = Y, La, Gd, Lu) Cosubstitution on the Structure and Luminescence Property of Sr9Mg1.5(PO4)7:Eu2+ Phosphor1The role of anionic heterovalent [PO 4 ] 3− → [GeO 4 ] 4− substitution on the luminescence properties of inorganic phosphors with the β-Ca 3 (PO 4 ) 2 -type structure: new data based on accurate crystal structure refinement6Multifunctional Ca9NaZn1-Mg (PO4)7:Eu2+ phosphor for full-spectrum lighting, optical thermometry and pressure sensor applications112A novel single-phased white light emitting phosphor with single Eu2+ doped whitlockite structure24NUV-pumped red-emitting Ca 9 MnK(PO 4 ) 7 phosphor: energy transfer and charge compensation3Presence of the irregular oxidation state of Bi 4+ and single-element white emission in YAl 3 (BO 3 ) 4 :Bi0Synthesis and Comparison of Eu3+ Doped M-Gd2(MoO4)3 and O-Gd2(MoO4)3 Phosphors0Tunable emission of Li 4 SrCaSi 2 O 4− y N 2 y / 3 :Eu 2+ phosphors based on anion substitution induction for WLEDs and optical thermometry12Tuning of the thermal quenching performance of Bi 3+ -doped scheelite Ca(Mo/W)O 4 solid solution phosphors13Anti-Defect engineering toward high luminescent efficiency in whitlockite phosphors53Charge compensating effect of rare earth ions Ln3+ (Ln =Y, La) on the photoluminescence improvement of Sr9MgK(PO4)7:Eu2+ phosphor5Recent development of aluminate materials for solid state lighting37Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors23Ln2Te6O15 (Ln = La, Gd, and Eu) “Anti-Glass” Phase-Assisted Lanthanum-Tellurite Transparent Glass–Ceramics: Eu3+ Emission and Local Site Symmetry Analysis13Triple luminescent center energy transfer enables color tuning in Na3Y(PO4)2:RE3+ (RE = Tb/Eu/Tm) for w-LEDs7Self-Reduction Mechanism and Luminescence Properties of Eu 2+ -Eu 3+ Doped Ca(PO 3 ) 2 Phosphor7Luminescence Enhancement of Red‐Emitting Sr9MnK(PO4)7 Phosphor via Energy Transfer and Charge Compensation3Design of K2SrCa(PO4)2-x(BO3)x:Eu2+ phosphors with full-visible spectrum by crystal structure modification12Synthesis, photoluminescent properties, and an insight into the Judd-Ofelt analysis of the NaPbBi(2-x)(PO4)3: xEu3+ orthophosphate phosphors for light applications42A novel extra-broadband visible-NIR phosphor doped with Ce3+ and Cr3+ towards multifunctional advanced applications20Fluorescence modulation in Pr3+-doped MGd2O4 (M = Sr, Ba) by the site engineering strategy4Preparation and Photoluminescent Properties of Tb3+-Doped Lu2W3O12 and Lu2Mo3O12 Green Phosphors18Investigation of the luminescence properties and energy transfer mechanisms in Gd 3 TaO 7 :Bi 3+ ,Eu 3+ phosphors for their potential application in full-spectrum WLEDs10Non-concentration quenching and energy transfer enhanced green emission in Ca 8 SrGd(PO 4 ) 7 :Eu 2+ ,Tb 3+ for near-UV white LEDs with a high color rendering index20White-emitting orthosilicate phosphor α-Sr 2 SiO 4 :Ce 3+ /Eu 2+ /K + : a bimodal temperature sensor with excellent optical thermometric sensitivity11Highly-efficient cyan-emitting phosphor enabling high-color-quality lighting and transparent anticounterfeiting64Quantum Cutting in KGd(CO3)2:Tb3+ Green Phosphor9A nitriding garnet structure cyan emitting phosphor Ca2(Y, Ce)Hf2(Al, Si)3(O, N)12 with high efficiency and excellent thermal stability10Enhanced Luminescence of Dye-Decorated ZIF-8 Composite Films via Controllable D–A Interactions for White Light Emission18Structural characterization, energy transfer, and Judd–Ofelt analysis of pure and the Eu 3+ ‐doped Ca 2 LiMg 2 V 3 O 12 phosphors14Gold nanoparticles with amyloid-β reduce neurocell cytotoxicity for the treatment and care of Alzheimer’s disease therapy2Structurally stable Mn4+-doped oxide phosphor with improved thermal stability for agricultural lighting22A novel red BaLaInO4: Eu3+ phosphor for WLEDs32Temperature-induced luminescence enhancement and quenching behavior of Eu3+ in Lu2(WO4)3 phosphors16Anomalous 5D0→7F4 Transition of Eu3+‐Doped BaLaGaO4 Phosphors for WLEDs and Plant Growth Applications95Designing of Eu2+-Activated Single-Phase White-Emitting Phosphor Through Modifying Cationic Sites for High Color Rendering Full-Spectrum Illumination0Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Judd-Ofelt analysis of Sm3+ doped Ca2LiMg2V3O12 phosphors: Unveiling luminescent and thermometric properties for multifunctional applications35One stone, two birds: Luminescence properties of Ca8ZnY(PO4)7:Eu2+, Mn2+ and multifunctional applications in WLEDs & optical anti-counterfeiting26Synergetic manipulation of components and multiple activator sites towards full-spectrum lighting in Eu2+-doped whitlockite phosphors for high color-rendering WLED4Ca9–yMgyNaGd0.667(PO4)7:Eu2+: A Single Eu2+-Doped Full-Spectrum White Light Emission Phosphor with High Color Rendering Index20Designing of Eu2+-activated single-phase white-emitting phosphor through modifying cationic sites for high color rendering full-spectrum illumination3KBaScSi3O9:Eu2+ Glass‐Ceramics as Single‐Phase High‐Power White Emitters49Photoluminescent properties and luminescent thermal stabilities of 100 mol% activator Tb2(MoO4)3 green phosphor0Innovations in phosphate phosphors: Bridging structure-property gaps for enhanced luminescence27Optimizing europium-doped eulytite phosphors: Unveiling the effects of concentration and temperature for enhanced LED and optical thermometric applications26Luminescence properties and mechanisms of Ca10(PO4)6F2:Er3+ as a green phosphor for white LEDs7Single‐Grain High‐Efficiency Full‐Visible‐Spectrum White Emitters17Single‐Grain High‐Efficiency Full‐Visible‐Spectrum White Emitters3Toward Recyclable, Luminescent Transparent Wood Film via Synergistic Light Responses of Lignocellulose and Phosphors for Plant Growth Lighting and Optical Thermometer15Luminescent Properties and Luminous Thermal Stability of Adjusting Colorful 100 mol% Activator Tb 2(1− x ) Eu 2 x (MoO 4 ) 3 Phosphors0A Novel Yellow Phosphor(Ba 3 Sc 2 (BO 3 ) 4 : Eu 2+ ) Suitable for Full‐Spectrum Lighting, Featuring Tunable Photoluminescence and Enhanced Luminous Thermal Stability23Mixed‐Phase and Solid‐Solution in Single Particles Yielding Better Phosphors6Color tuning of single-phased Ca9KMg(PO4)7:Sr2+, Eu2+, Mn2+ phosphor based on cation substitution and energy transfer for WLED applications8β-Ca3(PO4)2-type Eu2+-doped Phosphor: Applications in optical thermometry and full-spectrum lighting5Luminescence properties of multi-site Eu2+ emission in Ca9MgNa(PO4)7 phosphors with cation substitution5Adjusted photoluminescence, thermal stability, and application of Tb2(1-)Eu2W3O12 phosphors1Single-phase white-emitting phosphors based on Eu2+-activated apatite-type Ba5(PO4)3Cl induced by (BO3)3− diadochic substitution3A compositional feature-driven prediction model for the emission wavelength of Eu 2+ -doped whitlockite-type phosphors coupled with a material design framework0Optoelectronic and thermoelectric properties of terbium-doped silicon carbide (Tb-SiC): a first-principles study for engineering new PC-LEDs1Self-reduction regulation in europium-doped metaphosphate phosphor1Regulating cyan luminescence in Ca9ZnK(PO4)7: Eu2+ phosphors through Ca/Sr solid solution toward full-spectrum WLEDs0Temperature-sensitive color modulation in Ca7-mSrmMg2(PO4)6: Eu2 + for advanced anti-counterfeiting and WLED applications0Site engineering of single-phase β-Ca3(PO4)2-type phosphors via cation substitution for multifunctional luminescence0

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  2. An insight into the preferential substitution and structure repair in Eu 2+ -doped whitlockite-type phosphors based on the combined experimental and theoretical calculations

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  3. Crystal structure and photoluminescence tuning of novel single-phase Ca 8 ZnLu(PO 4 ) 7 :Eu 2+ ,Mn 2+ phosphors for near-UV converted white light-emitting diodes

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  4. Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes

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  5. Lithium ion doping triggered splendid quantum efficiency and thermal stability in Li 2 SrSiO 4 : x Eu 2+ phosphors for optical thermometry and high luminous efficiency white-LED

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  9. Giant Photoluminescence Improvement and Controllable Emission Adjustment in Bi3+-Activated Ca4ZrGe3O12 Phosphors for High-Quality White Light-Emitting Diodes

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  10. Color tunability and energy transfer studies of a new Eu3+ doped langbeinite-type phosphate phosphor for lighting applications

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  32. Facile synthesis and thermoluminescence properties of nano bio-ceramic β-Ca2P2O7:Dy phosphor irradiated with 75 meV C6+ ion beam

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  33. Structure evolution and tunable magneto‐optical multifunctional property study of novel Ca 18 K 3 Sc 1‐x Sm x (PO 4 ) 14 phosphors

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  39. Preparation and photoluminescence study of Alumin o-boro silicate YAG fluorescent glass for White LED

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  41. Full-visible-spectrum emission with high color rendering index and low correlated color temperature enabled by a single-phased phosphor of α-Sr2V1.98P0.02O7: 0.5% Eu3+

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