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RESEARCH PAPER · Chemical Engineering Journal · 2020

Ternary solid solution phosphors Ca1--Li Al1--Si1++N3-O :Ce3+ with enhanced thermal stability for high-power laser lighting

Shihai You, Shuxing Li, Le Wang, Takashi Takeda, Naoto Hirosaki, Rong‐Jun Xie

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Ternary solid solution phosphors Ca1--Li Al1--Si1++N3-O :Ce3+ with enhanced thermal stability for high-power laser lightingOriginalHigh quantum efficiency Ce:(Lu,Y) 3 (Al,Sc) 2 Al 3 O 12 transparent ceramics with excellent thermal stability for high-power white LEDs/LDs40Highly efficient and thermally robust cyan-green phosphor-in-glass films for high-brightness laser lighting32Thermal stability of nitride phosphors for light-emitting diodes66Ultra-bright green-emitting phosphors with an internal quantum efficiency of over 90% for high-quality WLEDs39High Efficiency Green‐Emitting LuAG:Ce Ceramic Phosphors for Laser Diode Lighting90Broadband emission Gd3Sc2Al3O12:Ce3+ transparent ceramics with a high color rendering index for high-power white LEDs/LDs38Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor21Design of a novel WLED structure based on the non-rare-earth Ca2Y(Nb,Sb)O6:Mn4+ materials37Controllable structural ordering via chemical substitution to the efficient and thermally stable luminescence in NASICON-type phosphor Series: Na1+Hf2−Sc (PO4)3:Eu12Ion-exchanged LTA zeolite derived nepheline phase NaAlSiO4:Eu2+ ceramic phosphor for laser illumination14Enhanced red emission in Li2Mg3TiO6: Mn4+ phosphor via Na+ and Ge4+ doping11Reidinger defects induced thermally stable green emission from Eu2+, Mn2+ co-doped Ba0.75Al11O17.25 transparent ceramics16Designing a Polyphosphate Polymorph of CsMg(PO3)3 as Host Lattice for Preparing Single Mn2+-Oxidation Doped Phosphor in the Open Environment18Emerging near-unity internal quantum efficiency and color purity from red-emitting phosphors for warm white LED with enhanced color rendition33Predicting spinel solid solutions using a random atom substitution method8Pressure-sensitive Ce 3+ photoluminescence in LiCaY 5 (BO 3 ) 6 : high internal quantum yields and energy transfer to Tb 3+13Investigations on photoluminescence properties of rare-earth ion single-doped CaSrSb2O7 phosphors32How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Eu3+ and Mn4+ co-doped BaLaMgNbO6 double perovskite phosphors for WLED application19A novel star-shaped Schiff base compound: Synthesis, properties and application in w-LEDs14Thermally Robust Orange‐Red‐Emitting Color Converters for Laser‐Driven Warm White Light with High Overall Optical Properties91Blue-green emitting LuASG:Ce phosphor ceramics with high luminous efficacy for high-power LEDs20Toward High‐Quality Laser‐Driven Lightings: Chromaticity‐Tunable Phosphor‐in‐Glass Film with “Phosphor Pattern” Design101High-efficiency yellow-emitting La3Si6N11:Ce phosphor-in-glass for laser-driven white lighting21Dual-emitting phosphor-glass composites by the melt-quenching method for high-quality laser lighting12Design of a Novel La3Si6N11:Ce3+ Phosphor-in-Glass Film for High Power Laser Lighting: Luminous Efficiency toward 200 lmW–127Color-tunable blue-emitting Na2MgSiO4:Ce3+ phosphors for white light-emitting diodes33Spectral Tuning, Stabilities under External Exposures, and Spontaneous Enhancement of Emission Intensity in Grown‐into‐Glass All‐Inorganic Metal Halide Perovskite Nanocrystals15Laser Phosphors for Next-Generation Lighting Applications152Novel double perovskite Ca2Gd0.5Nb1-W5/6O6:0.5 Eu3+ red phosphors with excellent thermal stability and high color purity for white LEDs92Powder synthesis and luminescence of a novel yellow-emitting Ba5Si11Al7N25: Eu2+ phosphor discovered by a single-particle-diagnosis approach for warm w-LEDs50Tunable emission and high chromogenic laser lighting of transparent ceramics for high-brightness white LEDs/LDs5Improved optical thermometric sensitivity of Eu 3+ ‐doped calcium niobate phosphor via nonstoichiometric control1Superhigh-luminance amorphous red phosphors for laser illumination and information recognition5Efficient blue-light-excited cyan-emitting CaLu2HfScAl3O12:Ce3+ phosphors for full-visible-spectrum warm-white LEDs13Hetero-valent substitution induced luminescence enhancement of Zn1-Ga2+O4+δ:Cr3+ near infrared phosphors for plant cultivation12The developments of cyan emitting phosphors to fulfill the cyan emission gap of white-LEDs9Crystal Field Engineering Yields New 3D Layered Solid Solution Phosphors (Ca/Sr)4MgAl2Si3O14:Eu2+ for White-Light-Emitting Diode Full-Spectrum Lighting17Efficient thermal and luminescent regulations of LuAG: Ce-PiG based remote LED/LD13Robust high-efficiency LuAG: Ce phosphor-in-silica glass (PiSG) for high-brightness laser lighting20Overcoming the cyan gap for full‐spectrum lighting using cation‐substitution‐induced rigid Ca 2 YZr 2 Al 3 O 12 :Ce 3+9High external quantum yield in near-infrared phosphor Bi2Ga4O9:Cr3+ excited by near-ultraviolet or blue light9Green-emissive Ce 3+ :Lu 3 Al 5 O 12 –Al 2 O 3 nanoceramics elaborated via glass crystallization for high-power laser lighting applications8Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Preparation of (Lu,Y) 3 (Al,Sc,Cr) 2 Al 3 O 12 phosphor ceramics with high thermal stability for near-infrared LED/LD46Defect regulation of a distinctive synthetic Eu2+-doped SiAlON S-phase towards controllable spectra and thermal quenching for white-light-emitting diode17A new yellowish‐green‐emitting phosphor: Eu 2+ ‐doped Ba 3 YAl 2 O 7.55Engineering interstitial Eu2+ in α-quartz creates broadband cyan emission toward full-visible-spectrum white LED lighting2Absolutely Structural Disorder Boosting Bandwidth toward Full‐Spectrum White Light from Single Occupancy of Activator36One-Pot Synthesis of High-Quality CsPbI3 Nanoplatelets with Orange-Red Light Emission3Enhanced Quantum Efficiency via Co‐Substitution in Red‐Emitting Phosphor Sr2[MgAl5N7] : Eu2+ for Advanced Spectroscopic Applications Including Laser Displays with Ultra‐High Luminescence Saturation Threshold11Enhanced Quantum Efficiency via Co‐Substitution in Red‐Emitting Phosphor Sr2[MgAl5N7] : Eu2+ for Advanced Spectroscopic Applications Including Laser Displays with Ultra‐High Luminescence Saturation Threshold10Narrow-band green nitride phosphor for wide color gamut backlighting11Defect Regulation Induced Luminescence Improvement of the Broadband Orange Phosphor Lu2CaMg2Si3O12:Ce3+ for WLED6Broadened and enhanced blue emission of interstitial Eu2+ in α-cristobalite via Al3+ codoping for high color rendering white LEDs2Toward High‐Brightness Laser Lighting: Progress and Perspectives on Phosphor‐in‐Glass Films23Luminescence improvement of Ce3+-doped Lu2CaMg2Si3O12 orange phosphor for WLED based on Ca vacancy3High brightness and light uniformity Tb3Al5O12: Ce3+, Gd3+ phosphors@silica aerogel composites with unique laser scattering performance for laser-driven lighting0Room-temperature fabrication of phosphor-in-geopolymer converter enabling high color quality for laser-driven lighting4CALSON:Ce 3+ Phosphor Ceramics for Laser‐Driven Solid‐State Lighting7Highly thermally stable Ce 3+ /Tb 3+ -activated Ba 2 MgY 2 (BO 3 ) 4 phosphors prepared by a one-step reductive solid-state reaction0荧光转换激光光源封装用荧光玻璃膜研究进展0Advancements in phosphor materials for laser lighting and display: strategies for enhancing luminescence saturation thresholds1Excitation‐Dependent Thermal Behavior of a New Type of Phosphors Ba 1‐x Sr 1+x Y 4 O 8 :Ce 3+0YGa3(BO3)4: Er3+ near-infrared compound with high thermal stability for bioimaging and nondestructive testing0Advanced phosphor converters for laser-driven light sources: a review0Revealing Anti‐Thermal Quenching Broadband Cyan‐Green Emission in Oxonitridoaluminosilicate Phosphors Induced by Anion Ordering Substitution0

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  2. Highly efficient and thermally robust cyan-green phosphor-in-glass films for high-brightness laser lighting

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  3. Thermal stability of nitride phosphors for light-emitting diodes

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  4. Ultra-bright green-emitting phosphors with an internal quantum efficiency of over 90% for high-quality WLEDs

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  5. High Efficiency Green‐Emitting LuAG:Ce Ceramic Phosphors for Laser Diode Lighting

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  6. Broadband emission Gd3Sc2Al3O12:Ce3+ transparent ceramics with a high color rendering index for high-power white LEDs/LDs

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  7. Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor

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  8. Design of a novel WLED structure based on the non-rare-earth Ca2Y(Nb,Sb)O6:Mn4+ materials

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  9. Controllable structural ordering via chemical substitution to the efficient and thermally stable luminescence in NASICON-type phosphor Series: Na1+Hf2−Sc (PO4)3:Eu

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  10. Ion-exchanged LTA zeolite derived nepheline phase NaAlSiO4:Eu2+ ceramic phosphor for laser illumination

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  14. Emerging near-unity internal quantum efficiency and color purity from red-emitting phosphors for warm white LED with enhanced color rendition

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  15. Predicting spinel solid solutions using a random atom substitution method

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  17. Investigations on photoluminescence properties of rare-earth ion single-doped CaSrSb2O7 phosphors

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  18. How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications

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  19. Eu3+ and Mn4+ co-doped BaLaMgNbO6 double perovskite phosphors for WLED application

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  20. A novel star-shaped Schiff base compound: Synthesis, properties and application in w-LEDs

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  22. Blue-green emitting LuASG:Ce phosphor ceramics with high luminous efficacy for high-power LEDs

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  48. Engineering interstitial Eu2+ in α-quartz creates broadband cyan emission toward full-visible-spectrum white LED lighting

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  49. Absolutely Structural Disorder Boosting Bandwidth toward Full‐Spectrum White Light from Single Occupancy of Activator

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