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RESEARCH PAPER · Chemical Engineering Journal · 2020

Zero-thermal-quenching of Mn4+ far-red-emitting in LaAlO3 perovskite phosphor via energy compensation of electrons’ traps

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Zero-thermal-quenching of Mn4+ far-red-emitting in LaAlO3 perovskite phosphor via energy compensation of electrons’ trapsOriginalA novel efficient single-phase dual-emission phosphor with high resemblance to the photosynthetic spectrum of chlorophyll A and B61Effect of SiO2 introduction on luminescence properties of LuAG:Mn2+ phosphors16The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs14Structural and optical characteristics of novel rare‐earth‐free red-emitting BaSn(PO4)2:Mn4+ phosphor35Tunable‐spectrum Mn 2+ doped garnet transparent ceramics for high‐color rendering laser lighting8A zero-thermal-quenching perovskite-like phosphor with an ultra-narrow-band blue-emission for wide color gamut backlight display applications67Evolution of a Snowflake-Like Mn 2+ Doped Cs 2NaBiCl 6 Nanosheet Phosphor Driven By Cation Exchange0Formation and enhancement of negative thermal quenching in emission of KGdF 4 :Eu 3+ , Yb 3+ @GQDs3Magical polyhedral twist via chemical unit co-substitution in LaAlO 3 :Mn 4+ to greatly enhance the zero phonon line for high-efficiency plant-growth LEDs49Research on the quantum confinement effect and enhanced luminescence of red-emitting P 5+ -doped CaAl 12 O 19 :Mn 4+ ,Mg 2+ phosphors17Thermal stability of nitride phosphors for light-emitting diodes66Very stable and high-quantum-yield phosphor Na 2 BaSr(PO 4 ) 2 :Eu 2+ for plant growth LEDs42Enhanced local symmetry achieved zero-thermal-quenching luminescence characteristic in the Ca2InSbO6:Sm3+ phosphors for w-LEDs227Synthesis red-emitting Ca2LaNbO6:xSm3+ phosphors for good color-rendering-index white-LED devices19Flux-assisted low-temperature synthesis of Mn4+-doped unusual broadband deep-red phosphors toward warm w-LEDs39Conversion of thermal energy to light energy and energy transfer in KGdF4: Eu3+,Tb3+ phosphors10Broadband near-infrared emission of K3ScF6:Cr3+ phosphors for night vision imaging system sources189Equivalent cation substitution-triggered highly efficient Mn4+ red emission in double-perovskite type (Ba, Sr)2(Gd, La, Y, Lu)(Nb, Sb)O6:Mn4+ solid solution phosphors and photophysical studies62Local structure and luminescent properties of Cs2KGaF6:Mn4+ phosphor for backlight white LEDs32Sr3LiTaO6:xMn4+ red-emitting phosphors for indoor plant growth lighting: High thermal stability and quantum efficiency30Abnormal thermal quenching behavior and optical properties of a novel apatite-type NaCa3Bi(PO4)3F:Sm3+ orange-red-emitting phosphor for w-LED applications59Excitation selective thermal characteristics of Mg28Ge7.55−xGaxO32F15.04: Mn4+ and application in single/dual-mode optical thermometry15Green synthesis, luminescent properties and application for WLED of flower-like K2LiAlF6:Mn4+ phosphor25Improved Photoluminescence Properties of Bi 3+ , Mn 4+ -Codoped Orthorhombic LaGaO 3 Perovskite Phosphor1Enhanced red emission in Li2Mg3TiO6: Mn4+ phosphor via Na+ and Ge4+ doping11High luminescent thermal stability and water resistance of K2SiF6:Mn4+@CaF2 red emitting phosphor41Achieving highly efficient far-red emission from luminescence-ignorable Ca2MgTeO6:Mn4+ to Ca2-Ln MgTe1-W O6:Mn4+ (Ln = La, Y, Gd) phosphors via solid solution and impurity doping strategies13Improved thermal stability of the near‐infrared Al‐modulated Zn 3 Ga 2 GeO 8 : Cr 3+ phosphors for plant growth applications36Negative thermal quenching of K3AlF6:Mn4+@GQDs phosphors caused by enhancement of the conversion of heat energy into light energy2Enhanced luminescence properties of Li2MgTiO4: Mn4+, Ge4+ phosphor via single cation substitution for indoor plant cultivation31Achievement of high-efficiency sunlight-like emission in Rb2CaP2O7: Ce3+, Eu2+ phosphors16Bright luminescence of Sb doping in all-inorganic zinc halide perovskite variant24Achieving zero-thermal quenching luminescence in ZnGa2O4: 0.02Eu3+ red phosphor47Enhancement of the luminescent thermal stability and water resistance of K2SiF6:Mn4+,Na+ by double coating of GQDs and K2SiF626Enhanced luminescence performances of BaLaMgTaO6:Mn4+ red phosphor by Bi3+, Ca2+ doping for indoor plant lighting supplementary LED23A facile surface passivation strategy for Na2SiF6:Mn4+,Li+ phosphors to achieve high moisture resistance and luminescent thermal stability16Enhancement of Eu2+ photoluminescence behavior in NaBaB9O15 based on the K+ doping13Realization of an Optical Thermometer via Structural Confinement and Energy Transfer39Doping Pb 2+ in LaAlO 3 to generate dual emission centers and an optical storage container for visible and near infrared persistent luminescence8Variation from Zero to Negative Thermal Quenching of Phosphor with Assistance of Defect States45Anti-thermal-quenching, color-tunable and ultra-narrow-band cyan green-emitting phosphor for w-LEDs with enhanced color rendering85A crystal defect led zero thermal quenching β-NaYF 4 : Eu 3+ ,Dy 3+ red emitting phosphor14A New Type of Zero Thermal Quenching Red Emitting Phosphor Β-Nayf4:Eu3+ for Nuv Leds5A novel red-emitting phosphor with an unusual concentration quenching effect for near-UV-based WLEDs40A single-component white-light-emitting fluorescent material with high color rendering index based on resonance energy transfer11An organic–inorganic hybrid K 2 TiF 6 : Mn 4+ red-emitting phosphor with remarkable improvement of emission and luminescent thermal stability21Deep-Red Emission in Mn4+ Activated Camgal10o17phosphor and Enhanced Optical Photoluminescence by Charge Compensator of Mg2+13High Water Resistance and Luminescent Thermal Stability of Organic-Inorganic Hybrid K2sif6:Mn4+ Red Emitting Phosphor Induced by Mof0Mn4+ Doped Mg2scsbo6 Deep-Red-Emitting Double-Perovskite Phosphors for Plant-Cultivation27Na0.2La0.2Sr1.6WO6:Mn4+: An efficient far-red-emitting phosphor via a cation-pair partial substitution16Post-doping induced morphology evolution boosts Mn 2+ luminescence in the Cs 2 NaBiCl 6 :Mn 2+ phosphor19Sol-Gel Preparation and Energy Transfer Properties of Gd2sral2o7:Bi3+, Mn4+ Phosphor for Indoor Plant Growth Led Lighting0Synthesis and optical properties of Gd 4 Al 2 O 9 :Eu 3+ , a red emitting phosphor with a strong negative thermal quenching effect8X-ray triggered pea-shaped LuAG:Mn/Ca nano-scintillators and their applications for photodynamic therapy7How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Light keys open locks of plant photoresponses: A review of phosphors for plant cultivation LEDs75Simultaneous Spectral Tuning and Thermal Stability Adjustment in Ca8ZnGa(1–x)Lax(PO4)7:Eu2+ Phosphors23Improvement of the luminescent thermal stability and water resistance of K2SiF6:Mn4+ by surface passivation45A novel Cr3+-activated far-red titanate phosphor: synthesis, luminescence enhancement and application prospect59Broadband near-infrared emitting Sr3Sc4O9: Cr3+ phosphors: Luminescence properties and application in light-emitting diodes46Metal To Metal Charge Transfer Induced Efficient Yellow/Far‐Red Luminescence in Na2Ca3(Nb, Ta)2O9:Bi3+ toward the Applications of White‐LEDs and Plant Growth Light48High Water Resistance and Luminescent Thermal Stability of LiyNa(2–y)SiF6: Mn4+ Red-Emitting Phosphor Induced by Codoping of Li+19Enhancement of the luminescent thermal stability and water resistance of K2TiF6:Mn4+ by organic inorganic hybrid matrix and surface passivation21Synthesis, crystal structure, and anti‐thermal quenching performance of Lu 2 Sr (1− x ) Al 4 SiO 12 : x Eu 2+ phosphors9Greatly enhanced deep-red luminescence performance of Ca2InSbO6:Mn4+ phosphor via multiple optimization strategies34Polyhedron engineering by chemical unit co-substitution in LaAlO3:0.02Pb2+ to generate multimode and condition-sensitive luminescence for dynamic anticounterfeiting34The optical properties of Mn4+ ions in Ba2CaWO6 with double perovskite structure for optical thermometer application13Double coating strategy simultaneously enhances emission, fluorescent thermal stability and water resistance of K2SiF6:Mn4+ phosphor4A novel Cr3+-doped stannate far red phosphor for plant lighting: structure evolution, broad-narrow spectrum tuning and application prospect39Review—Temperature Dependence of Transition-Metal and Rare-Earth Ion Luminescence (Mn 4+ , Cr 3+ , Mn 2+ , Eu 2+ , Eu 3+ , Tb 3+ , etc.) II: Experimental Data Analyses20Energy transfer properties of CaYAlO4:Bi3+, Mn4+ phosphor for indoor crop cultivation LED lighting10Highly Stable Orange‐Red Long‐Persistent Luminescent CsCdCl3:Mn2+ Perovskite Crystal110Highly Stable Orange‐Red Long‐Persistent Luminescent CsCdCl3:Mn2+ Perovskite Crystal8Achieving the ultra-broadband near-infrared La3SnGa5O14:Cr3+ phosphor via multiple lattice sites occupation for biological nondestructive detection and night-vision technology45Novel double molybdate LiLu(MoO4)2:Sm3+ red phosphors with excellent thermal stability for white LEDs31A novel far-red phosphors Li2ZnTi3O8:Cr3+ for indoor plant cultivation:Synthesis and luminescence properties55Cationic pair substitution in LaAlO 3 :Mn 4+ for octahedral-tilting-dependent zero-phonon line15Performance improvement of Sr4Al14O25:Mn4+ red emission phosphor via Na+ doping14Highly Luminescent Earth‐Benign Organometallic Manganese Halide Crystals with Ultrahigh Thermal Stability of Emission from 4 to 623 K26Mn4+ activated dodec-fluoride red phosphor Na3Li3In2F12:Mn4+ with excellent waterproof stability for WLEDs38Crystal defect induced zero thermal quenching β-NaYF 4 : Eu 3+ , Sm 3+ red-emitting phosphor10On The Validity of the Defect- Induced Negative Thermal Quenching of Eu2+-Doped Phosphors7Electronic Defect Engineering of Double-Doped Β-Kyf4:Eu3+,Bi3+ Red Phosphors: Negative Thermal Quenching and Applications for High-Efficiency White Light-Emitting Diodes0Facile synthesis, aggregation-induced emission, mechano- and thermochromism of o -carborane–tetraphenylethene dyads with a short CH(OH) linker10Light storage perovskites: Synthesis, mechanisms, and applications2Regulating anti-thermal quenching to zero thermal quenching for highly efficient blue-emitting Eu 2+ -doped K-beta-alumina phosphors21Theoretical calculations and photoluminescence properties of Sr 4 Al 14 O 25 :Mn 4+ red phosphors doped with Li +5Intrinsic imperfect and zero thermal quenching property for a novel β-NaYF4:Eu3+,Tb3+ red-light emitting phosphor for NUV LEDs8La-Doped Alumina, Lanthanum Aluminate, Lanthanum Hexaaluminate, and Related Compounds: A Review Covering Synthesis, Structure, and Practical Importance26Synthesis, luminescence properties and potential applications for plant growth: A novel Mn4+-activated SrLa2Al2O7 phosphor with far-red emission39A novel Tb3+ and Eu3+ co-doped dual-emitting phosphate K3SrBi(P2O7)2 phosphor for application in FIR thermometers65Enhancing quantum efficiency and thermal stability in Gd2SrAl2O7: Mn4+, Bi3+, Na+ far-red emitting phosphor by energy transfer and cation substitution strategy for indoor plant growth LED lighting22High-temperature solid-phase synthesis of eulyite-type Ba3Yb(PO4)3 as a single host for narrow-band Tb3+ green emission2A novel Mn 4+ ‐activated far‐red Sr 2 MgWO 6 phosphor: synthesis, luminescence enhancement, and application prospect13Broadband near-infrared emitting Cr3+-activated InGaO3(ZnO)4 phosphor and its application in pc-LEDs10Luminescence enhancement of Mn 4+ ‐activated double‐perovskite phosphors for LEDs through a co‐replacement strategy19A novel reddish-orange-emitting phosphor Ca3Gd7(PO4)(SiO4)5O2: Sm3+ for white light-emitting diodes13Spectral Broadening in Cr3+-Doped Sr0.92Mg0.91Al10.1O17 NIR Phosphor Realized by Multi-crystallographic Site Occupation12Design and fabrication of a bimodal emitting phosphor by co-doping two different activators for high sensitivity temperature sensing12Ca2+ enhanced far-red emission performance and efficiency of SrGd2Al2O7:Mn4+ phosphor for the potential application in plant growth lighting6Broadband Short-Wave Infrared-Emitting MgGa2O4:Cr3+, Ni2+ Phosphor with Near-Unity Internal Quantum Efficiency and High Thermal Stability for Light-Emitting Diode Applications115Luminescence properties and optical sensing behaviors of Sr2GdSbO6:Eu3+ phosphors57Cr3+-free broadband near-infrared phosphors NaAl5O8:Fe3+42Bi3+ sensitizer induced efficient deep-red luminescence in Mn4+-doped 4SrO‧7Al2O3 toward the applications of plant growth lamp5High-Efficiency Ce3+ Activated Orthorhombic Lanthanide Silicate Blue Phosphors for Plant Growth Lighting25Be 2+ ‐Induced Red Emission Enhancement in CaAl 12 O 19 :Mn 4+ for Wide Color Gamut Display: Suppressing Self‐Reduction of Mn 4+ to Mn 2+26Y2MAl4SiO12:Cr3+ (M=Mg, Ca, Sr, Ba) near-infrared phosphors via chemical unit co-substitution strategy for plant growth13Synthesis, luminescence properties, and thermal decomposition kinetics of NH4GdF4:Eu3+ with an intense negative thermal quenching effect6Giant enhancement of photoluminescence in Mn4+-activated Ba2CaWO6 phosphors via heterovalent doping with rare-earth ions28CaLaLiTeO6: Mn4+, Tm3+ phosphors with multiband near-infrared emission towards multifunctional applications11Crystal structure and luminescence properties of a novel near-infrared phosphor LiAlO2:Fe3+28A broadband near-infrared emission Na 3 Al 2 (PO 4 ) 2 F 3 :Cr 3+ phosphor exhibiting zero photoluminescence quenching at 398 K17Achieving high brightness and thermally stable far-red luminescence via ultrathin phosphor–glass composite engineering3High Quantum Efficiency Cs2sif6:Mn4+ Red Phosphors Prepared for Warm White Led Via Ion Exchange Method0Hydrothermal synthesis of ZnGa 2 O 4 nanophosphors with high internal quantum efficiency for near-infrared pc-LEDs13Multicolor Luminescence And Energy Transfer Of Ksrgd(Po 4 ) 2:Ln 3+ (Ln = CE, Sm, EU, Tb, Dy, Dy/Eu, Yb/Ho, Yb/Er, Yb/Tm) Phosphors for Wled And Multiple Anti-Counterfeiting0Photoluminescence Properties and Mn4+ → Tm3+ Energy Transfer of La0.557li0.33tio3: Mn4+, Tm3+ for Thermometry and Nir-Led Applications0Photoluminescence Properties and Mn4+ → Tm3+ Energy Transfer of La0.557li0.33tio3: Mn4+, Tm3+ for Thermometry and Nir-Led Applications0Thermal stability enhancement of an Mn 4+ -activated germanate phosphor by a cationic non-equivalent substitution strategy13Zero-thermal quenching luminescence and sensitization effect of Eu3+ in Ca3LiSbO6:Mn4+ red phosphor9Optical properties of Sr2LuNbO6:Mn4+ deep-red phosphor: crystal-field splitting and multimode vibrational coupling21Stabilization of Ti3+ in CaTiO3 by doping Y3+ to generate visible light-activated near-infrared persistent luminescence12Designing high thermally stable deep red phosphors based on low thermal expansion coefficients for optical applications16Trivalent chromium ion doping garnet phosphor with broadband near-infrared emission for night-vision applications7Dual substitution of host lattice ions to enhance the luminescence properties of Zn2TiO4:Cr3+ phosphor3Design of Eu3+-Doped Fluoride Phosphor with Zero Thermal Quenching Property Based on Density Functional Theory5Designing high-efficiency red-emitting Mg2In1-zSczSbO6:Mn4+,Li+ phosphors for plant growth lighting17Anti-counterfeiting applications of antimony-doped zero-dimensional indium halide with temperature-responsive broad emission23Harnessing the brilliance of Cr3+ doped LaAlO3–Al2O3 phosphors with exceptional responsiveness to far-red phytochrome for plant growth LEDs31A far-red-emitting LiGaTiO4:Cr3+ phosphor for potential application in plant growth LEDs18A green-light-driven Mn4+ doped aluminate for agricultural cultivation with high resemblance to the phytochrome spectrum9Awakening dumb Mn2+ mechanoluminescence site to achieve force, temperature and time-domain induced color tuning via trap-assisted energy transfer14Striking antithermal quenching and waterproofness of Mn4+-doped fluoride phosphors induced by synergy of double coating and single passivation8Effective red emission of Sb3+ sensitized Ho3+ doped Cs2NaGdCl6 perovskite under blue excitation14Multicolor luminescence and energy transfer of KSrGd(PO4)2:Ln3+ (Ln = Ce, Sm, Eu, Tb, Dy, Dy/Eu, Yb/Ho, Yb/Er, Yb/Tm) phosphors for WLED and multiple anti-counterfeiting7Highly effective red phosphor for warm white LEDs without rare earth elements7Theoretical calculation and luminescence property of Gd-doped Y3Ga5O12:Cr3+ NIR phosphors for plant growth13Electronic defect engineering of double-doped β-KYF4:Eu3+,Bi3+ red phosphors: Negative thermal quenching and applications for high-efficiency white light-emitting diodes5Manipulating energy transfer to achieve zero-thermal quenching luminescence in a white-emitting borotellurate phosphor9Fine‐Tuning of Near‐Infrared Emission in Fe‐Activated Spinel Phosphors via the Synergistic Effect of Sites Inversion and Atomic Disorder49Photoluminescence properties and Mn4+ → Tm3+ energy transfer of La0.557Li0.33TiO3: Mn4+, Tm3+ for thermometry and NIR-LED applications7Synergistic enhancement of Eu3+-doped LaAlO3 fluorescent materials by sol-gel process and aerogel structure for high power and precise transmission illumination3Achieving Thermally Stable YAl3–xGax(BO3)4:Cr3+ Near-Infrared Emitting Phosphors via Chemical Substitution for Plant Growth LEDs23Spectroscopic analysis of Mn4+-activated phosphors: Unveiling the relationship between energy levels and Racah parameters6A novel palmierite-type Sr9La(VO4)7: xEu3+ phosphors with superior quantum efficiency via defect engineering11Development of High‐Efficiency BaSrCaWO6:Mn4+ Red‐Emitting Phosphors via La3+ Addition Strategy2Realizing Antithermal Quenching Red Emission in Mn4+‐Activated Rb2NaVF6 for Optical Thermometry Sensor Application0Thermoluminescence glow curve study of UV-irradiated Mn4+doped zinc aluminate spinel nanophosphor9A deep-red emitting garnet-like Li6SrLa2Ta2O12:Mn4+ phosphor used for plant growth lighting14Room temperature synthesis of graphene quantum dots coated KGdF4: Eu3+, Sm3+ nanophosphors with negative luminescence thermal bursts4

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