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RESEARCH PAPER · Chemistry of Materials · 2020

Predicting Thermal Quenching in Inorganic Phosphors

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Predicting Thermal Quenching in Inorganic PhosphorsOriginalZero-thermal-quenching and improved chemical stability of a UCr4C4-type phosphor via crystal site engineering42Halide Perovskite Nanocrystal Emitters27The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs14A data-driven approach to predicting band gap, excitation, and emission energies for Eu 2+ -activated phosphors28High partial thermal conductivity of luminescence sites: a crucial factor for reducing the heat-induced lowering of the luminescence efficiency8Spontaneous-reduction and photoluminescence tuning in singly-doped Ba5-Ca (PO4)3Cl:Eu2+/Eu3+ phosphors23Characterization of Ce:CSSO, Pr:CSSO, and co-doped Ce,Pr:CSSO phosphors for aerosol phosphor thermometry8Ternary sulfides ALnS2:Eu2+ (A = Alkaline Metal, Ln = rare-earth element) for lighting: Correlation between the host structure and Eu2+ emission maxima18Designing a Thermally Robust Green-Emitting Phosphor Rb2HfSi2O7: Eu2+ by an Atomic Chain Vibration Model and Its White Light-Emitting Diode Application16Manipulating heat transport of photoluminescent composites in LEDs/LDs25An Integrated Luminescent Information Encryption–Decryption and Anticounterfeiting Chip Based on Laser Induced Graphene39Reidinger defects induced thermally stable green emission from Eu2+, Mn2+ co-doped Ba0.75Al11O17.25 transparent ceramics16Suppression of Eu2+ Luminescence Loss14Missing Member in the MIIMIIISi4N7 Compound Class: Carbothermal Reduction and Nitridation Synthesis Reveal Substitution of Nitrogen by Carbon and Oxygen in CaLu[Si4N7–2xCxOx]:Eu2+/Ce3+ (x≈0.3)2High thermal stability of green-emitting phosphor NaBaB9O15: Tb3+ via energy compensation31Anti-thermal-quenching, color-tunable and ultra-narrow-band cyan green-emitting phosphor for w-LEDs with enhanced color rendering85Correlated Na+ Ion Migration Invokes Zero Thermal Quenching in a Sodium Superionic Conductor-type Phosphor24Efficient and thermally stable broadband near-infrared emission from near zero thermal expansion AlP 3 O 9 :Cr 3+ phosphors67Energy levels of Eu 2+ states in the next-generation LED-phosphor SrLi 2 Al 2 O 2 N 2 :Eu 2+32Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba 1− x Sr x ScO 2 F:Eu 2+12The explanation of abnormal thermal quenching of the charge transfer band based on thermally coupled levels and applications as temperature sensing probes21Thermally Robust Broadband Near-Infrared Luminescence in the Nagap2o7:Cr3+ Phosphor2How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252MxLa1–xSiO2–yNz (M = Ca/Sr/Ba): Elucidating and Tuning the Structure and Eu2+ Local Environments to Develop Full-Visible Spectrum Phosphors32Superb thermal stability purple-blue phosphor through synergistic effect of emission compensation and nonradiative transition restriction of Eu2+31Synthesis and Luminescence Properties of Amber Emitting La7Sr[Si10N19O3] : Eu2+ and Syntheses of the Substitutional Variants RE8‐xAEx[Si10N20‐xO2+x] : Eu2+ with RE=La, Ce; AE=Ca, Sr, Ba; 0≤x≤28Electronic and Optical Properties of Eu2+-Activated Narrow-Band Phosphors for Phosphor-Converted Light-Emitting Diode Applications: Insights from a Theoretical Spectroscopy Perspective70Efficient near-infrared phosphors discovered by parametrizing the Eu(II) 5d-to-4f energy gap92Enhanced thermostability of Eu3+ ions photoluminescence by multi-level electron traps with various temperature responses4Challenges and Strategies to Design Phosphors for Future White Light Emitting Diodes104Thermal Quenching Mechanism of Metal–Metal Charge Transfer State Transition Luminescence Based on Double-Band-Gap Modulation24Broadband near-infrared luminescence in the NaAlP2O7:Cr3+ phosphor for spectroscopy applications19Thermally Robust Broadband Near-Infrared Luminescence in the NaGaP2O7:Cr3+ Phosphor23Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+77From lab to lamp: Understanding downconverter degradation in LED packages7Laser Phosphors for Next-Generation Lighting Applications152Efficient and Thermally Robust Broadband Near‐Infrared Emission in a Garnet Ca 3 MgHfGe 3 O 12 :Cr 3+ Phosphor48Highly Luminescent Earth‐Benign Organometallic Manganese Halide Crystals with Ultrahigh Thermal Stability of Emission from 4 to 623 K26Tuning the thermal quenching properties of Ga3+-modified LiTaO3:Bi3+ phosphor through defect engineering strategy12Na1.5Y2.5F9: Ce3+, Tb3+, Eu3+ glass-ceramics for white light9Highly Stable Zero-Dimensional Lead-Free Metal Halides for X-ray Imaging106On The Validity of the Defect- Induced Negative Thermal Quenching of Eu2+-Doped Phosphors7An efficient and thermally stable near-infrared phosphor derived from the Ln 3 ScInGa 3 O 12 :Cr 3+ (Ln = La, Gd, Y, and Lu) garnet family18Dopant-induced changes of local structures for adjusting the hydration ability of proton-conducting lanthanum scandates8Preparation and photoluminescence properties of Eu3+ doped Li2O–Al2O3–B2O3 glass-ceramics11α-Ba2ScAlO5: Eu3+ as a promising thermally stable orange-red emission phosphor10Dual-emitting temperature dependent material based on Bi3+/Eu3+ co-activated Ba2Y2Si4O13 phosphor with multicolor anti-counterfeiting22Thermal enhancement of upconversion luminescence in Sc2Mo3O12: Nd/Yb/Er crystals for optical temperature sensing56Observation of tunable persistent luminescence in XAl2O4: Eu2+ (X=Ca, Sr) doped borate glass for efficient optical information storage17Manipulation of Temperature-Dependent Luminescence Behaviors of Mn4+-Activated Fluoride Phosphors17In-plane Heat Transfer Enhancement of Phosphor Layer in Transmissive Laser-excited White Lighting0A guide to comprehensive phosphor discovery for solid-state lighting245The developments of cyan emitting phosphors to fulfill the cyan emission gap of white-LEDs9Cr 3+ ↔Fe 3+ Energy Transfer Offset Enabling Anti‐Thermal Quenching Near‐Infrared Emission for Coded Wireless‐Communication Applications43A novel reddish‐orange emitting NaSrBiTeO 6 :Sm 3+ phosphor with high moisture resistance and thermostability for horticultural light emitting diode applications17A broadband near-infrared emission Na 3 Al 2 (PO 4 ) 2 F 3 :Cr 3+ phosphor exhibiting zero photoluminescence quenching at 398 K17Highly efficient and thermally stable broadband green-emitting BaY 2 Sc 2 Al 2 SiO 12 :Ce 3+ phosphors enabling warm-white LEDs with high luminous efficacy and high color rendering index44Luminescence center modulation for the synthesis of a narrow-band green phosphor: mechanism and backlighting display application4Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Recent progress on modulating luminescence thermal quenching properties of Bi 3+ -activated phosphors77Regulating luminescence thermal quenching based on the synergistic effect of energy transfer and energy gap modulation3Structure and luminescence characteristics of self-activated vanadate garnet phosphors16Blue-emitting Bi3+-doped K2MGeO5 (M = Hf, Zr) phosphors for full-spectrum WLED: Crystal structure, electronic structure and luminescent properties12Structural and optical properties of Cd2MgTeO6:Dy3+, Na+ phosphors for potential application in w-LEDs and personal identification22Dy3+/Tm3+ activated single-phase tungstate phosphors with anti-thermal quenching and tunable luminescence properties for white LEDs applications41Bidirectional energy transfer in yellow-emitting Gd2WTiO8:Er3+,Sm3+ phosphors for white and NIR LEDs applications16Giant thermal enhancement of upconversion photoluminescence in Y2W3O12:Nd phosphor under 808 nm excitation11A highly thermal stable cubic-phase Sc(PO3)3:Cr3+ phosphor with emitting peak at 875 nm17A Robust Anti-Thermal-Quenching Phosphor Based on Zero-Dimensional Metal Halide Rb3InCl6:xSb3+80Ce 3+ -Activated SrLu 2 Al 3 ScSiO 12 Cyan-Green-Emitting Garnet-Structured Inorganic Phosphor Materials toward Application in Blue-Chip-Based Phosphor-Converted Solid-State White Lighting68Super thermally stable Rb-β-Al2O3:Eu blue phosphor for full-spectra lighting4Luminescence-Monitored Progressive Chemical Pressure Implementation Realized through Successive Y3+ and Mg2+ Doping into Ca10.5(PO4)7:Eu2+3Manipulating cationic ordering toward highly efficient and zero-thermal-quenching cyan photoluminescence34Negative Thermal Expansion Materials as Anti-Thermal-Quenching Phosphor Matrixes: Status, Opportunities, and Challenges51Highly thermally stable SrLaMgTaO6: Cr3+ double-perovskite phosphors for night-vision applications23A novel green phosphor Ba2Sc2((BO3)2B2O5):Ce3+ for high color rendering index full-spectrum lighting and low-temperature sensors21Striking antithermal quenching and waterproofness of Mn4+-doped fluoride phosphors induced by synergy of double coating and single passivation8Achieving zero-thermal quenching of Al2(WO4)3:Eu,Tb red phosphors with low thermal expansion for LEDs21Luminescence enhancement effects of Ca Sr2‒Nb2O7:Er3+,Tm3+ phosphors for temperature sensing and anti-counterfeiting applications14Advanced luminescence applications of 3d3 transition metal ions6A novel orange-red emitting K5Y(MoO4)4:Sm3+ phosphor with excellent color purity for temperature sensing and high CRI WLEDs19Synthesis, optical properties, and applications of Eu3+, Na+-doped high-color-purity Sr3MgNb2O9 red phosphors for w-LEDs and the detection of latent fingerprints16CaLu2Mg2Si3O12:Ce3+, Cr3+, Nd3+ Phosphor‐In‐Glass Film for Laser‐Driven Ultra‐Broadband Near‐Infrared Lighting with Watt‐Level Output35Rare-metal-free broadband near-infrared phosphors1Highly Efficient and Stable Narrow Band Green Emitting Phosphor of Sb 3+ /Ce 3+ Sensitized Cs 2 NaTbCl 6 for WLED36Absolutely Structural Disorder Boosting Bandwidth toward Full‐Spectrum White Light from Single Occupancy of Activator36Full-Visible-Spectrum White LEDs Enabled by a Blue-Light-Excitable Cyan Phosphor136Unveiling Suppressed Concentration Quenching Enhanced Broadband Near-Infrared Emitters7Rare‐Metal‐Free Ultrabroadband Near‐Infrared Phosphors72Highly Efficient Novel Garnet‐Structured Yellow Emitting Phosphor for High Power Laser‐Driven Lighting20Polymorphs of NASICON-Type Na3Sc2(PO4)3/Eu2+ Phosphors Analyzed by Single Crystal Structure Determination and Molecular Dynamics Simulations3Luminescent cyanide coordination polymer based on {Mo 6 I 8 } and {Ag 2 (dppm) 2 } clusters: exceptional stability and efficient scintillation2Modulating anti-thermal and concentration quenching for enhanced dysprosium emission6Modulating excitation light to alter temperature-dependence of two-photon upconversion luminescence in Yb 3+ /Tm 3+ co-doped LuAG transparent ceramics3Rare-earth-based donor–acceptor metal–organic frameworks with low thermal quenching and dual emission mechanisms for high-temperature sensing5Research progress on the design and regulation of Eu 2+ /Ce 3+ -activated anti-/zero thermal quenching phosphors9Optical Properties and Application of Dy3+-Doped Cd2CaTeO6 Yellow Phosphors for White LEDs6The Crystal Structure and Luminescence Behavior of Self-Activated Halotungstates Ba3WO5Cl2 for W-LEDs Applications1Highly Efficient and Thermally Stable NIR‐Emitting Phosphor with Largely Tunable Peak Wavelength and Bandwidth Toward NIR Spectroscopy Applications47Zero-thermal-quenching broadband NIR-II emitting Mg4Nb2O9: Ni2+ phosphor via defective engineering and multi-site occupation14A novel dual-excitation and dual-emission (DE2) CaS:EuCe-CN@g-C3N4 phosphor with enhanced thermal stability and humidity resistance3Compositionally Tuned Self-Activated Alkali Metal Vanadates for High Color Rendering White LEDs and IR Reflective Pigments2Enhancing the efficiency of dye sensitized solar cells using TiO2/ Sr1-xCaSiO4:xTb3+ nanocomposite as a photoelectrode modifier5Enlarging Environmental Asymmetry by the Site Tailoring to Enhance Luminescence Properties of Sm3+ in the (Gd,Na)3(Ga,In)2(Ga,Ge)3O12 Garnet21Bright upconversion over extended temperatures enabled by an organic surface layer50Broadband NIR phosphor with high external quantum yield and application of smoke penetration imaging3Synthesis, structural characterization, and photoluminescence properties of Dy3+-Doped CaB4O7 Phosphors: Influence of Li+ and K+ Co-doping14High-thermal-stability SrLaMgSbO6: Cr3+ phosphors for night vision and nondestructive testing13Activator – host structure relations of applied optical materials: a review7Wavelength-Tunable of Broad Red to Near-Infrared Emission in (Sr,Ba)3Sc4O9 :Eu2+ Phosphors: Crystal Field Effects and Thermal Stability6A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs81Emission tunable Ce3+, Mn2+ co-doped CaLu2Al4SiO12 for high color rendering whiteLED2Lanthanide cerium(III) complex with deep-red emission beyond 700 nm13Tunable luminescent color and anti-thermal quenching of Dy3+ or/and Eu3+ doping in Sc2(WO4)3 phosphors for white light-emitting diode applications4Unlocks Photoluminescence Quantum Efficiency Enhancement in Eu 2+ ‐Doped Phosphors via Bond Angle Variance Index22Unlocks Photoluminescence Quantum Efficiency Enhancement in Eu2+‐Doped Phosphors via Bond Angle Variance Index6A Zero‐Thermal Quenching Flexible Fiber for Visible Cellular Concentration Detection0A Strontium Aluminosilicate SrAl 2 SiO 6 Offering a Scalable Route to Persistent Luminescent Materials5From Model to Material: Machine Learning Enabled Discovery of LED‐Compatible Phosphors4Blue-to-cyan tunable emission in (Sr,Ca)LaGa3O7:Bi3+ phosphors achieved by adjusting the Sr:Ca ratio0Blue-to-cyan tunable emission in (Sr,Ca)LaGa3O7:Bi3+ phosphors achieved by adjusting the Sr:Ca ratio0Narrowing the cyan gap with a novel yellow-green garnet phosphor for high color-rendering full-spectrum WLEDs0Temperature-dependent mechanisms of Raman spectroscopy and photoluminescence in p-type 4H-SiC0A robust anti-thermal quenching red phosphors: Cs 2 ZrCl 6 :Sb 3+2Text mining-assisted machine learning prediction and experimental validation of emission wavelengths4Comparison of the structure–property relationships in CaZrO 3 perovskite doped with Pr 3 + , Sm 3 + , and Eu 3 + for solid-state lighting4Structural stability and tunable photoluminescence of Dy3+/Eu3+-doped BaY2O4 phosphors for high-temperature optoelectronic applications1Thermally stable near-infrared light-emitting materials2High-Quantum-Yield [Eu(Phen) 2 (NO 3 ) 3 ] Phosphor Exhibiting Zero Thermal Quenching under Real Operating Conditions (30–150 °C)1Vibronic coupling-driven, environmentally stable, and optically efficient red light-emitting lead-free perovskite-inspired materials for color-converting devices1Crystal‐Field‐Driven Modulation of Temperature‐Dependent Photophysics in Ce 3+ ‐Activated Transparent Ceramics1Unraveling Thermal Interactions in Lanthanide-Doped Phosphors: A Frequency-Domain Analysis Approach1Variation in the Singlet‐Triplet Energy Gap (Δ E ST ) Governs Multistep Thermal Responsive Photoluminescence in a Coordination Polymer Exhibiting Thermally Activated Delayed Fluorescence0Variation in the Singlet‐Triplet Energy Gap (Δ E ST ) Governs Multistep Thermal Responsive Photoluminescence in a Coordination Polymer Exhibiting Thermally Activated Delayed Fluorescence2A Non‐Stoichiometric Thioaluminate Phosphor with Severe Stacking Faults, Na 0.9 AlS 2 :Eu 2+1Defect‐Engineered Zero‐Dimensional Perovskite Cs 3 LuCl 6 : Tb 3+ Scintillator with Exceptional Thermal Stability for Flexible High‐Temperature X‐Ray Imaging2Luminescence properties and luminous thermal stability of LiZnPO4:xEu3+ phosphor0HF-free green synthesis of a highly efficient Na3Li3Sc2F12:Cr3 + near-infrared phosphor with exceptional thermal stability for real-time vein projection0Tunable thermally enhanced lasers based on 727 nm-emitting aqueous carbon dots3A garnet-structured broadband cyan phosphor CaSc2Mg2Ge3O12:Ce3+ as a high-sensitivity temperature sensor0Recent Progress in Lanthanide-Activated Halo-Phosphors for White Light-Emitting Diodes and Photovoltaic Efficiency Enhancement: A Comprehensive Review0Synergistic Effects of Lattice Stability and Frenkel Defects Designed for Anti‐Thermal Quenching X‐Ray Scintillators1Anomalous thermal enhancement and zero thermal quenching of blue-violet emission in GdCa4O(BO3)3:Bi3+ phosphor via defect-engineered deep trap levels0High Doping Concentration and Remarkable Negative Thermal Quenching in Eu 3+ ‐Activated CaCO 30The Anti‐Thermal Quenching Phosphor Landscape: Mechanisms, Materials, and Applications0Luminance Saturation in Luminescent Material: From Fundamental Mechanisms to Anti‐Saturation Material Design0Revealing Anti‐Thermal Quenching Broadband Cyan‐Green Emission in Oxonitridoaluminosilicate Phosphors Induced by Anion Ordering Substitution0From Phosphor Ceramics to Intelligent Light‐Conversion Materials: High‐Flux Luminescence, Glassy Composite Interface, and Machine‐Learning‐Guided Design0

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  1. Zero-thermal-quenching and improved chemical stability of a UCr4C4-type phosphor via crystal site engineering

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  2. Halide Perovskite Nanocrystal Emitters

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  3. The effect of local structure on the luminescence of Eu 2+ in ternary phosphate solid solutions by cationic heterovalent substitution and their application in white LEDs

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  4. A data-driven approach to predicting band gap, excitation, and emission energies for Eu 2+ -activated phosphors

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  7. Characterization of Ce:CSSO, Pr:CSSO, and co-doped Ce,Pr:CSSO phosphors for aerosol phosphor thermometry

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  21. The explanation of abnormal thermal quenching of the charge transfer band based on thermally coupled levels and applications as temperature sensing probes

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  22. Thermally Robust Broadband Near-Infrared Luminescence in the Nagap2o7:Cr3+ Phosphor

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  24. MxLa1–xSiO2–yNz (M = Ca/Sr/Ba): Elucidating and Tuning the Structure and Eu2+ Local Environments to Develop Full-Visible Spectrum Phosphors

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  31. Thermal Quenching Mechanism of Metal–Metal Charge Transfer State Transition Luminescence Based on Double-Band-Gap Modulation

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  32. Broadband near-infrared luminescence in the NaAlP2O7:Cr3+ phosphor for spectroscopy applications

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  33. Thermally Robust Broadband Near-Infrared Luminescence in the NaGaP2O7:Cr3+ Phosphor

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  34. Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+

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  35. From lab to lamp: Understanding downconverter degradation in LED packages

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  36. Laser Phosphors for Next-Generation Lighting Applications

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  37. Efficient and Thermally Robust Broadband Near‐Infrared Emission in a Garnet Ca 3 MgHfGe 3 O 12 :Cr 3+ Phosphor

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