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RESEARCH PAPER · Advanced Optical Materials · 2020

Highly Efficient Green‐to‐Yellowish‐Orange Emitting Eu2+‐Doped Pyrophosphate Phosphors with Superior Thermal Quenching Resistance for w‐LEDs

Yi Wei, Zhiyu Gao, Siwei Liu, Shuoting Chen, Gongcheng Xing, Wei Wang, Peipei Dang, Abdulaziz Abdullah Al Kheraif, Guogang Li, Jun Lin

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Highly Efficient Green‐to‐Yellowish‐Orange Emitting Eu2+‐Doped Pyrophosphate Phosphors with Superior Thermal Quenching Resistance for w‐LEDsOriginalBismuth activated full spectral double perovskite luminescence materials by excitation and valence control for future intelligent LED lighting28Highly efficient and thermally stable luminescence of Ca 3 Gd 2 Si 6 O 18 :Ce 3+ ,Tb 3+ phosphors based on efficient energy transfer38Site-selective occupation of Eu2+ activators toward full-visible-spectrum emission in well-designed borophosphate phosphors96Data-Driven Photoluminescence Tuning in Eu2+-Doped Phosphors76Two‐Step Sol–Gel Synthetic Strategy for Highly Dispersed Eu2+ Luminescence Centers for Tuning Emission5Exploiting the diverse photoluminescence behaviors of NaLuF4:xEu3+ nanoparticles and g-C3N4 to realize versatile applications in white light-emitting diode and optical thermometer161The photoluminescence, thermal properties and tunable color of bright green-emitting Ba3Sc(BO3)3:Ce3+/Tb3+ phosphors via efficient energy transfer41Hetero-valent substitution strategy toward orange-red luminescence in Bi3+ doped layered perovskite oxide phosphors for high color rendering index white light-emitting diodes105Facile modulation the sensitivity of Eu2+/Eu3+-coactivated Li2CaSiO4 phosphors through adjusting spatial mode and doping concentration33Red-tunable LuAG garnet phosphors via Eu 3+ →Mn 4+ energy transfer for optical thermometry sensor application72Near‐Unity Cyan‐Green Emitting Lead‐Free All‐Inorganic Cesium Copper Chloride Phosphors for Full‐Spectrum White Light‐Emitting Diodes25Preparation of zero-thermal-quenching tunable emission bismuth-containing phosphors through the topochemical design of ligand configuration31Near-ultraviolet excited broadband orange-yellow emitting Sr8MgIn(PO4)7:Eu2+ phosphors for WLEDs with high color rendering index10A broadband emitting Sr8MgGa(PO4)7:Eu2+ phosphor for application in white light-emitting diodes with excellent color rendering index6Rapid Synthesis of Red‐Emitting Sr2Sc0.5Ga1.5O5:Eu2+ Phosphors and the Tunable Photoluminescence Via Sr/Ba Substitution90Combinations of Superior Inorganic Phosphors for Level‐Tunable Information Hiding and Encoding61Broadband excited Na 3 Tb(PO 4 ) 2 :Ce 3+ /Eu 2+ green/yellow‐emitting phosphors with high color purity for LED‐based application15Li + Ion Induced Full Visible Emission in Single Eu 2+ ‐Doped White Emitting Phosphor: Eu 2+ Site Preference Analysis, Luminescence Properties, and WLED Applications93Tunable photoluminescence and temperature sensing properties of Ce3+, Eu2+ co-doped Ca2-Sr MgSi2O7 phosphors11Unraveling the Preferable Occupation and Luminescent Properties of Ce 3+ -Doped Ca 9 Nd(PO 4 ) 72Constructing a Model for Tuning the Thermal Quenching Properties of Bismuth-Doped Phosphors by Energy-Gap Modulation34Reidinger defects induced thermally stable green emission from Eu2+, Mn2+ co-doped Ba0.75Al11O17.25 transparent ceramics16Extension of Spectral Shift Controls from Equivalent Substitution to an Energy Migration Model Based on Eu2+/Tb3+-Activated Ba4–xSrxGd3–xLuxNa3(PO4)6F2 Phosphors11Full-visible-spectrum lighting enabled by site-selective occupation in the high efficient and thermal stable (Rb, K)2CaPO4F: Eu2+ solid-solution phosphors58Influence of synthesis conditions on structural and spectroscopic properties of the K2SrP2O7 pyrophosphate doped with the Eu3+ and Eu2+ ions17Realization of an Optical Thermometer via Structural Confinement and Energy Transfer39Anti-thermal-quenching, color-tunable and ultra-narrow-band cyan green-emitting phosphor for w-LEDs with enhanced color rendering85Fabrication, Photoluminescence, and Applications of Rare-Earth Ions-Activated Nanophosphors0Tuning of the thermal quenching performance of Bi 3+ -doped scheelite Ca(Mo/W)O 4 solid solution phosphors13Investigation of the Solid-Solution Limit, Crystal Structure, and Thermal Quenching Mitigation of Sr-Substituted Rb2CaP2O7:Eu2+ Phosphors for White LED Applications26How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Processing RGB Color Sensors for Measuring the Circadian Stimulus of Artificial and Daylight Light Sources12Competitive Site Occupation toward Improved Quantum Efficiency of SrLaScO 4 :Eu Red Phosphors for Warm White LEDs103High Water Resistance and Luminescent Thermal Stability of LiyNa(2–y)SiF6: Mn4+ Red-Emitting Phosphor Induced by Codoping of Li+19Superb thermal stability purple-blue phosphor through synergistic effect of emission compensation and nonradiative transition restriction of Eu2+31Enhanced thermostability of Eu3+ ions photoluminescence by multi-level electron traps with various temperature responses4Manipulating Upconversion Emission and Thermochromic Properties of Ho3+/Yb3+-Codoped Al2Mo3O12 Microparticles by Negative Lattice Expansion for Multimode Visual Optical Thermometry79Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Design of K2SrCa(PO4)2-x(BO3)x:Eu2+ phosphors with full-visible spectrum by crystal structure modification12Perovskite A-site symmetry tuning to achieve high quantum efficiency phosphor for WLED applications18Effect of local crystal field environment on luminous properties of Er3+/Yb3+-doped titanate upconversion luminescent materials17Highly-efficient Eu 2+ -activated Sr 8 Si 4 O 12 Cl 8 cyan-emitting phosphors with zero-thermal quenching luminescence for versatile applications16Spectral properties and self-reduction of Eu 3+ to Eu 2+ in aluminosilicate oxyfluoride glass30Broadband and Multimode Near‐Infrared Emitter Based on Cr3+‐Activated Stannate for Multifunctional Applications75Eu 2+ -Doped Ca 4 Y 3 Si 7 O 15 N 5 Phosphor with High Thermal Stability and Pressure Sensitivity for Dual-Functional Applications in W-LEDs and Pressure Sensors32Analyses of ultraviolet-excitable high-efficiency phosphorescent RGB phosphors with various Eu2O3 doping concentrations for fabricating white Light–Emitting diodes5Simultaneous Luminescence Color Tuning and Spectral Broadening of Cr3+ Near-Infrared Emission for Night Vision Application28Phosphor-aluminosilicate CsPbX3 perovskite fluorescent glass with low formation temperature for photoluminescence display applications2Enhancement of broad-spectrum orange emission and thermal stability in Rb2-xCsxCaP2O7:0.015Eu2+ phosphors by improving local structural symmetry6Structure and photoluminescence studies of Rb3GdSi2O7: Eu2+ phosphor used for NUV converted white LEDs10Vacancy-Enhanced Self-Reduction of Eu in Pyrophosphate Phosphor39Study synthetic method, photoluminescence mechanism and optimistic applications of KAlSiO 4 Phosphor0Valence conversion and site reconstruction in near-infrared-emitting chromium-activated garnet for simultaneous enhancement of quantum efficiency and thermal stability161Structure and tunable white-light emission of the Ce3+/Dy3+ co-doped MgO–K2O–B2O3–P2O5 borophosphate glasses by modulating Mg/K ratio18A promising yellow-emitting langbeinite-type phosphor NaBaY 2 (PO 4 ) 3 :Eu 2+ for WLEDs10Achieving Broadband NIR Emission in Fe 3+ ‐Activated ALaBB′O 6 (A = Ba, Sr, Ca; B–B′ = Li–Te, Mg–Sb) Phosphors via Multi‐Site Ionic Co‐Substitutions60A novel extra-broadband visible-emitting garnet phosphor for efficient single-component pc-WLEDs6An efficient blue–violet phosphor: an advanced material designed for high-quality full-spectrum lighting11Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Negative Thermal Quenching of Photoluminescence: An Evaluation from the Macroscopic Viewpoint28Multicolor regulation of trivalent lanthanide ions-codoped boggildite-type phosphor toward superb warm white luminescence for white light-emitting diodes13Realization and optimization of bismuth-activated Ba3Ga2O5Cl2 yellow phosphor for high-quality white LEDs82One stone, two birds: Luminescence properties of Ca8ZnY(PO4)7:Eu2+, Mn2+ and multifunctional applications in WLEDs & optical anti-counterfeiting26Bi3+-activated Na3Ca2TaO6: A novel narrow-band blue-emitting phosphor towards backlight display applications17Trivalent terbium host-sensitized orthoniobate green phosphor with high luminescence thermal stability for promising backlighting white light-emitting diodes1Photoluminescence studies and optimistic applications of KAlSiO4 phosphor synthesized by combustion method4Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review18Highly efficient and water-resistant BaGa4S7:Eu2+ phosphor prepared by a self-reduction method7Co-training machine learning enables interpretable discovery of near-infrared phosphors with high performance16Design of Dual-Mode Optical Thermometry Based on Thermally Activated Efficient Energy Transfer in LaNbO4/Ln3+ (Eu3+/Sm3+/Pr3+) Phosphors26Defect-Enabled Superior Negative Thermal Quenching in Palmierite Ba9La(VO4)7:Eu3+ for WLED In Situ Temperature Measuring12Enhanced luminescence of CaO:Eu2+ red phosphor in glass for high-power warm LED6Stability of Phosphors for White LED Excitable by Violet Light3Sr 8 MgSc(PO 4 ) 7 :Eu 2+ phosphor: d–f transition driven applications for solid-state lighting and extreme environment multimode sensing investigations18Structural regulation and properties of Ca8.96Li Na1-Al0.667(PO4)7:0.04Eu2 + full spectrum phosphor9Luminescent properties of Ce3 +, Li+, Eu2+ and Ce3+-Eu2+ energy transfer in Sr2-xBaxSiO4 phosphor6Violet light excitable K x Na 5 −x B 2 P 3 O 13 :Eu ( x = 0, 1, 2) borophosphates as novel phosphors for multifunctional applications2Ca9-zMzCsLu0.667(PO4)7:Eu2+ (M = Mg2+, Sr2+): β-Ca3(PO4)2-based LED phosphors with improved thermal stability and standard white light3A potential thermophotovoltaic emitter Er(Ta 1− x Nb x )O 4 (0 ≤ x ≤ 0.2) with excellent selective emission performance8Color tuning of single-phased Ca9KMg(PO4)7:Sr2+, Eu2+, Mn2+ phosphor based on cation substitution and energy transfer for WLED applications8A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs81Self-reduction regulation in NaZr2(PO4)3: Eu2+/Eu3+ phosphor and their potential optical thermometric applications4Controlled synthesis of Yb3 + /Er3+ co-doped ZrO2 phases and their luminescence properties3Progressive chemical pressure-induced trap-controlled multimode luminescence5Unveiling Sr2MgGe2O7:Eu3+ phosphors: Next-generation solutions for w-LEDs, deep learning-assisted forensic fingerprint detection and anti-counterfeiting9Solvent Polarity Triggered Rapidly Reversible Quadruple‐Mode Luminescence Adjustment in 0D Hybrid Antimony Halides1Solvent Polarity Triggered Rapidly Reversible Quadruple‐Mode Luminescence Adjustment in 0D Hybrid Antimony Halides13Multi-site occupied Cs2Ba3(P2O7)2:Eu2+ phosphor with blue-green dual emission for full-spectrum lighting2Tuning White-Light Emission of POSS-Based Fluorescent Hybrid Porous Polymers via Physical Blending for White LEDs0Tailoring cationic configurations in β‐Ca 3 (PO 4 ) 2 ‐type matrices for gentle orange emission toward eye‐comfort lighting2Thermal‐Robust and Glass‐Compatible K 1.3 Al 9 Ga 2 O 17.15 :Eu for Laser‐Driven Lighting and Underwater Optical Communication3Controlling trap energy re-releasing under near-infrared photo-stimulated luminescence in CaxSr1-xS: Eu2+ , Sm3+ phosphors for optical anti-counterfeiting0Environmentally Robust Sr 2‐x P 2 O 7 :xEu 3+ Red Phosphor for Multi‐Scenario Optoelectronic Applications1Selective emission optimization of (Er1–2Yb Gd )NbO4 (0≤x≤0.1) for thermophotovoltaic applications1Enhancing luminescence thermal stability of Sm3+/Pr3+-doped Na5Y(WO4)4 phosphors based on charge transfer band red-shift and defect compensation0A Promising Selective Emitter Ho(Ta1− x Nb x )O4 with Enhanced Performance for Thermophotovoltaic Applications0Reddish Orange Emitting Sm3+ Ion on Lithium Cadmium Orthophosphate Nanopowders for Solid State Lighting Applications0Surface modification of Ba1.53Sr0.37SiO4:0.1Eu2+ green emitting phosphors with theobromine (3,7-dimethylxanthine)0Luminance Saturation in Luminescent Material: From Fundamental Mechanisms to Anti‐Saturation Material Design0

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  50. Structure and photoluminescence studies of Rb3GdSi2O7: Eu2+ phosphor used for NUV converted white LEDs

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