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RESEARCH PAPER · Inorganic Chemistry · 1998

Composition Space Diagrams for Mixed Transition Metal Oxide Fluorides

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Composition Space Diagrams for Mixed Transition Metal Oxide FluoridesOriginalThe Polar [WO2F4]2- Anion in the Solid State65From Molecules to Frameworks: Variable Dimensionality in the UO2(CH3COO)2·2H2O/HF(aq)/Piperazine System. Syntheses, Structures, and Characterization of Zero-Dimensional (C4N2H12)UO2F4·3H2O, One-Dimensional (C4N2H12)2U2F12·H2O, Two-Dimensional (C4N2H12)2(U2O4F5)4·11H2O, and Three-Dimensional (C4N2H12)U2O4F679Syntheses, Structures, and Properties of RbScFAsO4 and CsScFAsO4: Scandium-Containing Analogues of Potassium Titanyl Phosphate (KTiOPO4)17Synthesis of the Neutral (CuF(NC5H5)4)2NbOF5 Cluster14The Structure-Directing Properties of [VOF5]2-66Hydrothermal Syntheses of Layered Uranium Oxyfluorides: Illustrations of Dimensional Reduction43Hydrothermal Syntheses, Structures, and Fluorescence Spectroscopy of New One-Dimensional Uranium Oxyfluorides Built from Edge-Sharing [UO2F5] Pentagonal Bipyramids78Hydrothermal Synthesis, Structure, and Magnetic Properties of a Layered Organically Templated Uranium Aquofluoride: [C5H14N2][U2F10(H2O)]44Absence of Ligand-Mediated Symmetry Reduction in a Solid Solution: Cu(NC5H5)4[(NbOF5)1-x(WO2F4)x] (0 ≤ x ≤ 1)2Hydrothermal Syntheses, Structures, and Magnetic Properties of the U(IV) Fluorides (C5H14N2)2U2F12·5H2O and (NH4)7U6F3143Organically Templated Zirconium Fluorides: Hydrothermal Syntheses, Structural Relationships, and Thermal Behavior of (C2H10N2)Zr2F10·H2O and (C4H12N2)ZrF6·H2O22Understanding the Role of Helical Chains in the Formation of Noncentrosymmetric Solids275Poly(tetrafluoroethylene) Impregnation for Ion-Exchange Reactions with Layered Ce(IV) Fluorides8Further Evidence for the Tetraoxoiodate(V) Anion, IO43-: Hydrothermal Syntheses and Structures of Ba[(MoO2)6(IO4)2O4]·H2O and Ba3[(MoO2)2(IO6)2]·2H2O48From Linear Inorganic Chains to Helices: Chirality in the M(pyz)(H2O)2MoO2F4 (M = Zn, Cd) Compounds62Organically templated uranium(vi) sulfates: understanding phase stability using composition space83Niobium and Tantalum7Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies17Variable Dimensionality in the UO2(CH3CO2)2·2H2O/HF/Isonicotinic Acid System: Synthesis and Structures of Zero-, One-, and Two-Dimensional Uranium Isonicotinates56Alignment of acentric MoO3F33− anions in a polar material: (Ag3MoO3F3)(Ag3MoO4)Cl440Exploration of Composition Space in Templated Uranium Sulfates89Probing helix formation in chains of vertex-linked octahedra44Examining the Out-of-Center Distortion in the [NbOF5]2- Anion271Fluorides: Solid‐State Chemistry1Fluorides: Solid‐State Chemistry0Evidence for Nonpolar Alignment of [NbOF5]2- Anions in Cd(pyridine)4NbOF5 Chains24Directed Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis72Synthesis, structure and characterization of a new inorganic-organic hybrid complex (C3H5N2)2[Cd(C3H4N2)2Nb2O3F8]·2H2O1The role of temperature in the solvothermal synthesis of hybrid vanadium oxyfluorides41The Ag2O−V2O5−HF(aq) System and Crystal Structure of α-Ag3VO446Novel Vanadium(IV) Oxyfluorides with ‘Spin-Ladder'-Like Structures, and Their Relationship to (VO)2P2O751[H4tren]3/2·(Al6F24)·3H2O, the most condensed fluoride in the Al(OH)3-tren-HFaq.-ethanol system14Composition space analysis of templated molybdates25Effects of Reaction Gel Dehydration on the Synthesis of Cu(NC5H5)4VOF4 and [Cu(NC5H5)4VOF4][Cu(NC5H5)4(H2O)VOF4]·H2O18Cation−Anion Interactions and Polar Structures in the Solid State196Noncentrosymmetry in Mixed Metal Oxide-Fluorides, Can We Control It?0Orientational disorder and phase transitions in crystals of (NH4)2NbOF517Synthetic Approaches for Noncentrosymmetric Molybdates59Disorder in crystals of dioxofluorotungstates, (NH4)2WO2F4 and Rb2WO2F429Organic–inorganic hybrid chains and layers constructed from copper-amine cations and early transition metal (Nb, Mo) oxyfluoride anions21Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions46Novel building units with bimetallic rings in inorganic/organic hybrid chains and layers2Microporosity, Optical Bandgap Sizes, and Photocatalytic Activity of M(I)-Nb(V) (M = Cu, Ag) Oxyfluoride Hybrids34Novel Layered Hybrid Fluoroaluminate in the Composition Space Diagram of the Al(OH)3-HguaCl-HFaq-EtOH System18Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8Crystal Growth of Ag3MOxF6−x (M = V, x = 2; M = Mo, x = 3)30New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)43Intramolecular mobility and phase transitions in ammonium oxofluoroniobates (NH4)2NbOF5 and (NH4)3NbOF6, a NMR and DFT study20Hydrothermal synthesis, crystal structure and property of a barbell-like copper complex with {(μ-F)[(μ-O)2(NbF4)2]} as the handle bar4Mixed metalII–metalIV hybrid fluorides11Understanding an Order–Disorder Phase Transition in Ionothermally Synthesized Gallium Phosphates9Structural evidence of [Rh(Thio)6]3+ and [Rh(Thio)5Cl]2+ cations in three novel ionic systems based on Co(III) dioximates13Beyond Charge Density Matching: The Role of C–H···O Interactions in the Formation of Templated Vanadium Tellurites16The Role of Polar, Lamdba (Λ)-Shaped Building Units in Noncentrosymmetric Inorganic Structures139The Dimeric [V2O4F6]4– Vanadium Oxide‐Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)8Chemistry of Polar Transition-Metal Oxides1Structure-Directing Self-Assembly, Structures and Characterization of Four d0-Transition Metal Oxide/Fluoride Compounds Constructed with Imidazole/1-Methylimidazole/1-Vinylimidazole and Copper(II)/Zinc(II)16Ba2YFeO5.5: A Ferromagnetic Pyroelectric Phase Prepared by Topochemical Oxidation.17Bonding and Structure of Oxofluoroniobate-Based Glasses7AgNa(VO2F2)2: A Trioxovanadium Fluoride with Unconventional Electrochemical Properties22Nonlinear Active Materials: An Illustration of Controllable Phase Matchability113Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model16From Solution to the Solid State: Control of Niobium Oxide–Fluoride [NbO x F y ] n − Species26Polar Alignment of Λ-Shaped Basic Building Units within Transition Metal Oxide Fluoride Materials15Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–20Synthesis and Magnetic Properties of β‐KVOF317Fluorides: Solid‐State Chemistry0Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability46Triazolyl–Based Copper–Molybdate Hybrids: From Composition Space Diagram to Magnetism and Catalytic Performance41Formation Principles for Vanadium Selenites: The Role of pH on Product Composition12Role of Noncovalent Interactions in Vanadium Tellurite Chain Connectivities14Two‐step Hydrothermal Syntheses and Structures of Three Tantalum Oxyfluoride Compounds with [M(phen)3]2+(M = Ru, Fe) Counter Ions3On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units55Structural chemistry of fluoride and oxofluoride complexes of titanium(IV)18The role of inorganic acidity on templated vanadate composition and dimensionality4Effect of the tetrahedral groups on the optical properties of LaBRO5 (R = Si and Ge): A first-principles study11Composition Space Analysis in the Development of Copper Molybdate Hybrids Decorated by a Bifunctional Pyrazolyl/1,2,4-Triazole Ligand31Mesoporous In-Sn binary oxides of crystalline framework with extended compositional variation0Temperature-Independent, Large Dielectric Constant Induced by Vacancy and Partial Anion Order in the Oxyfluoride Pyrochlore Pb2Ti2O6−δF2δ42Exploration of a Variety of Copper Molybdate Coordination Hybrids Based on a Flexible Bis(1,2,4-triazole) Ligand: A Look through the Composition-Space Diagram16Understanding structural adaptability: a reactant informatics approach to experiment design12Making an order: the concerted alignment of [MOF5]2− (M = Nb and Ta) dipolar anions in one-dimensional coordination chains sustained by tris(3,4,5-trimethyl-1H-pyrazole)copper(II)2A series of oxyfluoride chains containing asymmetric basic building units of both early- and late-transition metal cations5Templated vanadium tellurites: Identifying the effects of low density attractions on inorganic layer topology4Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands9Mixed Transition Metal (Oxy)fluoride Paramagnet Chains: Synthesis, Structure, and Characterization11BaWO 2 F 4 : a mixed anion X-ray scintillator with excellent photoluminescence quantum efficiency19Influence of structure-directing polyhedra and heterocyclic ligands on the chain structures and O/F ordering in a series of zinc vanadium oxyfluorides1Machine-Learning-Assisted Synthesis of Polar Racemates33Synthesis of NaMoO3F and Na5W3O9F5 with Morphological Controllability in Non-Aqueous Solvents15Mixed-Valent Copper Chalcogenides: Tuning Structures and Electronic Properties Using Multiple Anions20Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24Novel layered heterobimetallic fluorides with large optical band gaps3Solvothermal and hydrothermal methods for preparative solid-state chemistry5Controlling the Assembly of Tantalum Oxyfluoride Anions by Organic Amine Cations: From Molecular Cluster, Molecular Cage to Polymeric Chain1Targeting Oxide Concentration in Tantalum Oxide-Fluoride Anions0Single‐Step Synthesis of An Ideal Chain Antiferromagnet [H 2 (4,4′‐bipyridyl)](H 3 O) 2 Fe 2 F 10 with Spin S =5/20Single‐Step Synthesis of An Ideal Chain Antiferromagnet [H 2 (4,4′‐bipyridyl)](H 3 O) 2 Fe 2 F 10 with Spin S =5/26Fluorides: Inorganic Solid‐State and Structural Chemistry0

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  1. The Polar [WO2F4]2- Anion in the Solid State

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  2. From Molecules to Frameworks: Variable Dimensionality in the UO2(CH3COO)2·2H2O/HF(aq)/Piperazine System. Syntheses, Structures, and Characterization of Zero-Dimensional (C4N2H12)UO2F4·3H2O, One-Dimensional (C4N2H12)2U2F12·H2O, Two-Dimensional (C4N2H12)2(U2O4F5)4·11H2O, and Three-Dimensional (C4N2H12)U2O4F6

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  3. Syntheses, Structures, and Properties of RbScFAsO4 and CsScFAsO4: Scandium-Containing Analogues of Potassium Titanyl Phosphate (KTiOPO4)

    Chemistry of Materials · 1999-11-13

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  4. Synthesis of the Neutral (CuF(NC5H5)4)2NbOF5 Cluster

    Chemistry of Materials · 2000-06-16

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  5. The Structure-Directing Properties of [VOF5]2-

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    Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  6. Hydrothermal Syntheses of Layered Uranium Oxyfluorides: Illustrations of Dimensional Reduction

    Inorganic Chemistry · 2000-10-26

    Catherine E. Talley, Amanda C. Bean, Thomas E. Albrecht‐Schmitt

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  7. Hydrothermal Syntheses, Structures, and Fluorescence Spectroscopy of New One-Dimensional Uranium Oxyfluorides Built from Edge-Sharing [UO2F5] Pentagonal Bipyramids

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  8. Hydrothermal Synthesis, Structure, and Magnetic Properties of a Layered Organically Templated Uranium Aquofluoride: [C5H14N2][U2F10(H2O)]

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    Philip M. Almond, Laura Deakin, Arthur Mar, Thomas E. Albrecht‐Schmitt

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  9. Absence of Ligand-Mediated Symmetry Reduction in a Solid Solution: Cu(NC5H5)4[(NbOF5)1-x(WO2F4)x] (0 ≤ x ≤ 1)

    Crystal Growth & Design · 2001-03-03

    Kevin R. Heier, Alexander J. Norquist, Claude L. Mertzenich, Kenneth Reinhard Poeppelmeier

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  10. Hydrothermal Syntheses, Structures, and Magnetic Properties of the U(IV) Fluorides (C5H14N2)2U2F12·5H2O and (NH4)7U6F31

    Journal of Solid State Chemistry · 2001-04-01

    Philip M. Almond, Laura Deakin, Arthur Mar, Thomas E. Albrecht‐Schmitt

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  11. Organically Templated Zirconium Fluorides: Hydrothermal Syntheses, Structural Relationships, and Thermal Behavior of (C2H10N2)Zr2F10·H2O and (C4H12N2)ZrF6·H2O

    Journal of Solid State Chemistry · 2001-06-01

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  12. Understanding the Role of Helical Chains in the Formation of Noncentrosymmetric Solids

    Journal of the American Chemical Society · 2001-07-11

    Paul A. Maggard, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  13. Poly(tetrafluoroethylene) Impregnation for Ion-Exchange Reactions with Layered Ce(IV) Fluorides

    Chemistry of Materials · 2001-11-17

    Richard E. Sykora, Thomas E. Albrecht‐Schmitt

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  14. Further Evidence for the Tetraoxoiodate(V) Anion, IO43-: Hydrothermal Syntheses and Structures of Ba[(MoO2)6(IO4)2O4]·H2O and Ba3[(MoO2)2(IO6)2]·2H2O

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  15. From Linear Inorganic Chains to Helices: Chirality in the M(pyz)(H2O)2MoO2F4 (M = Zn, Cd) Compounds

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  16. Organically templated uranium(vi) sulfates: understanding phase stability using composition space

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  17. Niobium and Tantalum

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  18. Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies

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  19. Variable Dimensionality in the UO2(CH3CO2)2·2H2O/HF/Isonicotinic Acid System: Synthesis and Structures of Zero-, One-, and Two-Dimensional Uranium Isonicotinates

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  20. Alignment of acentric MoO3F33− anions in a polar material: (Ag3MoO3F3)(Ag3MoO4)Cl

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  21. Exploration of Composition Space in Templated Uranium Sulfates

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  22. Probing helix formation in chains of vertex-linked octahedra

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  23. Examining the Out-of-Center Distortion in the [NbOF5]2- Anion

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  24. Fluorides: Solid‐State Chemistry

    Encyclopedia of Inorganic Chemistry · 2005-09-07

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  25. Fluorides: Solid‐State Chemistry

    Encyclopedia of Inorganic and Bioinorganic Chemistry · 2005-09-07

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  26. Evidence for Nonpolar Alignment of [NbOF5]2- Anions in Cd(pyridine)4NbOF5 Chains

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  27. Directed Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis

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  28. Synthesis, structure and characterization of a new inorganic-organic hybrid complex (C3H5N2)2[Cd(C3H4N2)2Nb2O3F8]·2H2O

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  29. The role of temperature in the solvothermal synthesis of hybrid vanadium oxyfluorides

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  30. The Ag2O−V2O5−HF(aq) System and Crystal Structure of α-Ag3VO4

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  31. Novel Vanadium(IV) Oxyfluorides with ‘Spin-Ladder'-Like Structures, and Their Relationship to (VO)2P2O7

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  32. [H4tren]3/2·(Al6F24)·3H2O, the most condensed fluoride in the Al(OH)3-tren-HFaq.-ethanol system

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    Karim Adil, Jérôme Marrot, M. Leblanc, V. Maisonneuve

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  33. Composition space analysis of templated molybdates

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    J.H. Nelson, Alexander R. Johnston, Amy Narducci Sarjeant, Alexander J. Norquist

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  34. Effects of Reaction Gel Dehydration on the Synthesis of Cu(NC5H5)4VOF4 and [Cu(NC5H5)4VOF4][Cu(NC5H5)4(H2O)VOF4]·H2O

    Crystal Growth & Design · 2007-04-18

    Margaret E. Welk, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier, Alexander J. Norquist

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  35. Cation−Anion Interactions and Polar Structures in the Solid State

    Journal of the American Chemical Society · 2007-10-18

    Michael R. Marvel, Julien Lesage, Jaewook Baek, P. Shiv Halasyamani, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  36. Noncentrosymmetry in Mixed Metal Oxide-Fluorides, Can We Control It?

    MRS Proceedings · 2008-01-01

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  37. Orientational disorder and phase transitions in crystals of (NH4)2NbOF5

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  38. Synthetic Approaches for Noncentrosymmetric Molybdates

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  39. Disorder in crystals of dioxofluorotungstates, (NH4)2WO2F4 and Rb2WO2F4

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  40. Organic–inorganic hybrid chains and layers constructed from copper-amine cations and early transition metal (Nb, Mo) oxyfluoride anions

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  41. Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions

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  42. Novel building units with bimetallic rings in inorganic/organic hybrid chains and layers

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  43. Microporosity, Optical Bandgap Sizes, and Photocatalytic Activity of M(I)-Nb(V) (M = Cu, Ag) Oxyfluoride Hybrids

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  44. Novel Layered Hybrid Fluoroaluminate in the Composition Space Diagram of the Al(OH)3-HguaCl-HFaq-EtOH System

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  45. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

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  46. Crystal Growth of Ag3MOxF6−x (M = V, x = 2; M = Mo, x = 3)

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  47. New Layered Oxide-Fluoride Perovskites: KNaNbOF5 and KNaMO2F4 (M = Mo6+, W6+)

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  48. Intramolecular mobility and phase transitions in ammonium oxofluoroniobates (NH4)2NbOF5 and (NH4)3NbOF6, a NMR and DFT study

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  49. Hydrothermal synthesis, crystal structure and property of a barbell-like copper complex with {(μ-F)[(μ-O)2(NbF4)2]} as the handle bar

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  50. Mixed metalII–metalIV hybrid fluorides

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