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RESEARCH PAPER · Dalton Transactions · 2012

PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environments

Seung‐Jin Oh, Dong Woo Lee, Kang Min Ok

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PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environmentsOriginalEffect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)450Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)28Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment22From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations9Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites18Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)11Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism16A review of the structural architecture of tellurium oxycompounds170Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity38Formation of Ag Nanoparticles on β-Ag2WO4through Electron Beam Irradiation: A Synergetic Computational and Experimental Study45A Polar Titanium–Organic Chain with a Very Large Second-Harmonic-Generation Response5Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores14Stabilization of O–O Bonds by d0 Cations in Li4+ x Ni1– x WO6 (0 ≤ x ≤ 0.25) Rock Salt Oxides as the Origin of Large Voltage Hysteresis85Selective removal of heavy metal ions in aqueous solutions by sulfide-selector intercalated layered double hydroxide adsorbent60Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)218Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization3Development of Sn2+-based oxyfluoride photocatalyst with visible light response of ca. 650 nm via strengthened hybridization of Sn 5s and O 2p orbitals20Single crystal growth and piezoelectric features of the Ca 2 Nb 2 O 7 crystal with orthorhombic symmetry10Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 192

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  1. Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)4

    Inorganic Chemistry · 2012-07-02

    Dong Woo Lee, Dan‐bee Bak, Saet Byeol Kim, Jiwon Kim, Kang Min Ok

    Read original paper ↗ ·

  2. Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2012-07-16

    Dong Woo Lee, Saet Byeol Kim, Kang Min Ok

    Read original paper ↗ ·

  3. Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement

    Chemical Communications · 2013-01-01

    Xue‐Li Cao, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  4. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

    RSC Advances · 2013-01-01

    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

    Read original paper ↗ ·

  5. New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)

    Inorganic Chemistry · 2013-03-18

    Eun Pyo Lee, Seung Yoon Song, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  6. New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities

    Inorganic Chemistry · 2013-04-16

    Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  7. New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O

    Inorganic Chemistry · 2013-08-16

    Dong Woo Lee, Kang Min Ok

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  8. α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2013-09-11

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  9. Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment

    Journal of Solid State Chemistry · 2013-10-10

    Seong‐eun Bang, Zhi Quan Pan, Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  10. From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)6

    Inorganic Chemistry · 2013-10-21

    Hyun Sun Ahn, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  11. VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations

    Inorganic Chemistry · 2013-11-21

    Yiseul Shin, Dong Woo Lee, Kwang‐Yong Choi, Hyun‐Joo Koo, Kang Min Ok

    Read original paper ↗ ·

  12. Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

    Inorganic Chemistry · 2014-01-02

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  13. Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2014-04-22

    Seong‐eun Bang, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  14. Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)2

    Inorganic Chemistry · 2014-05-07

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  15. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

    Inorganic Chemistry · 2014-06-11

    Seung Yoon Song, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  16. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

    Inorganic Chemistry · 2014-08-07

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

    Read original paper ↗ ·

  17. Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations

    Journal of Solid State Chemistry · 2014-09-30

    Hyun Sun Ahn, Eun Pyo Lee, Hong‐Young Chang, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  18. Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)

    Dalton Transactions · 2015-01-01

    Shujuan Han, Ying Wang, Qun Jing, Hongping Wu, Shilie Pan, Zhihua Yang

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  19. pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites

    Inorganic Chemistry · 2015-02-17

    Vadim M. Kovrugin, Marie Colmont, Christine Terryn, S. Colis, Oleg I. Siidra, Sergey V. Krivovichev, Olivier Mentré

    Read original paper ↗ ·

  20. Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra

    Inorganic Chemistry · 2015-04-02

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  21. Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3

    Inorganic Chemistry · 2015-08-26

    Seong‐eun Bang, Kang Min Ok

    Read original paper ↗ ·

  22. Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)

    Journal of Solid State Chemistry · 2016-01-16

    Shujuan Han, Chunyan Bai, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  23. Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism

    Crystal Growth & Design · 2016-03-15

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Sergey V. Krivovichev, Olivier Mentré

    Read original paper ↗ ·

  24. A review of the structural architecture of tellurium oxycompounds

    Mineralogical Magazine · 2016-05-01

    Andrew G. Christy, Stuart J. Mills, Anthony R. Kampf

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  25. Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity

    Inorganic Chemistry · 2016-05-26

    Hongil Jo, Kang Min Ok

    Read original paper ↗ ·

  26. Formation of Ag Nanoparticles on β-Ag2WO4through Electron Beam Irradiation: A Synergetic Computational and Experimental Study

    Inorganic Chemistry · 2016-08-17

    Román Alvarez Roca, Amanda Fernandes Gouveia, Pablo Santana Lemos, Lourdes Gracia, Juán Andrés, E. Longo

    Read original paper ↗ ·

  27. A Polar Titanium–Organic Chain with a Very Large Second-Harmonic-Generation Response

    Inorganic Chemistry · 2016-11-10

    Bongsu Kim, Seung‐Jin Oh, Hongil Jo, Kang Min Ok

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  28. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  29. Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond

    Dalton Transactions · 2017-01-01

    Hongil Jo, Seung‐Jin Oh, Kang Min Ok

    Read original paper ↗ ·

  30. Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores

    Journal of Solid State Chemistry · 2019-01-11

    Soyon Lee, Hongil Jo, Kang Min Ok

    Read original paper ↗ ·

  31. Stabilization of O–O Bonds by d0 Cations in Li4+ x Ni1– x WO6 (0 ≤ x ≤ 0.25) Rock Salt Oxides as the Origin of Large Voltage Hysteresis

    Journal of the American Chemical Society · 2019-04-11

    Zane Taylor, Arnaud J. Perez, José Antonio Coca Clemente, Filipe Braga, Nicholas E. Drewett, Michael J. Pitcher, William J. Thomas, Matthew Stephen Dyer, Christopher M. Collins, Marco Zanella, Timothy J. Johnson, Sarah J. Day, Chiu Chung Tang, V.R. Dhanak, John B. Claridge, Laurence J. Hardwick, Matthew J. Rosseinsky

    Read original paper ↗ ·

  32. Selective removal of heavy metal ions in aqueous solutions by sulfide-selector intercalated layered double hydroxide adsorbent

    Journal of Material Science and Technology · 2019-04-24

    Jing Wang, Jing Wang, Liang Zhang, Tian-Shu Zhang, Ting Du, Tao Li, Tianli Yue, Chunhua Li, Jianlong Wang, Jianlong Wang

    Read original paper ↗ ·

  33. Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)2

    Inorganic Chemistry · 2020-02-13

    Tingting Shi, Fangfang Zhang, Yahui Li, Le Gao, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  34. Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization

    Journal of Solid State Chemistry · 2021-02-06

    Dong Woo Lee, Hye Ran Noh, Tae-Hyeong Kim, Jeongmook Lee, Jong‐Yun Kim, Kyung‐Tae Ko, Sang Ho Lim

    Read original paper ↗ ·

  35. Development of Sn2+-based oxyfluoride photocatalyst with visible light response of ca. 650 nm via strengthened hybridization of Sn 5s and O 2p orbitals

    Journal of Energy Chemistry · 2021-08-09

    Yanpei Luo, Xin Zhou, Jiangwei Zhang, Yu Qi, Zheng Li, Fuxiang Zhang, Can Li

    Read original paper ↗ ·

  36. Single crystal growth and piezoelectric features of the Ca 2 Nb 2 O 7 crystal with orthorhombic symmetry

    CrystEngComm · 2022-01-01

    Linfang Xie, Shuai Hou, Fapeng Yu, Xian Zhao

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  37. Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 19

    Dalton Transactions · 2023-01-01

    Qiuyuan Feng, Zhixia Gao, Ketian Hou, Jialong Wang, Hong Lei Du, Qun Jing

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